Golf ball cores based on polyalkenamer rubber having positive hardness gradients

• US 8,845,457 B2
• Filed: 08/12/2010
• Issued: 09/30/2014
• Est. Priority Date: 11/28/2001
• Status: Expired due to Fees

• Current Assignee: Acushnet Company (FILA Holdings Corp.)
• Original Assignee: Acushnet Company (FILA Holdings Corp.)
• Inventors: Comeau, Brian, Bulpett, David A., Sullivan, Michael J., Blink, Robert, Goguen, Douglas S., Binette, Mark L.
• Primary Examiner(s): Kim, Gene
• Assistant Examiner(s): SIMMS JR, JOHN ELLIOTT
• Application Number:
  US12/855,319
• Publication Number:
  US 20100323819A1
• Time in Patent Office: 1,510 Days
• Field of Search: None
• US Class Current: 473/374
• CPC Class Codes: A63B 37/0003 Golf balls
• CPC Class Codes: A63B 37/0051 Materials other than polybutadienes; Constructional details
• CPC Class Codes: A63B 37/00621 Centre hardness
• CPC Class Codes: A63B 37/00622 Surface hardness
• CPC Class Codes: A63B 37/0063 Hardness gradient
• CPC Class Codes: A63B 37/0064 Diameter
• CPC Class Codes: A63B 37/0066 Density; Specific gravity
• CPC Class Codes: A63B 37/0075 Three piece balls, i.e. cover, intermediate layer and core
• CPC Class Codes: A63B 37/02 Special cores balls with finger holes A63B37/0001, golf ball cores A63B37/005
• CPC Class Codes: A63B 37/06 Elastic cores
• CPC Class Codes: C08K 5/0025 Crosslinking or vulcanising agents; including accelerators
• CPC Class Codes: C08K 5/098 Metal salts of carboxylic acids
• CPC Class Codes: C08K 5/14 Peroxides

Abstract

Golf balls having a core comprising a polyalkenamer rubber composition are provided. The rubber composition may further include other rubbers such as, for example, polybutadiene, polyisoprene, ethylene propylene rubber, ethylene propylene diene rubber, and styrene-butadiene rubber. The rubber composition helps improve resiliency of the core and provides the ball with a comfortable and soft feel. In one version, a solid, single core having an outer surface and geometric center is provided, wherein the outer surface has a hardness greater than the hardness of the geometric center to define a positive hardness gradient of at least 10 Shore C. In a second version, a dual-core having an inner core and surrounding outer core layer is provided. The inner core has a positive hardness gradient, while the outer core has a zero; negative; or positive hardness gradient.

Claims

1. A golf ball, comprising a solid, single core having an outer surface and a geometric center, the core being formed from a rubber composition, the rubber composition comprising a cycloalkene rubber having a trans-bond content of 55% or greater and a melting point of 30°

C. or greater in an amount of 80 weight percent, and polybutadiene rubber having a cis-bond content of at least 40% in an amount of 20 weight percent, and peroxide in an amount of 2.5 phr or greater based on weight of the cycloalkene rubber, wherein the geometric center and the outer surface each has a hardness, the hardness of the outer surface being greater than the hardness of the geometric center to define a positive hardness gradient of at least 10 Shore C units; and

a cover layer surrounding the core.

2. The golf ball of claim 1, wherein the cycloalkene rubber has a trans-content of 75% or greater and a melting point of 50°

C. or greater.

3. The golf ball of claim 1, wherein the diameter of the core is from 1.51 to 1.59 inches.

4. The golf ball of claim 1, wherein the hardness of the center is in the range of 50 to 80 Shore C units.

5. The golf ball of claim 1, wherein the hardness of the center is in the range of 55 to 75 Shore C units.

6. The golf ball of claim 1, wherein the hardness of the outer surface is at least 70 Shore C units.

7. The golf ball of claim 1, wherein the hardness of the outer surface is in the range of 80 to 95 Shore C units.

8. The golf ball of claim 1, wherein the hardness of the outer surface is 80 to 95 Shore C units and the hardness of the center is 50 to 60 Shore C units.

9. The golf ball of claim 1, wherein the positive hardness gradient is at least 25 Shore C units.

10. The golf ball of claim 1, wherein the cover layer comprises an inner cover layer and an outer cover layer.

11. The golf ball of claim 10, wherein the outer cover layer has a material hardness less than the inner cover layer.