Complex crystal phosphor, light emitting device, surface light source apparatus, display apparatus, and lighting device

• US 8,821,758 B2
• Filed: 03/24/2011
• Issued: 09/02/2014
• Est. Priority Date: 03/26/2010
• Status: Active Grant

• Current Assignee: Samsung Electronics Co. Ltd.
• Original Assignee: Samsung Electronics Co. Ltd.
• Inventors: Kim, Do Hwan, Ryu, Jeong Ho, Kim, Sang Hyun, Yoon, Chul Soo
• Primary Examiner(s): Koslow, Carol M
• Assistant Examiner(s): EDMONDSON, LYNNE RENEE
• Application Number:
  US13/071,201
• Publication Number:
  US 20110234118A1
• Time in Patent Office: 1,258 Days
• Field of Search: 252/301.4 F, 252/301.4 R
• US Class Current: 252/301.4F
• CPC Class Codes: C09K 11/0883 Arsenides; Nitrides; Phosphides
• CPC Class Codes: C09K 11/77347 Silicon Nitrides or Silicon Oxynitrides
• CPC Class Codes: C09K 11/77348 Silicon Aluminium Nitrides or Silicon Aluminium Oxynitrides
• CPC Class Codes: H01L 33/502 Wavelength conversion materials

Abstract

A complex crystal phosphor is an inorganic composition containing at least an M element, an Al element, silicon, oxygen, and nitrogen. The inorganic composition has particles having at least two types of crystal phase, and the at least two types of crystal phase include a first crystal phase which is the same as a M₂SiO₄ crystal and a second crystal phase as a β-sialon crystal. Here, M is at least one element selected from the group consisting of (Mg), calcium (Ca), strontium (Sr), and barium (Ba).

Claims

1. A complex crystal phosphor of an inorganic composition comprising an M element, an Al element, silicon, oxygen, and nitrogen,

wherein the inorganic composition has particles of at least a first crystal phase and a second crystal phase, so that a single particle comprises both the first crystal phase and the second crystal phase, and the first crystal phase includes a M₂SiO_4-yN_y crystal, wherein 0<

x<

3 and y=2x/3, and the second crystal phase includes a β

-sialon crystal,

wherein M is at least one element selected from the group consisting of magnesium (Mg), calcium (Ca), strontium (Sr), and barium (Ba).

2. The phosphor of claim 1, wherein when an excitation source is irradiated, the complex crystal phosphor emits light having a peak wavelength ranging from about 570 nm to about 660 nm.

3. The phosphor of claim 2, wherein an emission wavelength spectrum of the complex crystal phosphor has a substantially single peak wavelength.

4. The phosphor of claim 2, wherein the excitation source has a peak wavelength ranging from about 300 nm to about 480 nm.

5. The phosphor of claim 3, wherein the half amplitude of the light emission wavelength spectrum is approximately 100 nm or greater.

6. The phosphor of claim 1, wherein the first crystal phase is Sr₂SiO_4-xN_y,wherein 0<

x<

3, y=2x/3.

7. The phosphor of claim 1, wherein the second crystal phase is Si_6-zAl_zO_zN_8-z, wherein 0<

z<

1.

8. The phosphor of claim 1, wherein the first crystal phase is contained at about 60 to about 95 mass percent, and the second crystal phase is contained at about 5 to about 40mass percent.

9. The phosphor of claim 1, wherein the complex crystal phosphor comprises a quasi-orthorhombic crystal in which the two crystal phases are mutually employed.

10. The phosphor of claim 1, wherein the complex crystal phosphor further comprises a third crystal phase as a M₂Si₅O_aN_8-b crystal, wherein 0<

a<

3, b=2a/3.

11. The phosphor of claim 10, wherein the first crystal phase is contained at about 50 to about 90 mass percent, the second crystal phase is contained at about 5 to about 40 mass percent, and the third crystal phase is contained at about 10 mass percent or less.

12. The phosphor of claim 1, wherein the phosphor further comprises at least one type of rare earth element as an activator.

13. The phosphor of claim 12, wherein the rare earth element is selected from the group consisting of cerium (Ce), praseodymium (Pr), neodymium (Nd), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), and ytterbium (Yb).