Borophosphate, borate phosphate, and metal borophosphate as novel flame proofing additives for plastics

• US 8,841,373 B2
• Filed: 07/01/2010
• Issued: 09/23/2014
• Est. Priority Date: 07/02/2009
• Status: Expired due to Fees

• Current Assignee: BASF SE
• Original Assignee: BASF SE
• Inventors: Ewald, Bastian, Hibst, Hartmut
• Primary Examiner(s): SZEKELY, PETER A
• Application Number:
  US13/381,789
• Publication Number:
  US 20120108713A1
• Time in Patent Office: 1,545 Days
• Field of Search: 524/405, 524/415
• US Class Current: 524/405
• CPC Class Codes: C08K 2201/014 Additives containing two or more different additives of the same subgroup in C08K
• CPC Class Codes: C08K 3/38 Boron-containing compounds
• CPC Class Codes: C09K 21/04 containing phosphorus

Abstract

The present invention relates to a mixture comprising at least one plastic K and from 0.1 to 50% by weight, based on the entire mixture, of at least one compound A selected from the group consisting of borophosphates, borate phosphates, metalloborophosphates, and mixtures thereof, to a process for the production of said mixture, and to the use of said mixture as flame retardant.

Claims

1. A mixture comprising at least one plastic K and from 0.1 to 30% by weight, based on the entire mixture, and at least one compound A which is a metalloborophosphate selected from the group consisting of NH₄[ZnBP₂O₈], Rb[ZnBP₂O₈], Cs[ZnBP₂O₈], NH₄[(Zn_1-xCo_x)BP₂O₈] (x=0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1.0), Na[ZnBP₂O₈].H₂O, (C₄N₃H₁₆)[Zn₃B₃P₆O₂₄].H₂O, (C₆N₄H₂₂)_1.5[Zn₆B₆P₁₂O₄₈].1.5H₂O, NH₄[ZnBP₂O₈], K[ZnBP₂O₈], [MBP₂O₈] (M=B, Al, Ga), and mixtures thereof.

2. The mixture according to claim 1, wherein the at least one plastic K is selected from the group consisting of polyoxymethylene homo- or copolymers, polycarbonates, polyesters, polyolefins, poly(meth)acrylates, polyamides, vinylaromatic polymers, polyarylene ethers, epoxy resins and mixtures thereof.

3. The mixture according to claim 1 further comprising at least one additional flame retardant selected from the group consisting of phosphorous containing compounds, nitrogen containing compounds, metal hydroxides, metal oxides, boron comprising compounds, silicates, silicon dioxide, sulfates, carbonates and mixtures thereof.

4. The mixture according to claim 3, wherein the at least one additional flame retardant is selected from the group consisting of triphenyl phosphine oxide, aluminum triethylphospinate, zinc diethylphosphonate, melamine cyanurate, melamine phosphate, melamine polyphosphate, melamine pyrophosphate, melaminammoniumpolyphosphate, melaminammoniumpyrophosphate, melaminborate, triphenylphosphate, resorcinol-bis-(diphenylphosphate), bis-phenol-A-bis-diphenylphosphate, resorcinol-bis-(2,6-dixylylene phosphate), aluminum hydroxide, aluminum oxide hydroxide, magnesium dihydroxide, zinc oxide, molybdenum trioxide, antimony oxide, aluminum trihydroxide, zinc borate, calcium silicate, magnesium silicate, calcium sulfate, magnesium carbonate, dihydroxaphosphaphenanthrene, dihydroxaphosphaphenanthrene-hydorchinone, potassium-diphenyl-sulfonsulfonate, polymethylphenylsiloxane, potassium-butylperfluorosulfonate and mixtures thereof.

5. The mixture according to claim 1 further comprising an antidripping agent.

6. A process for the production of a mixture according to claim 1 which comprises mixing the at least one plastic K with at least one compound A.

7. The mixture according to claim 1, wherein said at least one component A is from 1 to 30% by weight, based on the entire mixture.

8. The mixture according to claim 1, wherein said at least one component A is from 2 to 15% by weight, based on the entire mixture.

9. The mixture according to claim 1, wherein at least one plastic K in the mixture is from 50 to 99% by weight based on the entire mixture.

10. The mixture according to claim 1, wherein at least one plastic K in the mixture is from 85 to 98% by weight based on the entire mixture.