Coating formulations for optical elements

• US 8,864,898 B2
• Filed: 05/31/2011
• Issued: 10/21/2014
• Est. Priority Date: 05/31/2011
• Status: Expired due to Fees

• Current Assignee: Honeywell International Inc.
• Original Assignee: Honeywell International Inc.
• Inventors: Varaprasad, Desaraju, Korolev, Boris, Mukhopadhyay, Sudip
• Primary Examiner(s): Brunsman, David M
• Application Number:
  US13/149,281
• Publication Number:
  US 20120308725A1
• Time in Patent Office: 1,239 Days
• Field of Search: 106/287.1, 106/287.13, 106/287.14, 106/287.16
• US Class Current: 106/287.16
• CPC Class Codes: C09D 1/00 Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
• CPC Class Codes: C09D 183/02 Polysilicates
• CPC Class Codes: C09D 5/006 Anti-reflective coatings
• CPC Class Codes: C09D 7/20 Diluents or solvents
• CPC Class Codes: G02B 1/111 using layers comprising organic materials

Abstract

Anti-reflective coatings and coating formulations, optical elements and processes for preparing coating formulations and optical elements are described. The coating formulations are formed from at least one alkoxysilane material and at least one high boiling solvent. The coating formulation may be applied using roller coat processes.

Claims

1. A coating formulation comprising:

at least one alkoxysilane residue; and

at least 80 wt % of at least one solvent having a boiling point of at least 185°

C. at atmospheric pressure.

2. The coating formulation of claim 1 comprising at least 90 wt % of the at least one solvent.

3. The coating formulation of claim 1 wherein the coating formulation comprises less than 5 wt % of at least one solvent having a boiling point of less than 125°

C. at atmospheric pressure.

4. The coating formulation of claim 1 wherein the coating formulation comprises less than 5 wt % of at least one solvent having a boiling point of less than 150°

C. at atmospheric pressure.

5. The coating formulation of claim 1 wherein the coating formulation comprises less than 5 wt % of at least one solvent having a boiling point of less than 170°

C. at atmospheric pressure.

6. The coating formulation of claim 1 wherein the coating formulation comprises less than 5 wt % of at least one solvent having a boiling point of less than 185°

C. at atmospheric pressure.

7. The coating formulation of claim 1 comprising less than 10 wt % silicon dioxide solids concentration.

8. The coating formulation of claim 1 comprising less than 5 wt % silicon dioxide solids concentration.

9. The coating formulation of claim 1 comprising a tetraalkoxysilane residue.

10. The coating formulation of claim 9 wherein the at least one alkoxysilane residue comprises at least a second alkoxysilane residue selected from the group consisting of trialkoxysilane residues, dialkoxysilane residues, monoalkoxysilane residues, and combinations thereof.

11. The coating formulation of claim 1 further comprising at least one catalyst.

12. The coating formulation of claim 1 wherein the coating formulation comprises a pH of less than 5.

13. The coating formulation of claim 1 wherein the solvent comprises at least one alkylene glycol.

14. The coating formulation of claim 1 wherein the solvent is selected from at least one of ethylene glycol, propylene glycol, di(ethylene)glycol, tri(ethylene)glycol, tetra(ethylene)glycol, penta(ethylene)glycol, di(propylene)glycol, hexa(ethylene)glycol, and di(propylene)glycol methyl ether.

15. A coating formulation comprising:

at least one alkoxysilane residue;

at least about 50 wt % of at least one solvent having a boiling point of at least 125°

C. at atmospheric pressure; and

at least one polyol comprising at least one polyethylene or polycaprolactone polyol.

16. A method of forming an optical element comprising:

applying at least one layer of a coating formulation onto at least a portion of an optically transparent substrate, wherein the coating formulation comprises at least one alkoxysilane residue and at least 80 wt % of at least one solvent having a boiling point of at least 185°

C. at atmospheric pressure; and

heating the coating formulation to form a reflective coating on the optically transparent substrate.

17. The method of claim 16, wherein the applying step comprises roller coating the coating formulation onto at least a portion of an optically transparent substrate.

18. The method of claim 16 wherein the coating formulation is substantially free of solvent having a boiling point of less than 125°

C. at atmospheric pressure.

19. The method of claim 16 wherein the heating step comprises heating the coating formulation at from at least about 200°

C.

20. The method of claim 16 wherein the heating step further comprises heating the coating formulation at from at least about 400°

C.

21. The method of claim 16, wherein the heat step comprises initially heating the coating formulation at between about 200°

C. and 400°

C. and then subsequently heating the coating formulation at between about 400°

C. and 750°

C.

22. A method of producing a coating formulation, comprising:

combining at least one alkoxysilane, at least one catalyst and at least one solvent having a boiling point of at least 185°

C. at atmospheric pressure to form a coating formulation, wherein the coating formulation comprises at least 80 wt % of the at least one solvent.

23. The method of claim 22 wherein the coating formulation is substantially free of low boiling solvent having a boiling point of less than 125°

C. at atmospheric pressure.

24. The method of claim 22 wherein the catalyst comprises a base catalyst.

25. The method of claim 22 further comprises the steps of maintaining the pH of the coating formulation for a sufficient period of time at a sufficient temperature to form polymer particles and then reducing the pH of the coating formulation to less than about 5.0.

26. The method of claim 25, further comprising the step of adding an additional amount of solvent having a boiling point of at least 125°

C.

27. The method of claim 22, wherein the coating formulation comprises at least about 90 wt % of the at least one solvent.