Electrode structures for aqueous electrolyte lithium sulfur batteries

• US 8,828,573 B2
• Filed: 04/05/2012
• Issued: 09/09/2014
• Est. Priority Date: 11/15/2011
• Status: Active Grant

• Current Assignee: PolyPlus Battery Company
• Original Assignee: PolyPlus Battery Company
• Inventors: Visco, Steven J., Nimon, Yevgeniy S., Katz, Bruce D., De Jonghe, Lutgard C., Goncharenko, Nikolay, Loginova, Valentina
• Primary Examiner(s): Ruddock, Ula C
• Assistant Examiner(s): Chmielecki, Scott J
• Application Number:
  US13/440,847
• Publication Number:
  US 20130122344A1
• Time in Patent Office: 887 Days
• US Class Current: 429/105
• CPC Class Codes: H01M 10/36 Accumulators not provided for in groups H01M10/05-H01M10/34
• CPC Class Codes: H01M 2200/10 Temperature sensitive devices
• CPC Class Codes: H01M 2200/20 Pressure-sensitive devices
• CPC Class Codes: H01M 4/38 of elements or alloys
• CPC Class Codes: H01M 4/382 Lithium H01M4/405 takes precedence
• CPC Class Codes: H01M 4/405 Alloys based on lithium
• CPC Class Codes: H01M 4/5815 Sulfides
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y10T 29/49108 Electric battery cell making

Abstract

Provided are lithium sulfur battery cells that use water as an electrolyte solvent. In various embodiments the water solvent enhances one or more of the following cell attributes: energy density, power density and cycle life. Significant cost reduction can also be realized by using an aqueous electrolyte in combination with a sulfur cathode. For instance, in applications where cost per Watt-Hour (Wh) is paramount, such as grid storage and traction applications, the use of an aqueous electrolyte in combination with inexpensive sulfur as the cathode active material can be a key enabler for the utility and automotive industries, providing a cost effective and compact solution for load leveling, electric vehicles and renewable energy storage.

Claims

1. An aqueous lithium sulfur electrochemical cell comprising:

an anode structure comprising an electroactive component material;

a cathode comprising a solid electron transfer medium and solid phase active sulfur;

an aqueous electrolyte comprising at least 10 vol % of a non-aqueous solvent and greater than 10 vol % of water in direct contact with the electron transfer medium; and

active sulfur species in direct contact with the aqueous electrolyte;

wherein the anode electroactive material is isolated from direct contact with the aqueous electrolyte whereby the anode electroactive material does not contact water of the aqueous electrolyte or the active sulfur species.

2. The aqueous lithium sulfur electrochemical cell of claim 1, wherein the solid phase active sulfur is elemental sulfur.

3. The aqueous lithium sulfur electrochemical cell of claim 1, wherein the solid phase active sulfur is lithium sulfide.

4. The aqueous lithium sulfur electrochemical cell of claim 1, wherein the active sulfur concentration in the aqueous electrolyte is greater than 10 molar sulfur.

5. The aqueous lithium sulfur electrochemical cell of claim 1, wherein the active lithium sulfur stoichiometric ratio in the electrolyte is Li₂S_x (x>

5).

6. The aqueous lithium sulfur electrochemical cell of claim 1, wherein the electrochemical cell is a secondary battery cell.

7. The aqueous lithium sulfur electrochemical cell of claim 2, wherein the electrochemical cell is a secondary battery cell.

8. The aqueous lithium sulfur electrochemical cell of claim 3, wherein the electrochemical cell is a secondary battery cell.

9. The aqueous lithium sulfur electrochemical cell of claim 4, wherein the electrochemical cell is a secondary battery cell.

10. The aqueous lithium sulfur electrochemical cell of claim 5, wherein the electrochemical cell is a secondary battery cell.

11. An aqueous lithium sulfur electrochemical cell comprising:

an anode structure comprising a lithium electroactive material;

a cathode comprising a solid electron transfer medium;

an aqueous electrolyte comprising at least 10 vol % of a non-aqueous solvent and greater than 10 vol % of water in direct contact with the electron transfer medium; and

active sulfur species in direct contact with the aqueous electrolyte;

wherein the anode electroactive material is isolated from direct contact with the aqueous electrolyte whereby the anode electroactive material does not contact water of the aqueous electrolyte or the active sulfur species; and

wherein the active sulfur concentration in the aqueous electrolyte is greater than 10 molar sulfur and the cell is fabricated devoid of solid phase elemental sulfur.

12. An aqueous lithium sulfur electrochemical cell comprising:

an anode structure comprising a lithium electroactive material;

a cathode comprising a solid electron transfer medium;

an aqueous electrolyte comprising at least 10 vol % of a non-aqueous solvent and greater than 10 vol % of water in direct contact with the electron transfer medium; and

active sulfur species in direct contact with the aqueous electrolyte;

wherein the anode electroactive material is isolated from direct contact with the aqueous electrolyte whereby the anode electroactive material does not contact water of the aqueous electrolyte or the active sulfur species; and

wherein the electron transfer medium has an overpotential for H₂ evolution of at least 50 mV beyond the thermodynamic potential of water reduction.

13. The aqueous lithium sulfur electrochemical cell of claim 12, wherein the electron transfer medium has an overpotential for H₂ evolution of at least 100 mV beyond the thermodynamic potential of water reduction.

14. The aqueous lithium sulfur electrochemical cell of claim 12, wherein the electron transfer medium has an overpotential for H₂ evolution of at least 200 mV beyond the thermodynamic potential of water reduction.

15. The aqueous lithium sulfur electrochemical cell of claim 12, wherein the electron transfer medium has an overpotential for H₂ evolution of at least 300 mV beyond the thermodynamic potential of water reduction.

16. The aqueous lithium sulfur electrochemical cell of claim 12, wherein the electron transfer medium has an overpotential for H₂ evolution of at least 500 mV beyond the thermodynamic potential of water reduction.

17. An aqueous lithium sulfur electrochemical cell comprising:

an anode structure comprising a lithium electroactive material;

a cathode comprising a solid electron transfer medium;

an aqueous electrolyte comprising at least 10 vol % of a non-aqueous solvent and greater than 10 vol % of water in direct contact with the electron transfer medium; and

active sulfur species in direct contact with the aqueous electrolyte;

wherein the anode electroactive material is isolated from direct contact with the aqueous electrolyte whereby the anode electroactive material does not contact water of the aqueous electrolyte or the active sulfur species; and

wherein the cell is discharged to cell voltages below 2.1V.

18. The aqueous lithium sulfur electrochemical cell of claim 17, wherein the cell is discharged to cell voltages below 2.0V.

19. The aqueous lithium sulfur electrochemical cell of claim 17, wherein the cell is discharged to cell voltages below 1.9V.

20. The aqueous lithium sulfur electrochemical cell of claim 17, wherein the cell is discharged to cell voltages below 1.8V.