Polyacrylic acid (salt)-type water absorbent resin and method for producing of same
First Claim
1. A method for producing a polyacrylic acid (salt)-type water absorbent resin, comprising a step of preparing an aqueous monomer solution of an acrylic acid (salt), a step of continuously polymerizing the aqueous monomer solution, a step of finely shredding a hydrous gel-like crosslinked polymer during or after polymerization, a step of drying the obtained particulate hydrous gel-like crosslinked polymer, and a surface treatment step of adding and reacting a surface treatment agent to and with the dried water absorbent resin powder,wherein crosslinking reaction is carried out at a stirring power index of 3 to 15 W·
- hr/kg in a transverse type continuous stirring apparatus having stirring means including a feeding inlet and a discharging outlet of a water absorbent resin and one or more rotary shafts having with a plurality of stirring discs, and heating means after the addition of the surface-crosslinking agent in the surface treatment step;
wherein
(stirring power index)=((power consumption of apparatus at the time surface treatment)−
(power consumption at the time of idling))×
average retention time)/(treatment amount per unit time×
average retention time).
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Abstract
A process for producing a water absorbent resin is provided with which it is possible to efficiently and inexpensively obtain a surface-crosslinked water-absorbing resin having excellent material properties, while ensuring high productivity. In continuous production scaled up to a large scale (in particular, 1 t/hr or more), the physical properties are improved and stabilized (for example, a reduction in standard deviation of the physical properties) by a surface crosslinking treatment to further improve absorption against pressure (AAP) and saline flow conductivity (SFC). The process for producing a polyacrylic acid (salt)-type water absorbent resin includes a surface treatment step in which after addition of a surface-crosslinking agent, a crosslinking reaction is conducted in a transverse type continuous stirring apparatus having stirring means including a feeding inlet and a discharging outlet of a water absorbent resin and one or more rotary shafts having with a plurality of stirring discs, and heating means, at a stirring-power index of the device of 3-15 W·hr/kg.
(Stirring-power index)=((power consumption of apparatus at the time surface treatment)−(power consumption at the time of idling))×average retention time)/(treatment amount per unit time×average retention time).
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Citations
17 Claims
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1. A method for producing a polyacrylic acid (salt)-type water absorbent resin, comprising a step of preparing an aqueous monomer solution of an acrylic acid (salt), a step of continuously polymerizing the aqueous monomer solution, a step of finely shredding a hydrous gel-like crosslinked polymer during or after polymerization, a step of drying the obtained particulate hydrous gel-like crosslinked polymer, and a surface treatment step of adding and reacting a surface treatment agent to and with the dried water absorbent resin powder,
wherein crosslinking reaction is carried out at a stirring power index of 3 to 15 W· - hr/kg in a transverse type continuous stirring apparatus having stirring means including a feeding inlet and a discharging outlet of a water absorbent resin and one or more rotary shafts having with a plurality of stirring discs, and heating means after the addition of the surface-crosslinking agent in the surface treatment step;
wherein
(stirring power index)=((power consumption of apparatus at the time surface treatment)−
(power consumption at the time of idling))×
average retention time)/(treatment amount per unit time×
average retention time). - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17)
- hr/kg in a transverse type continuous stirring apparatus having stirring means including a feeding inlet and a discharging outlet of a water absorbent resin and one or more rotary shafts having with a plurality of stirring discs, and heating means after the addition of the surface-crosslinking agent in the surface treatment step;
Specification