Gas generating compositions having glass fibers

• US 8,808,476 B2
• Filed: 11/12/2008
• Issued: 08/19/2014
• Est. Priority Date: 11/12/2008
• Status: Active Grant

• Current Assignee: Autoliv ASP Incorporated (Autoliv Incorporated)
• Original Assignee: Autoliv ASP Incorporated (Autoliv Incorporated)
• Inventors: Mendenhall, Ivan V., Lund, Gary K.
• Primary Examiner(s): MCDONOUGH, JAMES E
• Application Number:
  US12/269,333
• Publication Number:
  US 20100116384A1
• Time in Patent Office: 2,106 Days
• Field of Search: 149/2, 149/45, 149/76, 149/108.4, 149/109.4
• US Class Current: 149/2
• CPC Class Codes: C06B 21/0091 Elimination of undesirable or temporary components of an intermediate or finished product, e.g. making porous or low density products, purifying, stabilising, drying; Deactivating; Reclaiming; porous inert particles or chemicals compounded for these purposes C06B23/00
• CPC Class Codes: C06B 23/001 Fillers, gelling and thickening agents (e.g. fibres) , absorbents for nitroglycerine binders, plasticisers for propellants C06B45/10; crosslinking or curing agents C06B45/10
• CPC Class Codes: C06B 23/007 Ballistic modifiers, burning rate catalysts, burning rate depressing agents, e.g. for gas generating
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

Compositions and methods relate to gas generants used in inflatable restraint systems. The gas generant grains include a fuel mixture having at least one fuel and at least one oxidizer, which have a burn rate that is susceptible to pressure sensitivity during combustion. The gas generant composition further includes a plurality of pressure sensitivity modifying glass fiber particles distributed therein to lessen the pressure sensitivity and/or to increase combustion stability of the gas generant. Such gas generants can be formed via spray drying techniques.

Claims

1. A gas generant composition comprising:

at least one fuel and at least one oxidizer, and a plurality of pressure sensitivity modifying milled glass fiber particles comprising a compound selected from the group consisting of aluminosilicate, borosilicate, calcium aluminoborosilicate and combinations thereof, wherein a comparative gas generant comprising said at least one fuel and said at least one oxidizer without said plurality of pressure sensitivity modifying milled glass fiber particles has a burn rate that is susceptible to pressure sensitivity during combustion and the gas generant has a reduced pressure sensitivity and/or increased combustion stability during combustion.

2. The gas generant composition of claim 1, wherein the gas generant composition has a linear burn rate pressure exponent of less than or equal to about 0.6.

3. The gas generant composition of claim 1, wherein said plurality of pressure sensitivity modifying milled glass fiber particles is present at greater than or equal to about 1% and less than about 10% by weight of the gas generant composition.

4. The gas generant composition of claim 3, wherein said fuel is about 40 to about 60 weight % of the total gas generant composition;

said at least one oxidizer comprises a primary oxidizer and a secondary oxidizer, wherein said primary oxidizer is about 25 to about 60 weight % of the total gas generant composition and said secondary oxidizer is about 1 to about 20 weight % of the total gas generant composition.

5. The gas generant composition of claim 4, further comprising less than or equal to about 5% by weight of a slag promoting agent in the total gas generant composition and less than or equal to about 5% by weight of a lubricating or press release agent in the total gas generant composition.

6. The gas generant composition of claim 1, wherein said oxidizer comprises a primary oxidizer and a secondary oxidizer comprising a perchlorate-containing compound.

7. The gas generant composition of claim 6, wherein said fuel comprises guanidine nitrate;

said primary oxidizer comprises basic copper nitrate; and

said secondary oxidizer is selected from an alkali metal perchlorate or an ammonium perchlorate.

8. The gas generant composition of claim 1, wherein said plurality of pressure sensitivity modifying milled glass fiber particles has an average aspect ratio (AR) ranging from about 10:

1 to about 50;

1.

9. The gas generant composition of claim 1, wherein said plurality of pressure sensitivity modifying milled glass fiber particles has an average aspect ratio (AR) ranging from about 10:

1 to about 20;

1 and has a length of greater than or equal to about 3 μ

m.

10. The gas generant composition of claim 1, wherein said plurality of pressure sensitivity modifying milled glass fiber particles has a length of greater than or equal to about 10 μ

m and less than or equal to about 200 μ

m.

11. The gas generant composition of claim 1, wherein said plurality of pressure sensitivity modifying milled glass fiber particles comprise milled glass fibers comprising calcium aluminoborosilicate.

18. The gas generant composition of claim 4, wherein said secondary oxidizer comprises a perchlorate-containing compound.

