Electroless plating performance of laser direct structuring materials

• US 8,883,900 B2
• Filed: 10/25/2011
• Issued: 11/11/2014
• Est. Priority Date: 10/25/2010
• Status: Active Grant

• Current Assignee: SHPP Global Technologies BV (Government of Saudi Arabia)
• Original Assignee: SABIC Global Technologies BV (Government of Saudi Arabia)
• Inventors: Jiang, Siguang, Meng, Jiru, Zou, Xiangping (David)
• Primary Examiner(s): LEE, DORIS L
• Application Number:
  US13/280,846
• Publication Number:
  US 20120279764A1
• Time in Patent Office: 1,113 Days
• Field of Search: 524/413
• US Class Current: 524/413
• CPC Class Codes: C08K 2003/2237 of titanium
• CPC Class Codes: C08K 2003/2296 of zinc
• CPC Class Codes: C08K 2003/265 Calcium, strontium or barium carbonate
• CPC Class Codes: C08K 2003/3045 Sulfates
• CPC Class Codes: C08K 2201/014 Additives containing two or more different additives of the same subgroup in C08K
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C08K 3/26 Carbonates; Bicarbonates
• CPC Class Codes: C08K 3/30 Sulfur-, selenium- or tellurium-containing compounds

Abstract

Thermoplastic compositions that are capable of being used in a laser direct structuring process to provide enhanced plating performance and good mechanical properties. The compositions of the present invention include a thermoplastic base resin, a laser direct structuring additive and a white pigment. The compositions can be used in a variety of applications such as personal computers, notebook and portable computers, cell phone antennas and other such communications equipment, medical applications, RFID applications, and automotive applications.

Claims

1. A thermoplastic composition, consisting essentially of:

a) from 65 to 92% by weight of a thermoplastic base resin, wherein the thermoplastic base resin is selected from polycarbonate, a polycarbonate/acrylonitrile-butadiene-styrene resin blend;

a poly(arylene ether) resin, a nylon-based resin, a polyphthalamide resin, a polyphenylene oxide resin or a combination including at least one of the foregoing resins;

b) from 0.5 to 20% by weight of a laser direct structuring additive; and

c) from 0.5 to 15% by weight of at least one pigment selected from TiO₂ including anatise, rutile, coated and uncoated, ZnO, BaSO₄, CaCO₃, BaTiO₃ or a combination including at least one of the foregoing pigments;

wherein the thermoplastic composition is capable of being plated after being activated using a laser, wherein laser activation of the composition exposes metal atoms of the laser direct structuring additive such that metal seeds are formed on areas of the composition activated by the laser.

2. The thermoplastic composition of claim 1, wherein the laser direct structuring additive is selected from a heavy metal mixture oxide spinel, a copper salt, or a combination including at least one of the foregoing laser direct structuring additives.

3. A thermoplastic composition, consisting essentially of:

a) from 70 to 90% by weight of a thermoplastic base resin, wherein the thermoplastic base resin is selected from polycarbonate, a polycarbonate/acrylonitrile-butadiene-styrene resin blend;

a poly(arylene ether) resin, a nylon-based resin, a polyphthalamide resin, a polyphenylene oxide resin or a combination including at least one of the foregoing resins;

b) from 1 to 10% by weight of a laser direct structuring additive selected from a heavy metal mixture oxide spinel, a copper salt, or a combination including at least one of the foregoing laser direct structuring additives; and

c) from 1 to 10% by weight of at least one pigment selected from TiO₂ including anatise, rutile, coated and uncoated, ZnO, BaSO₄, CaCO₃, BaTiO₃ or a combination including at least one of the foregoing pigments;

wherein the thermoplastic composition is capable of being plated after being activated using a laser, wherein laser activation of the composition exposes metal atoms of the laser direct structuring additive such that metal seeds are formed on areas of the composition activated by the laser.