Carbon nanotube synthesizing apparatus

• US 8,815,168 B2
• Filed: 03/09/2013
• Issued: 08/26/2014
• Est. Priority Date: 03/29/2012
• Status: Expired due to Fees

• Current Assignee: Honda Motor Co., Ltd. (Honda Motor Company), Waseda University (Waseda University Educational Association)
• Original Assignee: Honda Motor Co., Ltd. (Honda Motor Company), Waseda University (Waseda University Educational Association)
• Inventors: Kawarada, Hiroshi, Ohashi, Toshiyuki, Ohta, Masahiro, Tokune, Toshio, Nikawa, Hidefumi, Kato, Ryogo
• Primary Examiner(s): Mayekar, Kishor
• Application Number:
  US13/791,960
• Publication Number:
  US 20130259763A1
• Time in Patent Office: 535 Days
• Field of Search: 422/186.04, 422/186, 118/723.MW, 977/843
• US Class Current: 422/186
• CPC Class Codes: B01J 19/088 giving rise to electric discharges for heating purposes H05B7/00; for the production of ozone C01B13/11, H01T19/00
• CPC Class Codes: B01J 19/126 Microwaves
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: B82Y 40/00 Manufacture or treatment of nanostructures
• CPC Class Codes: C01B 32/16 Preparation
• CPC Class Codes: C01P 2002/82 by IR- or Raman-data

Abstract

A carbon nanotube synthesizing apparatus in which the state of generated plasma can be stabilized is provided. A carbon nanotube synthesizing apparatus 1 comprises a chamber 2, an antenna 3 including a tip 3a, a microwave conductor 4, a gas introducing unit 5, a gas discharging unit 6, a substrate holding unit 7, and a heating unit 8. The shape of the inner wall of the chamber 2 is symmetrical with respect to the tip 3a of the antenna 3.

Claims

1. A carbon nanotube synthesizing apparatus comprising:

a chamber;

an antenna which is provided under a central portion of a ceiling of the chamber and comprises a tip configured to generate plasma;

a microwave conductor which is provided in the central portion of the ceiling of the chamber and is configured to conduct a microwave to the antenna, the microwave forming a standing wave by being reflected by the tip of the antenna;

a gas inlet configured to introduce gas to the chamber;

a gas outlet configured to discharge gas from the chamber;

a substrate holding unit configured to hold a substrate for carbon nanotube synthesis in the chamber;

a position adjusting unit configured to adjust a position of the substrate for carbon nanotube synthesis to a position at a distance from an antenna in the chamber, the distance allowing the substrate for carbon nanotube synthesis to avoid being attacked by an ion that is generated as a by-product of a radical generated by plasma generated at the antenna and to be reached by the radical kept in a radical state; and

a heating unit configured to heat the substrate for carbon nanotube synthesis held by the substrate holding unit,

wherein a shape of an inner wall of the chamber is symmetrical with respect to the tip of the antenna, and

wherein the microwave conductor extends from a first surface of the chamber, the gas inlet is disposed in the ceiling of the chamber, the gas outlet is disposed in a surface opposite the ceiling of the chamber, and the gas inlet and the gas outlet are positioned symmetrical to each other in the chamber with respect to the tip of the antenna.

2. The carbon nanotube synthesizing apparatus according to claim 1, wherein a value of R/r, which is a ratio of an inner diameter R of the chamber to an outer diameter r of the antenna, is in a range of 10 to 40, where R is the inner diameter of the chamber and r is the outer diameter of the antenna.

3. The carbon nanotube synthesizing apparatus according to claim 1, wherein the microwave conductor is cylindrical, the antenna is conical, and a maximum diameter of the antenna is equal to a diameter of the microwave conductor.

4. The carbon nanotube synthesizing apparatus according to claim 1, wherein the microwave conductor comprises an insulating member therearound.

5. The carbon nanotube synthesizing apparatus according to claim 1, wherein the position adjusting unit comprises a first lifting and lowering unit configured to freely lift and lower the substrate holding unit, and the first lifting and lowering unit adjusts the position of the substrate for carbon nanotube synthesis to be the position at the distance, the distance allowing the substrate for carbon nanotube synthesis to avoid being attacked by the ion that is generated as the by-product of the radical generated by plasma generated at the antenna and to be reached by the radical kept in the radical state.

6. The carbon nanotube synthesizing apparatus according to claim 1, wherein the position adjusting unit comprises a second lifting and lowering unit configured to freely lift and lower the microwave conductor, and the second lifting and lowering unit adjusts a position of the antenna to be a position at a distance, the distance allowing the substrate for carbon nanotube synthesis to avoid being attacked by the ion that is generated as the by-product of the radical generated by plasma generated at the antenna and to be reached by the radical kept in the radical state.

7. The carbon nanotube synthesizing apparatus according to claim 1, wherein the heating unit comprises an induction heating coil provided around the substrate holding unit, and a power supply device configured to supply power to the induction heating coil.

8. The carbon nanotube synthesizing apparatus according to claim 7, wherein the heating unit is further configured to be movable in synchronization with and concomitantly with the substrate holding unit.

9. The carbon nanotube synthesizing apparatus according to claim 1, wherein the heating unit comprises an infrared heating device provided inside or outside the chamber, and a power supply device configured to supply power to the infrared heating device.

10. The carbon nanotube synthesizing apparatus according to claim 1, wherein the heating unit comprises a laser heating device provided outside the chamber, and a power supply device configured to supply power to the laser heating device.

11. The carbon nanotube synthesizing apparatus according to claim 1, wherein a portion of the microwave conductor extends into the chamber, and the portion is covered by an electrical insulator.