Thermally conductive nanocomposition and method of making the same

• US 8,840,803 B2
• Filed: 02/02/2012
• Issued: 09/23/2014
• Est. Priority Date: 02/02/2012
• Status: Expired due to Fees

• Current Assignee: Baker Hughes Incorporated (Baker Hughes Company)
• Original Assignee: Baker Hughes Incorporated (Baker Hughes Company)
• Inventors: Mazyar, Oleg A., Leonard, Ashley, Falkner, Joshua C.
• Primary Examiner(s): Green, Anthony J
• Application Number:
  US13/364,515
• Publication Number:
  US 20130200299A1
• Time in Patent Office: 964 Days
• Field of Search: 252/70, 252/71, 252/73, 252/74, 252/75, 252/77, 252/78.1, 977/948, 977/734, 977/742, 977/755, 977/762, 977/773, 977/775, 977/776, 977/779, 977/784, 977/785, 977/786, 977/831, 977/833, 62/64, 83/15, 165/104.11, 165/104.21, 166/302, 175/17, 219/68, 451/28, 451/36, 451/53
• US Class Current: 252/71
• CPC Class Codes: B26D 7/08 Means for treating work or cutting member to facilitate cutting tensioning band cutters B26D1/48
• CPC Class Codes: B62D 7/08 the pivotal axes being situated in a single plane transverse to the longitudinal centre line of the vehicle
• CPC Class Codes: C09K 5/10 Liquid materials
• CPC Class Codes: C09K 5/14 Solid materials, e.g. powdery or granular
• CPC Class Codes: E21B 43/128 Adaptation of pump systems with down-hole electric drives
• CPC Class Codes: F16J 15/02 between relatively-stationary surfaces F16J15/46, F16J15/48 take precedence
• CPC Class Codes: Y10T 83/041 By heating or cooling

Abstract

A nanocomposite fluid includes a fluid medium; and a nanoparticle composition comprising nanoparticles which are electrically insulating and thermally conductive. A method of making the nanocomposite fluid includes forming boron nitride nanoparticles; dispersing the boron nitride nanoparticles in a solvent; combining the boron nitride nanoparticles and a fluid medium; and removing the solvent.

Claims

1. A nanocomposite fluid comprising:

a fluid medium; and

a nanoparticle composition comprising nanoparticles which are electrically insulating and thermally conductive, and comprise boron nitride;

wherein the thermal conductivity of the nanocomposite fluid is about 0.2 W/m K to about 1 W/m K,

the nanocomposite fluid has a dielectric strength of at least about 80 kV/cm; and

the viscosity of the nanocomposite fluid is about 1 cps to about 5 cps.

2. The nanocomposite fluid of claim 1, wherein the boron nitride is derivatized with a functional group.

3. The nanocomposite fluid of claim 2, wherein the functional group is an alkyl group, hydroxyl group, or a combination comprising at least one of the foregoing.

4. The nanocomposite fluid of claim 1, wherein the nanoparticle is a nanotube, nanosphere, nanosheet, nanowire, nanorod, or a combination comprising at least one of the foregoing.

5. The nanocomposite fluid of claim 4, wherein the nanoparticle is the nanotube which has an aspect ratio of about 10 to about 400.

6. The nanocomposite fluid of claim 4, wherein the nanoparticle is the nanosphere which has a diameter of about 5 nm to about 800 nm.

7. The nanocomposite fluid of claim 1, wherein the fluid medium comprises de-ionized water, oil, synthetic oil, distillate oil, or a combination comprising at least one of the foregoing.

8. The nanocomposite fluid of claim 1, wherein the nanoparticle composition includes boron nitride nanotubes and boron nitride nanospheres.

9. The nanocomposite of claim 8, wherein the boron nitride nanotubes are present in an amount of about 0.001 wt % to about 10 wt %, the boron nitride nanospheres are present in an amount of about 0.001 wt % to about 10 w %, based on the weight of the nanocomposite fluid.

10. The nanocomposite fluid of claim 1, further comprising boron nitride microparticles.

11. The nanocomposite fluid of claim 1, further comprising an non-ionic surfactant.

12. The nanocomposite fluid of claim 11, wherein the non-ionic surfactant is a fatty alcohol, polyoxyethylene glycol alkyl ether, polyoxypropylene glycol alkyl ether, glucoside alkyl ether, polyoxyethylene glycol octylphenol ether, polyoxyethylene glycol alkylphenol ether, glycerol alkyl ester, polyoxyethylene glycol sorbitan alkyl ester, sorbitan alkyl ester, cocamide ethanolamine, amine oxide, block copolymer comprising polyethylene glycol and polypropylene glycol, polyethoxylated amine, or a combination comprising at least one of the foregoing.

