Heat transfer compositions

• US 8,808,571 B2
• Filed: 05/20/2011
• Issued: 08/19/2014
• Est. Priority Date: 05/20/2010
• Status: Expired due to Fees

• Current Assignee: Mexichem, S.A.B. De C.V. (Orbia Advance Corporation, S.A.B. de C.V.)
• Original Assignee: Mexichem, S.A.B. De C.V. (Orbia Advance Corporation, S.A.B. de C.V.)
• Inventors: Low, Robert E.
• Primary Examiner(s): MC GINTY, DOUGLAS J
• Application Number:
  US13/698,810
• Publication Number:
  US 20130126777A1
• Time in Patent Office: 1,187 Days
• Field of Search: 252/67, 252/68, 252/69, 252/364, 521/131, 621/14, 134/36, 605/31
• US Class Current: 252/67
• CPC Class Codes: B01D 11/0288 Applications, solvents
• CPC Class Codes: B01D 11/0492 Applications, solvents used
• CPC Class Codes: C02F 1/26 by extraction
• CPC Class Codes: C08J 2203/06 CO2, N2 or noble gases
• CPC Class Codes: C08J 2203/14 Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
• CPC Class Codes: C08J 2203/142 Halogenated saturated hydrocarbons, e.g. H3C-CF3
• CPC Class Codes: C08J 2207/04 Aerosol, e.g. polyurethane foam spray
• CPC Class Codes: C08J 2325/06 Polystyrene
• CPC Class Codes: C08J 2363/00 Characterised by the use of epoxy resins; Derivatives of epoxy resins
• CPC Class Codes: C08J 2375/00 Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
• CPC Class Codes: C08J 9/122 Hydrogen, oxygen, CO2, nitrogen or noble gases
• CPC Class Codes: C08J 9/127 Mixtures of organic and inorganic blowing agents
• CPC Class Codes: C08J 9/146 only fluorine as halogen atoms
• CPC Class Codes: C09K 2205/106 Carbon dioxide
• CPC Class Codes: C09K 2205/12 Hydrocarbons
• CPC Class Codes: C09K 2205/122 Halogenated hydrocarbons
• CPC Class Codes: C09K 2205/126 Unsaturated fluorinated hydrocarbons
• CPC Class Codes: C09K 23/007 Organic compounds containing halogen
• CPC Class Codes: C09K 3/30 for aerosols aerosol containers B65D83/14
• CPC Class Codes: C09K 5/041 for compression-type refrigeration systems
• CPC Class Codes: C09K 5/044 : comprising halogenated compounds
• CPC Class Codes: C09K 5/045 : containing only fluorine as halogen
• CPC Class Codes: C11D 7/5018 : Halogenated solvents
• CPC Class Codes: F01K 25/08 : using special vapours
• CPC Class Codes: F25B 13/00 : Compression machines, plants or systems, with reversible cycle defrosting cycles F25B47/02
• CPC Class Codes: F25B 30/02 : of the compression type
• CPC Class Codes: F25B 45/00 : Arrangements for charging or discharging refrigerant
• CPC Class Codes: F28D 15/02 : in which the medium condenses and evaporates, e.g. heat pipes heat pipes used in solar heat collectors F24S10/95; in radiators F28D1/0226; in nuclear reactors G21C15/257
• CPC Class Codes: F28D 5/00 : Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, using the cooling effect of natural or forced evaporation
• CPC Class Codes: Y02A 40/963 : Off-grid food refrigeration
• CPC Class Codes: Y10T 29/49716 : Converting
• CPC Class Codes: Y10T 29/49718 : Repairing

Abstract

The invention provides a heat transfer composition comprising (i) a first component selected from trans-1,3,3,3-tetrafluoropropene (R-1234ze(E)), cis-1,3,3,3-tetrafluoropropene (R-1234ze(Z)) and mixtures thereof; (ii) carbon dioxide (R-744); and (iii) a third component selected from 1,1-difluoroethane (R-152a), fluoroethane (R-161), and mixtures thereof.

Claims

1. A heat transfer composition comprising:

(i) from about 10 to about 95% by weight R-1234ze(E);

(ii) from about 2 to about 30% by weight R-744; and

(iii) from about 3 to about 60% by weight of a third component comprising R-161.

2. A method for reducing the environmental impact arising from the operation of a product comprising an existing compound or composition, the method comprising replacing at least partially the existing compound or composition with the composition of claim 1.

3. A method for preparing the composition of claim 1, the composition comprising R-134a, the method comprising introducing R-1234ze(E), R-744, and the third component, into a heat transfer device containing an existing heat transfer fluid which is R-134a.

4. A method according to claim 3 comprising the step of removing at least some of the existing R-134a from the heat transfer device before introducing the R-1234ze(E), R-744, and the third component.

5. A composition according to claim 1 comprising from about 4 to about 30% R-744 by weight.

6. A method for generating greenhouse gas emission credit comprising (i) replacing an existing compound or composition with the composition of claim 1, wherein the composition has a lower GWP than the existing compound or composition;

and (ii) obtaining greenhouse gas emission credit for said replacing step.

7. A method of claim 6 wherein the use of the composition results in at least one of a lower Total Equivalent Warming Impact, or a lower Life-Cycle Carbon Production than is attained by use of the existing compound or composition.

8. A composition according to claim 1 wherein the composition has a critical temperature of greater than about 65°

C.

9. A method of claim 6 carried out on a product from at least one field of air-conditioning, refrigeration, heat transfer, blowing agents, aerosols or sprayable propellants, gaseous dielectrics, cryosurgery, veterinary procedures, dental procedures, fire extinguishing, flame suppression, solvents, cleaners, air horns, pellet guns, topical anesthetics, or expansion applications.

