Screen-less anode design concepts for low cost lithium electrochemical cells for use in implantable medical device applications

• US 8,871,379 B2
• Filed: 10/28/2010
• Issued: 10/28/2014
• Est. Priority Date: 10/30/2009
• Status: Active Grant

• Current Assignee: Greatbatch Limited (Greatbatch Incorporated)
• Original Assignee: Greatbatch Limited (Greatbatch Incorporated)
• Inventors: Gan, Hong
• Primary Examiner(s): Douyette, Kenneth
• Assistant Examiner(s): Lee, James
• Application Number:
  US12/914,254
• Publication Number:
  US 20110104542A1
• Time in Patent Office: 1,461 Days
• Field of Search: 429/7, 429121-347
• US Class Current: 429/178
• CPC Class Codes: H01M 4/06 Electrodes for primary cells
• CPC Class Codes: H01M 4/13 Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
• CPC Class Codes: H01M 4/40 Alloys based on alkali metals
• CPC Class Codes: H01M 4/75 Wires, rods or strips
• CPC Class Codes: H01M 6/16 with organic electrolyte H01M6/18 takes precedence
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y10T 29/49108 Electric battery cell making

Abstract

A new cathode design having a first cathode active material of a relatively low energy density but of a relatively high rate capability contacted to one side of a current collector and a second cathode active material having a relatively high energy density but of a relatively low rate capability contacted to the opposite side thereof is described. A preferred cathode is: SVO/current collector/CF_x with the CF_x facing a lithium anode body devoid of a screen-type current collector. The lithium anode is either supported directly on the inner casing sidewall or is contacted to a relatively small strip of metal devoid of perforations and serving as an anode current collector electrically connected to the negative terminal.

Claims

1. An electrochemical cell, which comprises:

a) a casing;

b) an anode comprising;

i) a body of lithium as an anode active material, the body comprising spaced apart front and back major lithium body faces extending to a sidewall defining an anode thickness; and

ii) a metal strip comprising an anode current collector, wherein the metal strip comprises spaced apart front and back major strip faces extending to and meeting with a metal strip edge, and wherein the metal, strip extends from at least one proximal metal strip portion to a distal metal strip portion having a distal metal strip end;

iii) wherein the spaced apart front and back major strip faces of the at least one proximal metal strip portion extend within respective front and back planes in the anode thickness between the front and back major lithium body faces, and

iv) wherein lithium directly contacts the front and back major strip faces and the metal strip edge of the at least one proximal metal strip portion, and

v) wherein the proximal metal strip portion contacted by lithium is devoid of perforations, and

vi) wherein the distal metal strip portion is electrically connected to an anode terminal; and

c) a cathode of at least one cathode active material contacted to at least one side of a cathode current collector;

d) a separator disposed between the anode and the cathode to prevent direct physical contact between them; and

e) a nonaqueous electrolyte activating the anode and the cathode housed inside the casing.

2. The electrochemical cell of claim 1 wherein the sidewall of the lithium body comprises spaced apart upper and lower lithium body edges defining an anode height, and right and left lithium body edges defining an anode width.

3. The electrochemical cell of claim 2 wherein the proximal metal strip portion extends into the lithium body from about 2% to about 100% of the anode height.

4. The electrochemical cell of claim 1 wherein a first longitudinal axis of the distal metal strip portion meets a second longitudinal axis of the at least one proximal metal strip portion at an angle ranging from 20°

to 160°

.

5. The electrochemical cell of claim 1 wherein the lithium body is not in contact with a casing sidewall.

6. The electrochemical cell of claim 1 wherein the metal strip comprising the anode current collector has either a uniform or non-uniform width along its length from a proximal end of the at least one proximal metal strip portion to the distal end of the distal metal strip portion.

7. The electrochemical cell of claim 1 wherein the casing is the anode terminal.

8. The electrochemical cell of claim 1 wherein the lithium is provided in an anode to cathode capacity ratio (A/C ratio) of from about 1.2 to about 5 based on a gram amount of the anode active material to the cathode active material.

