Methods and configurations for H2S concentration in acid gas removal

• US 8,845,788 B2
• Filed: 08/07/2012
• Issued: 09/30/2014
• Est. Priority Date: 08/08/2011
• Status: Active Grant

• Current Assignee: Fluor Technologies Corporation (Fluor Corporation)
• Original Assignee: Fluor Technologies Corporation (Fluor Corporation)
• Inventors: Mak, John
• Primary Examiner(s): Smith, Duane
• Assistant Examiner(s): HALL, CABRENA L
• Application Number:
  US13/569,069
• Publication Number:
  US 20130036911A1
• Time in Patent Office: 784 Days
• Field of Search: 952/35, 952/36, 96243-371
• US Class Current: 95/173
• CPC Class Codes: B01D 2252/20489 with two or more hydroxyl groups
• CPC Class Codes: B01D 2256/00 Main component in the product gas stream after treatment
• CPC Class Codes: B01D 2256/22 Carbon dioxide
• CPC Class Codes: B01D 2257/304 Hydrogen sulfide
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1462 Removing mixtures of hydrogen sulfide and carbon dioxide
• CPC Class Codes: C10K 1/08 by washing with liquids; Reviving the used wash liquors gas washers B01D
• CPC Class Codes: C10K 3/04 reducing the carbon monoxide content , e.g. water-gas shift [WGS]
• CPC Class Codes: Y02P 20/151 Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Abstract

A syngas treatment plant is configured to remove sulfurous compounds from syngas in a configuration having two flash stages for a physical solvent to so enrich the acid gas to at least 40 mol % H2S or higher as required by the Claus unit and to flash and recycle CO2 back to the syngas feed. Contemplated methods and configurations advantageously remove sulfur to less than 10 ppmv while increasing H2S selectivity at high pressure operation to thereby allow production of an H2S stream that is suitable as feed gas to a Claus plant.

Claims

1. A method of treating an H2S- and CO2-containing syngas, comprising:

absorbing in an absorber at syngas pressure H2S and CO2 from the H2S- and CO2-containing syngas using a lean physical solvent to so form a treated CO2-containing syngas and a rich solvent comprising H2S and CO2, wherein the lean physical solvent is a H2S selective physical solvent;

heating and flashing the rich solvent comprising H2S and CO2 in at least two successive flash stages to produce respective flash gases enriched in CO2 and respective flashed rich solvents comprising H2S, wherein the step of heating the rich solvent in the at least two stages uses heat from the lean solvent;

cooling the flash gases to form respective cooled flash gases and respective condensate streams, recycling the flash gases enriched in CO2 to the syngas or absorber and feeding the condensate streams into a stripper; and

regenerating the condensate streams and the flashed rich solvent comprising H2S in the stripper to so form the lean physical solvent and an H2S rich acid gas stream that has a CO2 content of at least 30 mol % and an H2S to CO2 ratio of at least 1.1;

1.

2. The method of claim 1 wherein the step of absorbing is performed at a pressure of between 400 psig and 900 psig.

3. The method of claim 1 wherein the step of heating the rich solvent is performed in heat exchangers having a temperature approach of 20°

F. or less.

4. The method of claim 1 wherein the step of recycling further comprises a step of compressing the flash gases enriched in CO2.

5. The method of claim 1 wherein the H2S- and CO2-containing syngas is a shifted syngas.

6. The method of claim 1 wherein the H2S- and CO2-containing syngas has a molar ratio of CO2 to H2S of at least 10:

1.

7. The method of claim 1 wherein the treated CO2-containing syngas has an H2S concentration of equal or less than 10 ppmv.

8. The method of claim 1 wherein the treated CO2-containing syngas has a reduced CO2 content relative to that of the H2S- and CO2-containing syngas.

9. The method of claim 1 wherein the H2S rich acid gas stream has an H2S content of at least 40 mol %.

10. The method of claim 1 wherein the H2S rich acid gas stream contains a higher molar fraction of H2S relative to CO2.

11. The method of claim 1 wherein the flashed rich solvent comprising H2S has a CO2 to H2S molar ratio of equal or less than 1.0 where the H2S- and CO2-containing syngas is a shifted syngas.

12. The method of claim 1 wherein the flashed rich solvent comprising H2S has a CO2 to H2S molar ratio of equal or less than 0.6 where the H2S- and CO2-containing syngas is an unshifted syngas.

13. The method of claim 1 wherein the rich solvent comprising H2S has a CO2 to H2S molar ratio of equal or less than 5.0 where the H2S- and CO2-containing syngas is a shifted syngas.

14. The method of claim 1 wherein the rich solvent comprising H2S has a CO2 to H2S molar ratio of equal or less than 2.0 where the H2S- and CO2-containing syngas is an unshifted syngas.