Device and method for calculating value of rechargeable battery

• US 8,836,284 B2
• Filed: 05/17/2010
• Issued: 09/16/2014
• Est. Priority Date: 05/17/2010
• Status: Active Grant

• Current Assignee: Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Original Assignee: Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Inventors: Takahashi, Kenji, Haga, Nobuyasu, Tomura, Shuji
• Primary Examiner(s): Tso, Edward
• Assistant Examiner(s): BOATENG, ALEXIS ASIEDUA
• Application Number:
  US13/698,584
• Publication Number:
  US 20130057291A1
• Time in Patent Office: 1,583 Days
• Field of Search: 320/104, 320/110, 320/132, 320/112, 320/113, 320/114, 320/115, 320/116, 320/118, 320/122, 320/127, 320/137, 320/134, 320/136, 324/426, 324/427, 324/430
• US Class Current: 320/122
• CPC Class Codes: G01R 31/389 Measuring internal impedance, internal conductance or related variables
• CPC Class Codes: H01M 10/48 Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569
• CPC Class Codes: H01M 10/54 Reclaiming serviceable parts of waste accumulators
• CPC Class Codes: H01M 50/209 adapted for prismatic or rectangular cells H01M50/216 takes precedence
• CPC Class Codes: H01M 50/227 Organic material
• CPC Class Codes: H01M 50/264 for cells or batteries, e.g. straps, tie rods or peripheral frames
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02W 30/84 Recycling of batteries or fuel cells

Abstract

A rechargeable battery is used with a plurality of battery cells restrained by a restraint member. After the rechargeable battery has the restraint member removed therefrom and is thus disassembled when the rechargeable battery is subsequently re-restrained by the restraint member and thus reused an internal resistance measurement unit measures the rechargeable battery'"'"'s internal resistance based on battery data detected after the rechargeable battery is re-restrained. At least for the internal voltage, from a value thereof as measured after the battery is re-restrained an evaluation unit evaluates a value of the rechargeable battery that is reused.

Claims

1. A value calculation device for a rechargeable battery used with a plurality of battery cells restrained by a restraint member, comprising:

a detector for detecting battery data obtained as said rechargeable battery is electrically charged and discharged;

a first measurement unit for measuring a battery parameter of said rechargeable battery after said rechargeable battery has said restraint member removed therefrom and the plurality of battery cells has a portion thereof replaced and is thus disassembled when said rechargeable battery is subsequently re-restrained by said restraint member and thus reused, said measuring being based on said battery data detected after said rechargeable battery is re-restrained; and

an evaluation unit for evaluating from said battery parameter a value of said rechargeable battery reused, said battery parameter at least including an internal resistance of said rechargeable battery.

2. The value calculation device for a rechargeable battery according to claim 1, further comprising a second measurement unit for measuring said battery parameter of one of said rechargeable battery and said battery cell before said rechargeable battery is re-restrained, said measuring being based on said battery data detected before said rechargeable battery is re-restrained, wherein:

said battery parameter includes a first parameter measured by said first measurement unit and a second parameter measured by said second measurement unit;

said first parameter includes said internal resistance; and

said second parameter includes a full charge capacity of said rechargeable battery.

3. The value calculation device for a rechargeable battery according to claim 1, wherein:

said rechargeable battery is a rechargeable lithium ion battery;

said first measurement unit includes

a degradation parameter acquisition unit operative to perform a degradation diagnosis based on an open circuit voltage characteristic of said rechargeable lithium ion battery indicating how said rechargeable lithium ion battery varies in open circuit voltage as said rechargeable lithium ion battery varies in capacity to obtain a capacity ratio of a positive electrode of said rechargeable lithium ion battery, a capacity ratio of a negative electrode of said rechargeable lithium ion battery, and a battery capacity fluctuation amount, and

a lithium deposition estimation unit operative to apply said capacity ratios respectively of said positive and negative electrodes that are obtained to a previously obtained correspondence between said capacity ratios respectively of said positive and negative electrodes and a first amount of said battery capacity fluctuation amount to separate said battery capacity fluctuation amount that is obtained into said first amount and a second amount of said battery capacity fluctuation amount, said first amount corresponding to degradation attributed to wear, said second amount corresponding to degradation attributed to deposition of lithium; and

one of said battery parameter and said first parameter includes said second amount.

4. The value calculation device for a rechargeable battery according to claim 2, wherein:

said rechargeable battery is a rechargeable lithium ion battery;

said second measurement unit includes

a degradation parameter acquisition unit operative to perform a degradation diagnosis based on an open circuit voltage characteristic of said rechargeable lithium ion battery indicating how said rechargeable lithium ion battery varies in open circuit voltage as said rechargeable lithium ion battery varies in capacity to obtain a capacity ratio of a positive electrode of said rechargeable lithium ion battery, a capacity ratio of a negative electrode of said rechargeable lithium ion battery, and a battery capacity fluctuation amount, and

a lithium deposition estimation unit operative to apply said capacity ratios respectively of said positive and negative electrodes that are obtained to a previously obtained correspondence between said capacity ratios respectively of said positive and negative electrodes and a first amount of said battery capacity fluctuation amount to separate said battery capacity fluctuation amount that is obtained into said first amount and a second amount of said battery capacity fluctuation amount, said first amount corresponding to degradation attributed to wear, said second amount corresponding to degradation attributed to deposition of lithium; and

said second parameter includes said second amount.

