Toner making process

• US 8,858,896 B2
• Filed: 01/14/2013
• Issued: 10/14/2014
• Est. Priority Date: 01/14/2013
• Status: Active Grant

• Current Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Original Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Inventors: Liu, Yu, Wang, Yulin, Lee, Frank Ping-Hay, Zhou, Ke, Qiu, Shigang S.
• Primary Examiner(s): EGWIM, KELECHI CHIDI
• Application Number:
  US13/741,278
• Publication Number:
  US 20140200298A1
• Time in Patent Office: 638 Days
• Field of Search: 422/305, 422/129, 422/306, 430/137.4, 524/99
• US Class Current: 422/305
• CPC Class Codes: C08K 5/05 Alcohols; Metal alcoholates
• CPC Class Codes: C08K 5/07 Aldehydes; Ketones

Abstract

Processes for making toners, and in particular, emulsion aggregation (EA) toners. These toners exhibit a low melt temperature while simultaneously exhibiting excellent relative humidity sensitivity regarding charging properties. In embodiments, the process comprises the preparation of the latex emulsion comprising high ratio resin compositions by injection of steam and neutralization agent vapors into the latex emulsion.

Claims

1. A process for making a latex emulsion comprising:

mixing at least one resin with an organic solvent to form a resin composition;

generating neutralization agent vapors;

combining the neutralization agent vapors with steam; and

exposing the resin composition to the combination of the neutralization agent vapors and steam to initiate emulsification of the resin composition to form a latex emulsion.

2. The process of claim 1, wherein the neutralization agent is further vaporized by contact with the steam.

3. The process of claim 1, wherein the neutralizing agent is selected from the group consisting of ammonium hydroxide, sodium carbonate, potassium hydroxide, sodium hydroxide, sodium bicarbonate, lithium hydroxide, potassium carbonate, triethyl amine, triethanolamine, pyridine, pyridine derivatives, diphenylamine, diphenylamine derivatives, poly(ethylene amine), poly(ethylene amine) derivatives, amine bases and piperazine, and mixtures thereof.

4. The process of claim 1, wherein the resin is selected from the group consisting of polyester, polyacrylate, polyolefin, polystyrene, polycarbonate, polyamide, polyimide, and mixtures thereof.

5. The process of claim 4, wherein the polyester resin is selected from the group consisting of amorphous resins, crystalline resins, and mixtures thereof.

6. The process of claim 1, wherein a ratio of the neutralization agent in the latex emulsion is from about 25% to about 500%.

7. The process of claim 1, wherein the resin is present in the resin composition in an amount of from about 1% to about 99% by weight of the total weight of the resin composition.

8. The process of claim 1, wherein the neutralization agent vapors and steam is mixed in a weight ratio of from about 1:

100 to about 10;

1.

9. The process of claim 1, wherein a temperature of the steam is from about about 80°

C. to about 150°

C.

10. The process of claim 1, wherein a pressure of the steam introduced to the resin composition is from 0.04 bar to about 4.76 bar.

11. The process of claim 1, wherein the latex emulsion has an average particle size from about 5 nm to about 1000 nm.

12. The process of claim 1, wherein the organic solvent is selected from the group consisting of ketone, alcohol, ester, ether, and mixtures thereof.

13. A process for making a toner comprising:

mixing at least one polyester resin with a solvent to form a resin composition;

generating neutralization agent vapors;

combining the neutralization agent vapors with steam;

exposing the resin composition to the combination of the neutralization agent vapors and steam to initiate emulsification of the resin composition to form a latex emulsion;

forming a pre-toner mixture by mixing the latex emulsion with an optional colorant, and an optional wax;

aggregating particles from the pre-toner mixture; and

coalescing the aggregated particles to form toner particles.

14. The process of claim 13, wherein the neutralization agent vapor is further vaporized by contact with the steam.

15. The process of claim 13, wherein a neutralization ratio of the neutralization agent in the latex emulsion is from about 25% to about 500%.

16. The process of claim 13, wherein the resin is present in the resin composition in an amount of from about 1% to about 99% by weight of the total weight of the resin composition.

17. The process of claim 13, wherein the latex emulsion has an average particle size from about 5 nm to about 1000 nm.

18. The process of claim 13, wherein the resin is selected from the group consisting of polyester, polyacrylate, polyolefin, polystyrene, polycarbonate, polyamide, polyimide, and mixtures thereof.

19. The process of claim 13, wherein the neutralizing agent is selected from the group consisting of ammonium hydroxide, sodium carbonate, potassium hydroxide, sodium hydroxide, sodium bicarbonate, lithium hydroxide, potassium carbonate, triethyl amine, triethanolamine, pyridine, pyridine derivatives, diphenylamine, diphenylamine derivatives, poly(ethylene amine), poly(ethylene amine) derivatives, amine bases and pieprazine, and mixtures thereof.

20. An apparatus for preparing a latex or emulsion, comprising:

a reaction vessel for initiating emulsification,

a steam generator connected to the reaction vessel for providing steam to the reaction vessel; and

a source of neutralization agent liquid connected to the reaction vessel for providing neutralization agent vapors to the reaction vessel.