10. A method according to claim 2, wherein the product is selected from a heat transfer device, a blowing agent, a foamable composition, a sprayable composition, a solvent or a mechanical power generation device.

11. A method according to claim 10 wherein the product is a heat transfer device.

12. A composition according to claim 1 wherein the third component is R-161 or a mixture of R-161 and R-152a.

13. A composition according to claim 12 comprising from about 45 to about 94% R-1234ze(E), from about 4 to about 30% by weight R-744 and from about 2 to about 25% by weight R-161.

14. A composition according to claim 13 comprising from about 62 to about 92% R-1234ze(E), from about 10 to about 28% by weight R-744 and from about 2 to about 10% by weight R-161.

15. A composition according to claim 1, further comprising R-125.

16. A composition according to claim 1, wherein the composition has a GWP of less than 1000.

17. A composition according to claim 1, wherein the composition has a volumetric refrigeration capacity within about 15%, of an existing refrigerant that the composition is intended to replace.

18. A composition according to claim 1, wherein the composition is less flammable than R-152a alone or R-161 alone.

19. A composition according to claim 18, wherein the composition has at least one of:

(a) a higher flammable limit;

(b) a higher ignition energy;

or

(c) a lower flame velocity

compared to R-152a alone or R-161 alone.

20. A composition according to claim 1 wherein the composition has a fluorine ratio (F/(F+H)) of from about 0.42 to about 0.7.

21. A composition according to claim 1 wherein the composition is non-flammable.

22. A composition according to claim 1, wherein the composition has a cycle efficiency within about 5% of an existing refrigerant that the composition is intended to replace.

23. A composition according to claim 1, wherein the composition has a compressor discharge temperature within about 15 k of an existing refrigerant that the composition is intended to replace.

24. A composition comprising a lubricant and the composition of claim 1.

25. A composition according to claim 24, wherein the lubricant is selected from mineral oil, silicone oil, PABs, POEs, PAGs, PAG esters, PVEs, poly (alpha-olefins) and combinations thereof.

26. A composition according to claim 24 further comprising a stabilizer.

27. A composition according to claim 26, wherein the stabilizer is selected from diene-based compounds, phosphates, phenol compounds and epoxides, and mixtures thereof.

28. A composition comprising a flame retardant and the composition of claim 1.

29. A composition according to claim 28, wherein the flame retardant is selected from the group consisting of tri-(2-chloroethyl)-phosphate, (chloropropyl) phosphate, tri-(2,3-dibromopropyl)-phosphate, tri-(1,3-dichloropropyl)-phosphate, diammonium phosphate, various halogenated aromatic compounds, antimony oxide, aluminium trihydrate, polyvinyl chloride, a fluorinated iodocarbon, a fluorinated bromo carbon, trifluoro iodomethane, perfluoroalkyl amines, bromo-fluoroalkyl amines and mixtures thereof.

30. A composition according to claim 1 wherein the composition is a refrigerant composition.

31. A heat transfer device containing the composition of claim 1.

32. A method according to claim 6, wherein the existing compound or composition is a heat transfer composition.

33. A heat transfer device according to claim 31 wherein the heat transfer device is a refrigeration device.

34. A heat transfer device according to claim 33 wherein the heat transfer device is selected from group consisting of automotive air conditioning systems, residential air conditioning systems, commercial air conditioning systems, residential refrigerator systems, residential freezer systems, commercial refrigerator systems, commercial freezer systems, chiller air conditioning systems, chiller refrigeration systems, and commercial or residential heat pump systems.

35. A heat transfer device according to claim 33 wherein the heat transfer device contains a compressor.

36. A blowing agent comprising the composition of claim 1.

37. A foamable composition comprising one or more components capable of forming foam and the composition of claim 1, wherein the one or more components capable of forming foam are selected from polyurethanes, thermoplastic polymers and resins and mixtures thereof.

38. A method according to claim 32 wherein the heat transfer composition is a refrigerant selected from R-134a, R-1234yf, R-152a, R-404A, R-410A, R-507, R-407A, R-407B, R-407D, R-407E and R-407F.

39. A foam comprising the composition of claim 1.

40. A sprayable composition comprising material to be sprayed and a propellant comprising the composition of claim 1.

41. A method for cooling an article comprising condensing the composition of claim 1 and thereafter evaporating the composition in the vicinity of the article to be cooled.

42. A method for heating an article comprising condensing the composition of claim 1 in the vicinity of the article to be heated and thereafter evaporating the composition.

43. A method for extracting a substance from biomass comprising contacting biomass with a solvent comprising the composition of claim 1 and separating the substance from the solvent.

44. A method of cleaning an article comprising contacting the article with a solvent comprising the composition of claim 1.

45. A method of extracting a material from an aqueous solution comprising contacting the aqueous solution with a solvent comprising the composition of claim 1 and separating the material from the solvent.

46. A method for extracting a material from a particulate solid matrix comprising contacting the particulate solid matrix with a solvent comprising the composition of claim 1 and separating the material from the solvent.

47. A mechanical power generation device containing the composition of claim 1.

48. A mechanical power generating device according to claim 47 wherein the mechanical power generating device is adapted to use a Rankine Cycle or modification thereof to generate work from heat.

49. A method of retrofitting a heat transfer device comprising the step of removing an existing heat transfer fluid, and introducing the composition of claim 1.

50. A method of claim 49 wherein the heat transfer device is a refrigeration device.

51. A method according to claim 50 wherein the heat transfer device is an air conditioning system.