Wetness sensor for use in an absorbent article

• US 8,871,994 B2
• Filed: 12/10/2010
• Issued: 10/28/2014
• Est. Priority Date: 12/10/2010
• Status: Active Grant

• Current Assignee: Kimberly-Clark Worldwide Incorporated (Kimberly-Clark Corporation)
• Original Assignee: Kimberly-Clark Worldwide Incorporated (Kimberly-Clark Corporation)
• Inventors: Wei, Ning, Song, Xuedong
• Primary Examiner(s): Hand, Melanie
• Assistant Examiner(s): HAIRELL, AUNDRIA C
• Application Number:
  US12/964,811
• Publication Number:
  US 20120150134A1
• Time in Patent Office: 1,418 Days
• Field of Search: 604/361
• US Class Current: 604/361
• CPC Class Codes: A61F 13/42 with wetness indicator or alarm
• CPC Class Codes: A61F 2013/422 the alarm being a colour change
• CPC Class Codes: A61L 15/56 Wetness-indicators or colourants

Abstract

A wetness sensor for an absorbent article that is formed from an ink is provided. The ink includes a proton-accepting chromogen and a proton-donating agent (or color developer). Prior to use, the ink is generally dry and in a protonated form so that it has a visible color. However, upon contact with bodily fluids (e.g., urine, fecal matter, mucus, menses, vaginal fluid, etc.), water in the fluid can lead to deprotonation of the chromogen, thereby resulting in a shift of the absorption maxima of the chromogen towards either the red (“bathochromic shift”) or blue end of the spectrum (“hypsochromic shift”). To increase the rate of the color change during use, the proton-donating agent is an aliphatic carboxylic acid that is highly soluble in the bodily fluid (e.g., urine), and therefore results in a color change that is very rapid and may be detected within a relatively short period of time.

Claims

1. An absorbent article comprising:

a substantially liquid impermeable layer;

a liquid permeable layer;

an absorbent core positioned between the substantially liquid impermeable layer and the liquid permeable layer; and

a wetness sensor integrated into the article and positioned such that the sensor is in fluid communication with a bodily fluid from a wearer of the article, wherein the wetness sensor includes an ink comprising a proton-accepting chromogen and a proton-donating agent, wherein the proton-donating agent includes an aliphatic carboxylic acid, the weight ratio of the proton-donating agent to the proton-accepting chromogen being from about 0.4 to about 10, wherein the ink undergoes a visible color change upon contact with the bodily fluid, further wherein the ink is free of wetting agents.

2. The absorbent article of claim 1, wherein the aliphatic carboxylic acid exhibits a solubility in water of greater than about 5 grams per 100 milliliters of water at a temperature of 20°

C.

3. The absorbent article of claim 1, wherein the aliphatic carboxylic acid exhibits a solubility in water of from about 30 to about 200 grams per 100 milliliters of water at a temperature of 20°

C.

4. The absorbent article of claim 1, wherein the aliphatic carboxylic acid has a first acid dissociation constant of about 0.5 to about 6.

5. The absorbent article of claim 1, wherein the aliphatic carboxylic acid is polyprotic.

6. The absorbent article of claim 1, wherein the aliphatic carboxylic acid includes acrylic acid, methacrylic acid, malonic acid, succinic acid, adipic acid, maleic acid, malic acid, oleic acid, tartaric acid, citric acid, formic acid, acetic acid, glycolic acid, oxalic acid, propionic acid, glutaric acid, gluconic acid, lactic acid, aspartic acid, glutaminic acid, itaconic acid, trifluoroacetic acid, or a mixture thereof.

7. The absorbent article of claim 1, wherein the aliphatic carboxylic acid is a polymeric acid.

8. The absorbent article of claim 1, wherein the proton-accepting chromogen is a leuco dye that is generally colorless when deprotonated.

9. The absorbent article of claim 1, wherein the proton-accepting chromogen includes a phthalide, phthalene, acyl-leucomethylene, fluorane, spiropyrane, cumarin, or a combination thereof.

10. The absorbent article of claim 1, wherein the weight ratio of the proton-donating agent to the proton-accepting chromogen is from about 1 to about 4.

11. The absorbent article of claim 1, wherein the ink further comprises an organic binder.

12. The absorbent article of claim 1, wherein the ink further comprises a macromolecular anchoring compound.

13. The absorbent article of claim 1, wherein the wetness sensor is disposed on the substantially liquid-impermeable layer.

14. The absorbent article of claim 13, wherein the substantially liquid-impermeable layer is a nonwoven composite formed from a nonwoven web laminated to a film.

15. The absorbent article of claim 1, wherein the wetness sensor further comprises a substrate on which the ink is disposed, wherein the substrate is integrated into the absorbent article.

16. An absorbent article comprising a wetness sensor that includes an ink disposed on a substrate, wherein the ink comprises a leuco dye and a proton-donating agent, the proton-donating agent including an aliphatic carboxylic acid having a solubility in water of greater than about 5 grams per 100 milliliters of water at a temperature of 20°

C. and a first acid dissociation constant of from about 0 to about 8, the weight ratio of the proton-donating agent to the leuco dye being from about 0.4 to about 10, wherein the ink undergoes a visible color change upon contact with an aqueous fluid, further wherein the ink is free of wetting agents.

17. The absorbent article of claim 16, wherein the aliphatic carboxylic acid exhibits a solubility in water of from about 30 to about 200 grams per 100 milliliters of water at a temperature of 20°

C.

18. The absorbent article of claim 16, wherein the aliphatic carboxylic acid has a first acid dissociation constant of about 0.5 to about 6.

19. The absorbent article of claim 16, wherein the aliphatic carboxylic acid is polyprotic.

20. The absorbent article of claim 16, wherein the aliphatic carboxylic acid includes acrylic acid, methacrylic acid, malonic acid, succinic acid, adipic acid, maleic acid, malic acid, oleic acid, tartaric acid, citric acid, formic acid, acetic acid, glycolic acid, oxalic acid, propionic acid, glutaric acid, gluconic acid, lactic acid, aspartic acid, glutaminic acid, itaconic acid, trifluoroacetic acid, or a mixture thereof.

21. The absorbent article of claim 16, wherein the aliphatic carboxylic acid is a polymeric acid.

22. The absorbent article of claim 16, wherein the leuco dye includes a phthalide, phthalene, acyl-leucomethylene, fluorane, spiropyrane, cumarin, or a combination thereof.

23. The absorbent article of claim 16, wherein the weight ratio of the proton-donating agent to the leuco dye is from about 1 to about 4.

24. The absorbent article of claim 16, wherein the ink further comprises an organic binder.

25. A wetness sensor for an absorbent article that comprises an ink disposed on a substrate, wherein the ink comprises a leuco dye and a proton-donating agent, the proton-donating agent including an aliphatic carboxylic acid having a solubility in water of greater than about 5 grams per 100 milliliters of water at a temperature of 20°

C. and a first acid dissociation constant of from about 0 to about 8, the weight ratio of the proton-donating agent to the leuco dye being from about 0.4 to about 10, wherein the ink undergoes a visible color change upon contact with an aqueous fluid, further wherein the ink is free of wetting agents.