9. The electrochemical cell of claim 1 wherein the cathode active material is selected from the group consisting of silver vanadium oxide (SVO), copper silver vanadium oxide (CSVO), V₂O₅, MnO₂, copper oxide, TiS₂, Cu₂S, FeS, FeS₂, copper vanadium oxide, CF_x, Ag₂O, Ag₂O₂, CuF, LiCoO₂, LiNiO₂, LiMnO₂, Ag₂CrO₄, and mixtures thereof.

10. The electrochemical cell of claim 2 wherein a width of the distal metal strip portion is from about 1% to about 20% of the anode width.

11. The electrochemical cell of claim 1 wherein the metal strip is substantially centered in the between the front and hack major lithium body faces.

12. An electrochemical cell, which comprises:

a) a casing;

b) an anode comprising;

i) lithium as an anode active material having spaced apart front and back major lithium body faces extending to a sidewall defining an anode thickness, wherein the sidewall comprises spaced apart upper and lower lithium body edges defining an anode height, and right and left lithium body edges defining an anode width; and

ii) a metal strip comprising an anode current collector, wherein the metal strip comprises spaced apart front and back major strip faces extending to and meeting with right and left strip edges, and wherein the metal strip extends from at least one proximal metal strip portion to a distal metal strip portion having a distal metal strip end;

iii) wherein the metal strip is substantially centered in the anode thickness with the spaced apart front and back major strip faces extending within respective front and back planes between the front and back major lithium body faces, and

iv) wherein lithium directly contacts the front and back major strip faces and the right and left strip edges at the proximal metal strip portion and part of the distal metal strip portion, but not the distal metal strip end, and

v) wherein the metal strip is devoid of perforations where it is contacted by lithium, and

vi) wherein the distal metal strip end is electrically connected to an anode terminal; and

c) a cathode comprising a first cathode active material and a second cathode active material, wherein the first cathode active material has a relatively low energy density but a relatively high rate capability with respect to the second cathode active material and is contacted to one side of a cathode current collector and wherein the second cathode active material has a relatively high energy density but a relatively low rate capability with respect to the first cathode active material and is contacted to the other side of the cathode current collector;

d) a separator disposed between the anode and the cathode to prevent direct physical contact between them; and

e) a nonagueous electrolyte activating the anode and the cathode housed inside the casing.

13. The electrochemical cell of claim 12 wherein a width of the distal metal strip portion is from about 1% to about 20% the anode width.

14. The electrochemical cell of claim 12 wherein the distal metal strip portion extends into the lithium body from about 2% to about 100% of the anode height.

15. The electrochemical cell of claim 12 wherein a first longitudinal axis of the distal metal strip portion meets a second longitudinal axis of the at least one proximal metal strip portion at an angle ranging from 20°

to 160°

.

16. The electrochemical cell of claim 12 wherein the cathode is provided in a configuration selected from the group consisting of

i) SVO/current collector/CF_x;

ii) SVO/current collector/SVO/CF_x;

iii) CF_x/SVO/current collector/SVO/CF_x; and

iv) SVO/CF_x/current collector/CF_x/SVO.

17. The electrochemical cell of claim 12 wherein the second cathode active material faces the anode.

18. The electrochemical cell of claim 12 wherein the lithium is provided in an anode to cathode capacity ratio (A/C ratio) from about 1.2 to about 5 based on a gram amount of the anode active material to the total gram amounts of the first and second cathode active materials.

19. The electrochemical cell of claim 12 wherein the anode and cathode are electrochemically associated with each other in a configuration of

anode/[separator/cathode/separator/anode]_n, wherein n≧

1.

20. The electrochemical cell of claim 12 wherein a casing sidewall serves as the anode terminal for an electrode assembly having a configuration of:

casing sidewall/anode/separator/cathode/separator/anode/separator/casing sidewall.

21. The electrochemical cell of claim 12 wherein the first cathode active material is selected from the group consisting of silver vanadium oxide (SVO), copper silver vanadium oxide (CSVO), V₂O₅, MnO₂, LiCoO₂, LiNiO₂, LiMnO₂, TiS₂, Cu₇S, FeS, FeS₂, copper oxide, copper vanadium oxide, and mixtures thereof, and the second cathode active material is selected from the group consisting of CF_x, Ag₂O, Ag₂O₂, CuF, Ag₂CrO₄, MnO₂, SVO, and mixtures thereof.