9. The value calculation device for a rechargeable battery according to claim 2, wherein:

said rechargeable battery is a rechargeable lithium ion battery;

said first measurement unit includes

a degradation parameter acquisition unit operative to perform a degradation diagnosis based on an open circuit voltage characteristic of said rechargeable lithium ion battery indicating how said rechargeable lithium ion battery varies in open circuit voltage as said rechargeable lithium ion battery varies in capacity to obtain a capacity ratio of a positive electrode of said rechargeable lithium ion battery, a capacity ratio of a negative electrode of said rechargeable lithium ion battery, and a battery capacity fluctuation amount, and

a lithium deposition estimation unit operative to apply said capacity ratios respectively of said positive and negative electrodes that are obtained to a previously obtained correspondence between said capacity ratios respectively of said positive and negative electrodes and a first amount of said battery capacity fluctuation amount to separate said battery capacity fluctuation amount that is obtained into said first amount and a second amount of said battery capacity fluctuation amount, said first amount corresponding to degradation attributed to wear, said second amount corresponding to degradation attributed to deposition of lithium; and

one of said battery parameter and said first parameter includes said second amount.

5. A value calculation method for a rechargeable battery used with a plurality of battery cells restrained by a restraint member, comprising the steps of:

detecting battery data after said rechargeable battery has said restraint member removed therefrom and is thus disassembled and the plurality of battery cells has a portion thereof replaced and when said rechargeable battery is subsequently re-restrained by said restraint member and thus reused, said battery data being detected as said rechargeable battery is electrically charged and discharged;

measuring a battery parameter of said rechargeable battery after said rechargeable battery is re-restrained; and

an evaluating a value of said rechargeable battery reused, said evaluating being based on said battery parameter measured in the step of measuring,

said battery parameter at least including an internal resistance of said rechargeable battery.

6. The value calculation method for a rechargeable battery according to claim 5, further comprising the step of measuring said battery parameter of one of said rechargeable battery and said battery cell before said rechargeable battery is re-restrained, said measuring being based on said battery data detected before said rechargeable battery is re-restrained, wherein:

said battery parameter includes a first parameter measured in the step of measuring after said rechargeable battery is re-restrained and a second parameter measured in the step of measuring before said rechargeable battery is re-restrained;

said first parameter includes said internal resistance; and

said second parameter includes a full charge capacity of said rechargeable battery.

7. The value calculation method for a rechargeable battery according to claim 5, wherein:

said rechargeable battery is a rechargeable lithium ion battery;

the step of measuring after said rechargeable battery is re-restrained includes the steps of

performing a degradation diagnosis based on an open circuit voltage characteristic of said rechargeable lithium ion battery indicating how said rechargeable lithium ion battery varies in open circuit voltage as said rechargeable lithium ion battery varies in capacity to obtain a capacity ratio of a positive electrode of said rechargeable lithium ion battery, a capacity ratio of a negative electrode of said rechargeable lithium ion battery, and a battery capacity fluctuation amount, and

applying said capacity ratios respectively of said positive and negative electrodes that are obtained to a previously obtained correspondence between said capacity ratios respectively of said positive and negative electrodes and a first amount of said battery capacity fluctuation amount to separate said battery capacity fluctuation amount that is obtained into said first amount and a second amount of said battery capacity fluctuation amount, said first amount corresponding to degradation attributed to wear, said second amount corresponding to degradation attributed to deposition of lithium; and

one of said battery parameter and said first parameter includes said second amount.

8. The value calculation method for a rechargeable battery according to claim 6, wherein:

said rechargeable battery is a rechargeable lithium ion battery;

the step of measuring before said rechargeable battery is re-restrained includes the steps of

performing a degradation diagnosis based on an open circuit voltage characteristic of said rechargeable lithium ion battery indicating how said rechargeable lithium ion battery varies in open circuit voltage as said rechargeable lithium ion battery varies in capacity to obtain a capacity ratio of a positive electrode of said rechargeable lithium ion battery, a capacity ratio of a negative electrode of said rechargeable lithium ion battery, and a battery capacity fluctuation amount, and

applying said capacity ratios respectively of said positive and negative electrodes that are obtained to a previously obtained correspondence between said capacity ratios respectively of said positive and negative electrodes and a first amount of said battery capacity fluctuation amount to separate said battery capacity fluctuation amount that is obtained into said first amount and a second amount of said battery capacity fluctuation amount, said first amount corresponding to degradation attributed to wear, said second amount corresponding to degradation attributed to deposition of lithium; and

said second parameter includes said second amount.

10. The value calculation method for a rechargeable battery according to claim 6, wherein:

said rechargeable battery is a rechargeable lithium ion battery;

the step of measuring after said rechargeable battery is re-restrained includes the steps of

performing a degradation diagnosis based on an open circuit voltage characteristic of said rechargeable lithium ion battery indicating how said rechargeable lithium ion battery varies in open circuit voltage as said rechargeable lithium ion battery varies in capacity to obtain a capacity ratio of a positive electrode of said rechargeable lithium ion battery, a capacity ratio of a negative electrode of said rechargeable lithium ion battery, and a battery capacity fluctuation amount, and

applying said capacity ratios respectively of said positive and negative electrodes that are obtained to a previously obtained correspondence between said capacity ratios respectively of said positive and negative electrodes and a first amount of said battery capacity fluctuation amount to separate said battery capacity fluctuation amount that is obtained into said first amount and a second amount of said battery capacity fluctuation amount, said first amount corresponding to degradation attributed to wear, said second amount corresponding to degradation attributed to deposition of lithium; and

one of said battery parameter and said first parameter includes said second amount.