Fuel cell system operated on liquid fuels

• US 8,822,094 B2
• Filed: 04/02/2007
• Issued: 09/02/2014
• Est. Priority Date: 04/03/2006
• Status: Active Grant

• Current Assignee: Bloom Energy Corporation
• Original Assignee: Bloom Energy Corporation
• Inventors: Venkataraman, Swaminathan, Ballantine, Arne Watson, Weingaertner, David
• Primary Examiner(s): Walls, Cynthia K.
• Application Number:
  US11/730,540
• Publication Number:
  US 20070231635A1
• Time in Patent Office: 2,710 Days
• Field of Search: None
• US Class Current: 429/440
• CPC Class Codes: H01M 2008/1293 Fuel cells with solid oxide electrolytes
• CPC Class Codes: H01M 8/04097 with recycling of the reactants H01M8/04119, H01M8/04104 take precedence
• CPC Class Codes: H01M 8/0612 from carbon-containing material
• CPC Class Codes: H01M 8/0662 Treatment of gaseous reactants or gaseous residues, e.g. cleaning
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A fuel cell system includes a fuel cell stack, a heavy hydrocarbon fuel source, and a fractionator configured to separate light ends from heavy ends of a heavy hydrocarbon fuel provided from the heavy hydrocarbon fuel source.

Claims

1. A fuel cell system, comprising:

a fuel cell stack;

a heavy hydrocarbon fuel source;

a fractionator configured to separate light ends from heavy ends of a heavy hydrocarbon fuel provided from the heavy hydrocarbon fuel source;

a fuel reformer, wherein the fuel reformer is thermally integrated with the fuel cell stack by thermal conduction through a thermally conductive material such that heat resulting from a reaction in the fuel cell stack drives a net endothermic reaction in the fuel reformer, wherein the thermal conduction excludes heat provided from a cathode exhaust conduit of the fuel cell stack to the fuel reformer;

a burner or catalytic reactor;

a conduit feeding the light ends from the fractionator to the fuel reformer;

a conduit feeding a reformed fuel from the fuel reformer to the fuel cell stack;

a conduit feeding a first portion of an anode exhaust stream from the fuel cell stack to the burner or catalytic reactor;

a conduit recycling a second portion of the anode exhaust stream into a fuel inlet stream without purification of the anode exhaust stream; and

a conduit feeding the heavy ends from the fractionator to the burner or catalytic reactor.

2. The system of claim 1, wherein the fuel cell stack comprises a SOFC stack.

3. The system of claim 1, wherein the heavy hydrocarbon fuel source comprises a jet fuel tank.

4. The system of claim 1, wherein the heavy hydrocarbon fuel source comprises a diesel fuel tank.

9. The system of claim 1, wherein the fuel reformer is thermally integrated with the fuel cell stack by thermal conduction through the thermally conductive material between the fuel reformer and an anode exhaust conduit of the fuel cell stack.

5. A fuel cell system, comprising:

a fuel cell stack;

a first means for separating light ends from heavy ends of a heavy hydrocarbon fuel;

a second means for reforming fuel, wherein the second means is thermally integrated with the fuel cell stack by thermal conduction through a thermally conductive material such that heat resulting from a reaction in the fuel cell stack drives a net endothermic reaction for reforming fuel, wherein the thermal conduction excludes heat provided from a cathode exhaust conduit of the fuel cell stack to the second means for reforming fuel;

a third means for burning or catalytically reacting the heavy ends and a first portion of an anode exhaust stream from the fuel cell stack;

a fourth means for feeding the light ends from the first means to the second means;

a fifth means for feeding the first portion of the anode exhaust stream from the fuel cell stack to the third means;

a sixth means for feeding the heavy ends from the first means to the third means;

a seventh means for providing the light ends reformed by the second means to be used as fuel in the fuel cell stack; and

an eighth means for recycling a second portion of the anode exhaust stream into a fuel inlet stream without purification of the anode exhaust stream.

6. The system of claim 5, wherein the heavy hydrocarbon fuel comprises diesel fuel or jet fuel.

7. The system of claim 5, wherein the fuel cell stack comprises a SOFC stack.

8. The system of claim 5, wherein the second means is thermally integrated with the fuel cell stack by thermal conduction through the thermally conductive material between the second means and an anode exhaust conduit of the fuel cell stack.

10. A fuel cell system, comprising:

a fuel cell stack;

a heavy hydrocarbon fuel source;

a fractionator configured to separate light ends from heavy ends of a heavy hydrocarbon fuel provided from the heavy hydrocarbon fuel source;

a fuel reformer, wherein the fuel reformer is thermally integrated with the fuel cell stack by thermal conduction through a thermally conductive material between the fuel reformer and an anode exhaust conduit of the fuel cell stack;

a burner or catalytic reactor;

a conduit feeding the light ends from the fractionator to the fuel reformer;

a conduit feeding a reformed fuel from the fuel reformer to the fuel cell stack; and

a conduit feeding the heavy ends from the fractionator to the burner or catalytic reactor.