12. A gas generant comprising:

a mixture comprising at least one fuel and at least one oxidizer, wherein the mixture has a burn rate that is susceptible to pressure sensitivity during combustion;

a plurality of pressure sensitivity modifying milled glass fiber particles comprising at least one compound selected from the group consisting of silicon dioxide, aluminosilicate, borosilicate, calcium aluminoborosilicate, and combinations thereof, distributed in the fuel mixture at greater than or equal to about 1% and less than about 10% by weight, wherein the plurality of pressure sensitivity modifying milled glass fibers reduces said pressure sensitivity of said mixture during combustion, so that the gas generant composition has a linear burn rate pressure exponent of less than or equal to about 0.6.

13. The gas generant composition of claim 12, wherein said plurality of pressure sensitivity modifying milled glass fiber particles has an average aspect ratio (AR) ranging from about 10:

1 to about 50;

1 and an average length of greater than or equal to about 10 μ

m and less than or equal to about 200 μ

m.

14. The gas generant composition of claim 12, wherein said plurality of pressure sensitivity modifying milled glass fiber particles comprises calcium aluminoborosilicate.

15. The gas generant composition of claim 12, wherein said at least one oxidizer comprises a primary oxidizer and a secondary oxidizer comprising a perchlorate-containing compound.

16. The gas generant composition of claim 15, wherein said at least one fuel mixture comprises guanidine nitrate;

said primary oxidizer comprises basic copper nitrate;

said secondary oxidizer is selected from an alkali metal perchlorate or an ammonium perchlorate.

17. The gas generant composition of claim 12, wherein said at least one fuel is about 40 to about 60 weight % of the total gas generant composition;

said at least one oxidizer comprises a primary oxidizer and a secondary oxidizer, wherein said primary oxidizer is about 25 to about 60 weight % of the total gas generant composition and said secondary oxidizer is about 1 to about 20 weight % of the total gas generant composition.

19. A gas generant composition comprising:

at least one fuel and at least one oxidizer, and a plurality of pressure sensitivity modifying milled E-glass fiber particles comprising calcium aluminoborosilicate having a density of about 0.525 g/cm³, wherein a comparative gas generant comprising the at least one fuel and the at least one oxidizer without the plurality of pressure sensitivity modifying milled E-glass fiber particles has a burn rate that is susceptible to pressure sensitivity during combustion and the gas generant has a reduced pressure sensitivity during combustion so that the gas generant composition has a linear burn rate pressure exponent of less than or equal to about 0.6.

20. The gas generant composition of claim 19, wherein the at least one fuel is present at about 40 to about 60% by weight of the total gas generant composition;

the at least one oxidizer is present at about 25 to about 80% by weight, and the plurality of pressure sensitivity modifying milled E-glass fiber particles is present at greater than or equal to about 1% and less than about 10% by weight of the gas generant composition.

21. The gas generant composition of claim 20, wherein the at least one oxidizer comprises a primary oxidizer and a secondary oxidizer comprising a perchlorate selected from an alkali metal perchlorate or an ammonium perchlorate, wherein the primary oxidizer is present at about 25 to about 60 weight % of the total gas generant composition;

and the secondary oxidizer is present at about 1 to about 20 weight % of the total gas generant composition.

22. A gas generant composition comprising:

at least one fuel and at least one oxidizer, and a plurality of pressure sensitivity modifying milled E-glass fiber particles comprising calcium aluminoborosilicate having a density of about 0.525 g/cm³, wherein the plurality of pressure sensitivity modifying milled E-glass fiber particles comprises about 53.5% by weight silicon dioxide (SiO₂), about 8% by weight boron oxide (B₂O₃), about 14.5% by weight aluminum oxide (Al₂O₃), about 21.7% by weight calcium oxide (CaO), and about 1.1% by weight magnesium oxide (MgO), and wherein a comparative gas generant comprising the at least one fuel and the at least one oxidizer without the plurality of pressure sensitivity modifying milled E-glass fiber particles has a burn rate that is susceptible to pressure sensitivity during combustion and the gas generant has a reduced pressure sensitivity during combustion so that the gas generant composition has a linear burn rate pressure exponent of less than or equal to about 0.6.

23. A gas generant composition comprising:

at least one fuel, a primary oxidizer, a secondary oxidizer, and a plurality of pressure sensitivity modifying milled E-glass fiber particles comprising calcium aluminoborosilicate having a density of about 0.525 g/cm³, wherein the fuel comprises 5-amino tetrazole present at about 24% by weight of the total gas generant composition, the primary oxidizer comprises ammonium nitrate present at about 65 to about 66% by weight of the total gas generant composition, the secondary oxidizer comprises potassium nitrate present at about 6 to about 7% by weight of the total gas generant composition, and the plurality of pressure sensitivity modifying milled E-glass fiber particles is present at about 3% by weight of the total gas generant composition, wherein a comparative gas generant comprising the at least one fuel, the primary oxidizer, and the secondary oxidizer without the plurality of pressure sensitivity modifying milled E-glass fiber particles has a burn rate that is susceptible to pressure sensitivity during combustion and the gas generant has a reduced pressure sensitivity during combustion so that the gas generant composition has a linear burn rate pressure exponent of less than or equal to about 0.6.