Electrolyzer apparatus and method of making it

• US 8,808,512 B2
• Filed: 01/22/2013
• Issued: 08/19/2014
• Est. Priority Date: 01/22/2013
• Status: Active Grant

• Current Assignee: GTA, Inc.
• Original Assignee: GTA, Inc.
• Inventors: Greenbaum, Elias
• Primary Examiner(s): Smith, Nicholas A
• Application Number:
  US13/747,238
• Publication Number:
  US 20140202877A1
• Time in Patent Office: 574 Days
• Field of Search: 204263-266, 205628-639, 123/3
• US Class Current: 204/263
• CPC Class Codes: C02F 1/46104 Devices therefor; Their operating or servicing
• CPC Class Codes: C02F 2201/46115 Electrolytic cell with membranes or diaphragms
• CPC Class Codes: C25B 1/04 by electrolysis of water
• CPC Class Codes: C25B 11/02 characterised by shape or form
• CPC Class Codes: C25B 13/00 Diaphragms; Spacing elements
• CPC Class Codes: C25B 13/02 characterised by shape or form
• CPC Class Codes: C25B 9/00 Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
• CPC Class Codes: C25B 9/19 with diaphragms
• CPC Class Codes: C25B 9/73 of the filter-press type
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
• CPC Class Codes: Y02P 20/133 Renewable energy sources, e.g. sunlight
• CPC Class Codes: Y10T 29/49108 Electric battery cell making
• CPC Class Codes: Y10T 29/4911 including sealing

Abstract

An apparatus for the electrolytic splitting of water into hydrogen and oxygen gases is disclosed. The apparatus comprises: (i) a first hemi-enclosure; (ii) a second hemi-enclosure; (iii) a diaphragm electrode array positioned between the first hemi-enclosure and the second hemi-enclosure comprising: (a) a diaphragm, that passes ions and impedes the passage of gases, comprising a first side and a second opposed side; (b) a first plurality of electrodes in a first vicinity of the first side of the diaphragm; and (c) a second plurality of electrodes in a second vicinity of the second opposed side of the diaphragm; (iv) a fastener, for leak-tight fastening of the first hemi-enclosure, the diaphragm electrode array, and the second hemi-enclosure, whereby a leak-tight enclosure is formed; (v) contacts, for electrically powering the first and second pluralities of electrodes, and; (vi) pathways, configured to remove hydrogen and oxygen gases from the enclosure.

Claims

1. An apparatus for the electrolytic splitting of water into hydrogen and oxygen gases, the apparatus comprising:

a first hemi-enclosure;

a second hemi-enclosure that is separable from and not integral with the first hemi-enclosure;

a diaphragm electrode array positioned between the first hemi-enclosure and the second hemi-enclosure comprising;

a diaphragm, that passes ions and impedes the passage of gases, comprising a first side and a second opposed side;

a first plurality of electrodes in the vicinity of the first side of the diaphragm;

a second plurality of electrodes in the vicinity of the second opposed side of the diaphragm;

a fastener, for leak-tight fastening of the first hemi-enclosure, the diaphragm electrode array, and the second hemi-enclosure, whereby a leak-tight enclosure is formed;

contacts, for electrically contacting the first and second pluralities of electrodes; and

pathways, configured to separately remove hydrogen and oxygen gases from the enclosure, the pathways including;

a first headspace comprising a barrier associated with the first hemi-enclosure that is impermeable to ions, gases, and water;

a first pipe communicatively-coupled to the first headspace that receives gas generated within the first headspace and routes that received gas;

outside of the first hemi-enclosure and the first headspace;

then back inside of the first hemi-enclosure;

then through a substantial portion of fluid contained within the first hemi-enclosure; and

then back outside of the first hemi-enclosure through a bottom portion of the first hemi-enclosure;

a second headspace comprising a barrier associated with the second hemi-enclosure that is impermeable to ions, gases, and water;

a second pipe communicatively-coupled to the second headspace that receives gas generated within the second headspace and routes that received gas;

outside of the second hemi-enclosure and the second headspace;

then back inside of the second hemi-enclosure;

then through a substantial portion of fluid contained within the second hemi-enclosure; and

then back outside of the second hemi-enclosure through a bottom portion of the second hemi-enclosure.