22. The electrochemical cell of claim 12 wherein the cathode current collector is selected from the group consisting of stainless steel, titanium, tantalum, platinum, gold, aluminum, cobalt nickel alloys, highly alloyed ferritic stainless steel containing molybdenum and chromium, and nickel-, chromium-, and molybdenum-containing alloys, and if titanium, it has a coating selected from the group consisting of graphite/carbon material, iridium, iridium oxide and platinum provided thereon.

23. The electrochemical cell of claim 12 wherein the electrolyte has a first solvent selected from the group consisting of tetrahydrofuran, methyl acetate, diglyme, triglyme, tetraglyme, dimethyl carbonate, 1,2-dimethoxyethane, 1,2-diethoxyethane, 1-ethoxy, 2-methoxyethane, ethyl methyl carbonate, methyl propyl carbonate, ethyl propyl carbonate, diethyl carbonate, dipropyl carbonate, and mixtures thereof, a second solvent selected from the group consisting of propylene carbonate, ethylene carbonate, butylene carbonate, acetonitrile, dimethyl sulfoxide, dimethyl formamide, dimethyl acetamide, γ

-valerolactone, γ

-butyrolactone, N-methyl-pyrrolidinone, and mixtures thereof, and a lithium salt selected from the group consisting of LiPF₆, LiBF₄, LiAsF₆, LiSbF₆, LiClO₄, LiO₂, LiAlCl₄, LiGaCl₄, LiC(SO₂CF₃)₃, LiN(SO₂CF₃)₂, LiSCN, LiO₃SCF₃, LiC₆F₅SO₃, LiO₂CCF₃, LiSO₆F, LiB(C₆H₅)₄, LiCF₃SO₃, and mixtures thereof.

24. An implantable medical device, which comprises:

a housing;

a control circuitry contained inside the housing to control functioning of the medical device; and

an electrochemical cell contained inside the housing for powering the control circuitry, the improvement, in the cell comprising;

a) a casing;

b) an anode comprising;

i) a body of lithium as an anode active material having spaced apart front and back major faces, the front and back major faces extending to an upper edge and a spaced apart lower edge defining an anode height, and right and left edges defining an anode width; and

ii) a metal strip comprising an anode current collector, wherein the metal strip comprises spaced apart front and back major strip faces extending to and meeting with right and left strip edges, and wherein the metal strip extends from at least one proximal metal strip portion to a distal metal strip portion having a distal metal strip end;

iii) wherein the metal strip is substantially centered in the anode thickness with the spaced apart front and back major strip faces extending within respective front and back planes between the front and back major lithium body sides, and

iv) wherein lithium directly contacts the front and back major strip faces and the right and left strip edges at the proximal metal strip portion and part of the distal metal strip portion, but not the distal metal strip end, and

v) wherein the metal strip is devoid of perforations where it is contacted by lithium, and

vi) wherein the distal metal strip end is electrically connected to an anode terminal; and

c) a cathode comprising a first cathode active material and a second cathode active material, wherein the first cathode active material has a relatively low energy density but a relatively high rate capability with respect to the second cathode active material and is contacted to one side of a cathode current collector and wherein the second cathode active material has a relatively high energy density but a relatively low rate capability with respect to the first cathode active material and is contacted to the opposite side of the cathode current collector, and wherein the second cathode active material faces the anode;

d) a separator disposed between the anode and the cathode to prevent direct physical contact between them; and

e) a nonaqueous electrolyte activating the anode and the cathode housed inside the casing.

25. The medical device of claim 24 wherein the first cathode active material is selected from the group consisting of SVO, CSVO, V₂O₅, MnO₇, LiCoO₂, LiNiO₂, LiMnO₂, TiS₂, Cu₂S, FeS, FeS₂, copper oxide, copper vanadium oxide, and mixtures thereof and the second cathode active material is selected from the group consisting of CF_x, Ag₂O, Ag₂O₂, CuF, Ag₂CrO₄, MnO₂, SVO, and mixtures thereof.

26. The medical device of claim 24 selected from the group consisting of a cardiac pacemaker, a defibrillator, a neurostimulator, a drug pump, a hearing assist device, and a bone growth device.