13. The nanocomposite fluid of claim 1, further comprising a solvent, wherein the solvent is not the same as the fluid medium.

14. The nanocomposite fluid of claim 1, further comprising an additive nanoparticle including functionalized carbon nanotubes, functionalized fullerenes, nanodiamonds, functionalized graphene, polysilsesquioxanes, inorganic nanoparticles, nanoclays, or a combination comprising at least one of the foregoing.

15. The nanocomposite fluid of claim 1, wherein the nanoparticle is present in an amount of about 0.01 wt % to about 10 wt %, based on the weight of the nanocomposite fluid.

16. The nanocomposite fluid of claim 1, wherein the fluid medium is present in an amount of about 20 wt % to about 99.99 wt %, based on the weight of the nanocomposite fluid.

17. The nanocomposite fluid of claim 1, wherein the nanoparticles have a thermal conductivity of about 150 W/m K to about 8000 W/m K.

18. The nanocomposite fluid of claim 1, wherein the fluid medium comprises natural oil, synthetic oil, distillate oil, or a combination comprising at least one of the foregoing.

19. The nanocomposite fluid of claim 1, wherein the nanoparticles comprises boron nitride nanotubes and an additive nanoparticle comprising functionalized carbon nanotubes, functionalized fullerenes, nanodiamonds, functionalized graphene, polysilsesquioxanes, inorganic nanoparticles, nanoclays, or a combination comprising at least one of the foregoing, wherein the additive nanoparticle comprises single or multi-walled nanotubes, spheres, balls, platelets, sheets, ribbons, or annular shapes.

20. The nanocomposite fluid of claim 19, wherein the additive nanoparticle comprises spheres.

28. A method for cutting a workpiece, comprising:

disposing an electrode proximate to and spaced apart from the workpiece;

disposing the nanocomposite fluid of claim 1 between the electrode and the workpiece; and

passing an electric discharge through the nanocomposite fluid to cut the workpiece.

29. The method of claim 28, further comprising moving the electrode to a new position of the workpiece.

30. A process for cooling a downhole element, comprising:

disposing the nanocomposite fluid of claim 1 downhole; and

contacting the downhole element with the nanocomposite fluid to cool the downhole element.

31. The process of claim 30, further comprising:

circulating the nanocomposite fluid downhole; and

contacting the nanocomposite fluid with a heat exchanger to decrease the temperature of the nanocomposite fluid.

32. The process of claim 30, wherein the downhole element is a transformer, motor, pump, resistive heater, induction heater, drill bit, sensor, current source, or a combination comprising at least one of the foregoing.

21. A method of making a nanocomposite fluid, comprising:

forming nanoparticles which are electrically insulating and thermally conductive, the nanoparticles being comprised of boron nitride;

suspending the nanoparticles in a solvent, surfactant, or a combination comprising at least one of the foregoing; and

combining the nanoparticles and a fluid medium,

wherein, when present, the solvent is removed after combining the nanoparticles and the fluid medium to form the nanocomposite fluid,

wherein the thermal conductivity of the nanocomposite fluid is about 0.2 W/m K to about 1 W/m K,

the nanocomposite fluid has a dielectric strength of at least about 80 kV/cm; and

the viscosity of the fluid is about 1 cps to about 5 cps.

22. The method of claim 21, wherein the solvent has a boiling point which is less than 120°

C.

23. The method of claim 22, wherein the solvent includes acetone, dichloromethane, tetrahydrofuran, ethyl acetate, acetonitrile, methanol, ethanol, propanol, water, or a combination comprising at least one of the foregoing.

24. The method of claim 21, wherein the method is performed at a temperature which is less than about 30°

C.

25. The method of claim 21, wherein the method is performed at a pressure which is less than 1 atmosphere (101,325 pascals).

26. The method of claim 21, wherein the fluid medium is an oil or de-ionized water.

27. A method of making a nanocomposite fluid, comprising:

forming nanoparticles which are electrically insulating and thermally conductive, and comprises boron nitride;

suspending the nanoparticles in a solvent, surfactant, or a combination comprising at least one of the foregoing; and

combining the nanoparticles and a fluid medium,

wherein, when present, the solvent is removed after combining the nanoparticles and the fluid medium to form the nanocomposite fluid; and

wherein the nanoparticles comprises a coating disposed on the nanoparticle.

33. A nanocomposite fluid comprising:

a fluid medium; and

a nanoparticle composition comprising boron nitride, wherein the boron nitride is derivatized to include an alkyl group or coated with a coating comprising a metal boride, a metal carbide, a metal nitride, a metal carbonate, a metal bicarbonate, or combinations thereof.

34. The nanocomposite fluid of claim 33, wherein the boron nitride is derivatized to include a C2-C100 alkyl group.