2. The apparatus of claim 1, further comprising a source of electrical power for powering the apparatus.

3. The apparatus of claim 1 wherein the hemi-enclosures are comprised of discrete zone components within each hemi-enclosure.

4. The apparatus of claim 1 wherein each headspace includes a baffle comprised of a hydrophilic surface.

5. The apparatus of claim 1 further comprising heat sinks configured to exchange heat between the water and ambient environment using the electrolytically produced gases flowing in the pipes that exit the apparatus through bottom portions of the hemi-enclosures.

6. The apparatus of claim 1 wherein the contacts comprise busbars, shim stock, sheet metal, edge connectors containing a plurality of sockets that connect with the plurality of external wire contacts, or strip connectors, or any combination thereof.

7. The apparatus of claim 1 wherein each electrode includes a catalyst.

11. The apparatus of claim 2 wherein the source of electrical power is comprised of substantially one power supply.

8. An electrolysis apparatus for splitting water into hydrogen and oxygen gases using electrolysis, the electrolysis apparatus comprising:

a first hemi-enclosure;

a second hemi-enclosure that is separable from and not integral with the first hemi-enclosure;

a diaphragm electrode array positioned between the first hemi-enclosure and the second hemi-enclosure comprising;

a diaphragm, that passes ions and impedes the passage of gases, comprising a first side and a second opposed side;

a first plurality of wire electrodes in the vicinity of the first side of the diaphragm, wherein the wires emerge from the apparatus in a first interface defined by abutting edges of the first hemi-enclosure and the first side of the diaphragm to form a first plurality of electrical wire contacts that are external to the apparatus;

a second plurality of wire electrodes in the vicinity of the second opposed side of the diaphragm, wherein the wires emerge from the apparatus in a second interface defined by abutting edges of the second hemi-enclosure and the second side of the diaphragm to form a second plurality of electrical wire contacts that are external to the apparatus;

a fastener that fastens the first hemi-enclosure, the diaphragm electrode array and the second hemi-enclosure together so as to form a leak-tight enclosure;

a first pipe configured to remove the hydrogen gas from the enclosure, but not the oxygen gas; and

a second pipe configured to remove the oxygen gas from the enclosure, but not the hydrogen gas.

9. The apparatus of claim 8 wherein the external wires are trimmed.

10. The apparatus of claim 8 further comprising:

a first headspace comprising a barrier associated with the first hemi-enclosure that is impermeable to ions, gases, and water;

wherein the first pipe is communicatively-coupled to the first headspace that receives the hydrogen gas generated within the first headspace and routes that received gas;

outside of the first hemi-enclosure;

then back inside of the first hemi-enclosure;

then through a substantial portion of fluid contained within the first hemi-enclosure; and

then again outside of the first hemi-enclosure through a bottom portion of the first hemi-enclosure; and

a second headspace comprising a barrier associated with the second hemi-enclosure that is impermeable to ions, gases, and water;

wherein the second pipe is communicatively-coupled to the second headspace that receives the oxygen gas generated within the second headspace and routes that received gas;

outside of the second hemi-enclosure;

then back inside of the second hemi-enclosure;

then through a substantial portion of fluid contained within the second hemi-enclosure; and

then again outside of the second hemi-enclosure through a bottom portion of the second hemi-enclosure.

12. The apparatus of claim 10 wherein the first plurality of wire electrodes is anchored by opposing edges of the first hemi-enclosure and the first side of the diaphragm and the second plurality of wire electrodes is anchored by opposing edges of the second hemi-enclosure and the second side of the diaphragm.