27. A method for providing an electrochemical cell, comprising the steps of

a) providing a casing;

b) providing an anode comprising;

i) a body of lithium as an anode active material having spaced apart front and back major faces extending to a sidewall defining an anode thickness; and

ii) a metal strip comprising an anode current collector, wherein the metal strip comprises spaced apart front and back major strip faces extending to and meeting a metal strip edge, and wherein the metal strip extends from at least one proximal metal strip portion to a distal metal strip portion having a distal metal strip end;

iii) wherein the metal strip is substantially centered in the anode thickness with the spaced apart front and back major strip faces extending within respective front and back planes between the front and back major lithium body sides, and

iv) wherein lithium directly contacts the front and back major strip faces and the metal strip edge at the proximal metal strip portion and part of the distal metal strip portion, but not the distal metal strip end, and

v) wherein the metal strip is devoid of perforations where it is contacted by lithium, and

vi) wherein the distal metal strip is electrically connected to an anode terminal, and

c) providing a cathode of a cathode active material;

d) disposing a separator between the anode and the cathode to prevent direct physical contact between them housed inside the casing; and

e) activating the anode and the cathode with a nonaqueous electrolyte.

28. The method of claim 27, including providing a width of the distal metal strip portion being from about 1% to about 20% an anode width measured from a right edge to a left edge of the lithium body sidewall.

29. The method of claim 27 including providing the distal, metal strip portion extending into the lithium body from about 2% to about 100% of an anode height measured from an upper edge to a lower edge of the lithium body sidewall.

30. The method of claim 27 including providing a first longitudinal axis of the distal metal strip portion meeting a second longitudinal axis of the at least one proximal metal strip portion at an angle ranging from 20°

to 160°

.

31. The method of claim 27 including providing the lithium in an anode to cathode capacity ratio (A/C ratio) ranging from about 1.2 to about 5 based on a gram amount of the anode active material to the total gram amounts of the first and second cathode active materials.

32. The method of claim 27 including selecting the first cathode active material from the group consisting of silver vanadium oxide (SVO), copper silver vanadium oxide (CSVO), V₂P₅, MnO₂, LiCoO₂, LiNiO₂, LiMnO₂, TiS₂, Cu₂S, FeS, FeS₂, copper oxide, copper vanadium oxide, and mixtures thereof, and the second cathode active material from the group consisting of CF_x, Ag₂O, Ag₂O₂, CuF, Ag₂CrO₄, MnO₂, SVO, and mixtures thereof.

33. The method of claim 27 including selecting the cathode current collector from the group consisting of stainless steel, titanium, tantalum, platinum, gold, aluminum, cobalt nickel alloys, highly alloyed ferritic stainless steel containing molybdenum and chromium, and nickel-, chromium-, and molybdenum-containing alloys, and if titanium, it has a coating selected from the group consisting of graphite/carbon material, iridium, iridium oxide and platinum provided thereon.

34. The method of claim 27 including providing the electrolyte has a first solvent selected from the group consisting of tetrahydrofuran, methyl acetate, diglyme, triglyme, tetraglyme, dimethyl carbonate, 1,2-dimethoxyethane, 1,2-diethoxyethane, 1-ethoxy, 2-methoxyethane, ethyl methyl carbonate, methyl propyl carbonate, ethyl propyl carbonate, diethyl carbonate, dipropyl carbonate, and mixtures thereof, a second solvent selected from the group consisting of propylene carbonate, ethylene carbonate, butylene carbonate, acetonitrile, dimethyl sulfoxide, dimethyl formamide, dimethyl acetamide, γ

-valerolactone, γ

-butyrolactone, N-methyl-pyrrolidinone, and mixtures thereof, and a lithium salt selected from the group consisting of LiPF₆, LiBF₄, LiAsF₆, LiSbF₆, LiClO₄, LiO₂, LiAlCl₄, LiGaCl₄, LiC(SO₂CF₃)₃, LiN(SO₂CF₃)₂, LiSCN, LiO₃SCF₃, LIC₆F₅SO₃, LiO₂CCF₃, LiSO₆F, LiB(C₆H₅)₄, LiCF₃SO₃, and mixtures thereof.