Apparatus and method for dissolution of ozone in water and catalytic oxidation

• US 8,808,550 B2
• Filed: 03/18/2010
• Issued: 08/19/2014
• Est. Priority Date: 03/18/2010
• Status: Active Grant

• Current Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Inventors: Dholakia, Vipul P.
• Primary Examiner(s): STELLING, LUCAS A
• Application Number:
  US12/726,702
• Publication Number:
  US 20110226705A1
• Time in Patent Office: 1,615 Days
• Field of Search: 210/750, 210/752, 210/759, 210/760, 210/763, 210/765, 210/192, 210/194, 210/197, 210/205, 210/218, 210/510.1, 210/151, 422/211, 422/218, 422/222, 422/186.07
• US Class Current: 210/759
• CPC Class Codes: C02F 1/722 Oxidation by peroxides
• CPC Class Codes: C02F 1/725 by catalytic oxidation
• CPC Class Codes: C02F 1/78 with ozone C02F1/4672 takes precedence
• CPC Class Codes: C02F 2101/30 Organic compounds
• CPC Class Codes: C02F 2101/308 Dyes; Colorants; Fluorescent agents
• CPC Class Codes: C02F 2201/782 Ozone generators
• CPC Class Codes: C02F 2209/23 O3
• CPC Class Codes: C02F 2209/40 Liquid flow rate
• CPC Class Codes: C02F 2301/022 Laminar
• CPC Class Codes: C02F 2301/066 Overpressure, high pressure
• CPC Class Codes: C02F 2303/18 Removal of treatment agents after treatment

Abstract

A system and method for oxidation treatment of water in which ozone gas is dissolved in water by passing a mixed gas-liquid stream through a monolith at an elevated pressure that is close to the preferred gas output pressure for an ozone generator. The monolith is preferably contained at least partially within a gas-liquid separator vessel. Advanced oxidation is optionally provided by injecting hydrogen peroxide and/or embedding a catalyst on the monolith. At least a portion of the treated water is preferably recycled in order to increase total ozone dosing in the effluent stream.

Claims

1. A method for treating water, the method comprising:

(a) introducing water into a pre-treatment stream;

(b) generating a gas stream containing at least 3% ozone gas;

(c) introducing the gas stream into the pre-treatment stream at an injection point, resulting in a mixed-phase stream comprising ozone gas and water;

(d) passing the mixed-phase stream through a monolith having an inlet end and an outlet end and located downstream from the injection point, resulting in a reaction product;

(e) separating any undissolved gas in the reaction product from a liquid-phase portion of the reaction product; and

(f) diverting at least a portion of the liquid-phase portion of the reaction product to an effluent stream;

wherein the monolith comprises a unitary structure having walls that define parallel channels within the monolith that fill a cross-sectional area of the monolith, wherein gas-liquid flow through the monolith is laminar in nature, and wherein the channels extend through the length of the monolith from the inlet end to the outlet end.

2. The method of claim 1, further comprising:

(g) recirculating at least part of the liquid-phase portion of the reaction product into the pre-treatment stream.

3. The method of claim 1, further comprising:

(h) recovering the reaction product from the monolith in a separator vessel; and

(i) withdrawing the liquid phase portion of the reaction product from the separator vessel.

4. The method of claim 3, further comprising:

(j) maintaining a sufficient liquid-phase portion of the reaction product in the separator vessel to cover an outlet end of the monolith.

5. The method of claim 1, wherein step (d) further comprises passing the mixed-phase stream through the monolith at a liquid velocity that is between 0.2 m/s and 1.0 m/s.

6. The method of claim 1, wherein step (d) further comprises passing the mixed-phase stream through a monolith having between 100 and 1200 channels per square inch (15 and 186 channels per square centimeter).

7. The method of claim 1, further comprising:

(k) passing the mixed-phase stream through a static mixer upstream from the monolith and downstream from the injection point.

8. The method of claim 1, further comprising:

(l) injecting hydrogen peroxide into the water stream upstream from the monolith.

9. The method of claim 1, wherein step (d) comprises passing the mixed-phase stream through a monolith downstream from the injection point, the monolith having a catalyst impregnated thereon, resulting in at least a portion of the ozone gas being dissolved into the water and transfer of at least a portion of the dissolved ozone to the catalyst surface for reaction.

10. The method of claim 1, further comprising:

(m) diverting a portion of a water stream to form an influent stream;

(n) injecting the influent stream into the pre-treatment stream; and

(o) injecting the effluent stream into the water stream downstream from the influent stream.

11. A water treatment system comprising:

a water supply line;

an ozone generator for generating an output gas stream containing ozone;

an ozone supply line that is configured to carry the output gas stream from the ozone generator and to connect to the water supply line at an injection point;

a monolith having an outlet end and an inlet end that is downstream from the injection point and is in flow communication with the water supply line;

a vessel that is in flow communication with the outlet end of the monolith;

a gas purge line located on the vessel;

a vessel output line located on the vessel for extracting liquid from the vessel, the vessel output line being positioned below the gas purge line; and

an effluent port located on the vessel output line;

wherein the monolith comprises a unitary structure having walls that define parallel channels within the monolith that fill a cross-sectional area of the monolith, wherein gas-liquid flow through the monolith is laminar in nature, and wherein the channels extend through the length of the monolith from the inlet end to the outlet end.

12. The water treatment system of claim 11, wherein the outlet end of the monolith is positioned within the vessel.

13. The water treatment system of claim 11, further comprising a recycle line that is configured to return at least some of the liquid from the vessel output line to the water supply line.

14. The water treatment system of claim 11, wherein the monolith comprises a plurality of parallel channels.

15. The water treatment system of claim 14, wherein the plurality of parallel channels are arranged at a density of between 100 and 1200 channels per square inch (15 and 186 channels per square centimeter).

16. The water treatment system of claim 11, further comprising a pump in flow communication with the water supply line for providing a pressurized flow of water through the water supply line.

17. The water treatment system of claim 11, further comprising a hydrogen peroxide port that is in flow communication with the water line and is connected to a supply of hydrogen peroxide.

18. The water treatment system of claim 11, further comprising an ozone recycle line that is configured to divert at least a portion of the gas collected from the gas purge line to the ozone supply line.

19. The water treatment system of claim 11, wherein the monolith is impregnated with a catalyst.

20. The water treatment system of claim 19, wherein the catalyst is an oxidation catalyst.