Selective catalytical dehydrochlorination of hydrochlorofluorocarbons
First Claim
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1. A dehydrochlorination process comprising contacting RfCHClCH2Cl with a catalyst in a reaction zone to produce a product mixture comprising RfCCl═
- CH2, wherein said catalyst comprises an alkali metal halide salt of the formula MY supported on carbon, and wherein Rf is a perfluorniated alkyl group, M=K, Na or Cs, and Y=F, Cl or Br and wherein the catalyst contains from about 5wt % to about 40wt % alkali metal halide salt based on the total amount of alkali metal halide salt and carbon.
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Abstract
A dehydrochlorination process is disclosed. The process involves contacting RfCHClCH2Cl with a catalyst in a reaction zone to produce a product mixture comprising RfCCl═CH2, wherein said catalyst comprises MY supported on carbon, and wherein Rf is a perfluorinated alkyl group, M=K, Na or Cs, and Y=F, Cl or Br.
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22 Claims
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1. A dehydrochlorination process comprising contacting RfCHClCH2Cl with a catalyst in a reaction zone to produce a product mixture comprising RfCCl═
- CH2, wherein said catalyst comprises an alkali metal halide salt of the formula MY supported on carbon, and wherein Rf is a perfluorniated alkyl group, M=K, Na or Cs, and Y=F, Cl or Br and wherein the catalyst contains from about 5wt % to about 40wt % alkali metal halide salt based on the total amount of alkali metal halide salt and carbon.
- View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12)
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13. A dehydrochlorination process comprising contacting RfCHClCH2Cl with a catalyst in a reaction zone to produce a product mixture comprising RfCCl═
- CH2, wherein said catalyst comprises MY supported on carbon, and wherein Rf is a perfluorniated alkyl group, M=K, Na or Cs, and Y=F, Cl or Br, wherein the product selectivity to RfCCl═
CH2 is at least 90 mole %. - View Dependent Claims (14, 15, 16, 17, 18, 19, 20, 21, 22)
- CH2, wherein said catalyst comprises MY supported on carbon, and wherein Rf is a perfluorniated alkyl group, M=K, Na or Cs, and Y=F, Cl or Br, wherein the product selectivity to RfCCl═
Specification