Phosphor composition, light-emitting device having the same, cured product having the same, lighting system having the same, and display having the same

• US 8,884,514 B2
• Filed: 03/15/2013
• Issued: 11/11/2014
• Est. Priority Date: 06/30/2004
• Status: Active Grant

• Current Assignee: Mitsubishi Rayon Company Limited (Mitsubishi Chemical Holdings Corporation)
• Original Assignee: Mitsubishi Chemical Corporation (Mitsubishi Chemical Group Corp.)
• Inventors: Shimomura, Yasuo, Kaneda, Hideaki, Kijima, Naoto
• Primary Examiner(s): Patel, Nimeshkumar
• Assistant Examiner(s): HORIKOSHI, STEVEN Y
• Application Number:
  US13/831,945
• Publication Number:
  US 20130200779A1
• Time in Patent Office: 606 Days
• Field of Search: 252/301.4 F, 313/503
• US Class Current: 313/503
• CPC Class Codes: C09K 11/0883 Arsenides; Nitrides; Phosphides
• CPC Class Codes: C09K 11/64 containing aluminium
• CPC Class Codes: C09K 11/77348 Silicon Aluminium Nitrides or Silicon Aluminium Oxynitrides
• CPC Class Codes: C09K 11/77742 Silicates
• CPC Class Codes: H01L 2224/45144 Gold (Au) as principal constituent
• CPC Class Codes: H01L 2224/48091 Arched
• CPC Class Codes: H01L 2224/48247 connecting the wire to a bond pad of the item
• CPC Class Codes: H01L 2924/00 Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
• CPC Class Codes: H01L 2924/00014 the subject-matter covered by the group, the symbol of which is combined with the symbol of this group, being disclosed without further technical details
• CPC Class Codes: H01L 33/504 Elements with two or more wavelength conversion materials
• CPC Class Codes: H05B 33/12 Light sources with substantially two-dimensional radiating surfaces

Abstract

To enhance luminance and color rendering of a light emitting device comprising phosphors as wavelength converting material and at least one semiconductor light emitting device that emits visible light, as said phosphors, are used phosphors which are one or more kinds of phosphors selected from a group consisting of oxides, oxynitrides and nitrides, and are a mixture consisting of two or more kinds of phosphors whose luminous efficiency is 35% or higher when excited by the visible light from said semiconductor light emitting device at room temperature. In addition, said mixture contains a first phosphor, and a second phosphor that is different from said first phosphor and capable of absorbing emitted light from said first phosphor, and said first phosphor is contained 85 weight % or more of said mixture of phosphors.

Claims

1. A composition, comprising:

a mixture of a first phosphor, and a second phosphor that is different from the first phosphor; and

a resin;

wherein;

each of the first phosphor and the second phosphor is independently selected from the group consisting of oxides, oxynitrides, and nitrides;

each of the first phosphor and the second phosphor has a luminous efficiency of 35% or higher when excited by visible light from a semiconductor light emitting device at room temperature;

the second phosphor is capable of absorbing emitted light from the first phosphor;

the first phosphor is present in the mixture of phosphors in an amount of at least 85% by weight;

the second phosphor has the following formula (3);

M_aA_bD_cE_dX_e 

 

(3)

wherein;

M is Eu and optionally at least one element selected from the group consisting of Mn, Ce, Pr, Nd, Sm, Tb, Dy, Ho, Er, Tm, and Yb;

A is selected from the group consisting of bivalent metal elements other than M;

D is at least one element selected from the group consisting of tetravalent metal elements;

E is at least one element selected from the group consisting of trivalent metal elements;

X is at least one element selected from the group consisting of 0, N, and F; and

a, b, c, d, and e satisfy the following conditions;

a+b=1;

0.00001≦

a≦

0.1;

0.5≦

c≦

1.8;

0.5≦

d≦

1.8;

0.8×

(⅔

+4/3×

c+d)≦

e; and

e≦

1.2×

(⅔

+4/3×

c+d).

2. The composition of claim 1, wherein:

an emission peak wavelength L1 of the first phosphor is in a range of 490 nm≦

L1 ≦

550 nm; and

an emission peak wavelength L2 of the second phosphor is in a range of 600 nm≦

L2 ≦

700 nm.

3. The composition of claim 1, wherein A is at least one element selected from the group consisting of Mg, Ca, Sr and Ba.

4. The composition of claim 1, wherein:

A is at least one element selected from the group consisting of Mg, Ca, Sr and Ba;

D is at least one element selected from the group consisting of Si, Ge, Sn, Ti, Zr and Hf; and

E is at least one element selected from the group consisting of B, Al, Ga, In, Sc, Y, La, Gd and Lu.

5. The composition of claim 1, wherein

M comprises Eu;

A comprises Ca;

D comprises Si;

E comprises Al; and

X comprises N.

6. The composition of claim 1, wherein

M is Eu;

A is Ca;

D is Si;

E is Al; and

X is N or a mixture of N and O.

7. A light emitting device, comprising the composition of claim 1.

8. A cured product, comprising the composition of claim 1, wherein the resin is cured.

9. A light emitting device, comprising:

the cured product of claim 8; and

at least one semiconductor light emitting device that emits visible light.

10. The light emitting device of claim 9, wherein a color coordinate (x, y) of light emitted by the mixture of phosphors is within a range defined by a quadrangle with apexes having CIE color coordinates (0.450, 1.350), (0.550, 0.450), (0.400, 0.600), and (0.300, 0.500), when the mixture of phosphors is irradiated by the emitted light from the semiconductor light emitting device.

11. The light emitting device of claim 9, wherein a color coordinate of a composite of light emitted by the semiconductor light emitting device and light emitted by the mixture of phosphors when excited by the emitted light from the semiconductor light emitting device, is in a range defined by a quadrangle with apexes having CIE color coordinates (0.275, 0.175), (0.450, 0.400), (0.350, 0.450), and (0.175, 0.250).

12. A lighting system, comprising the light emitting device of claim 9.

13. A display, comprising the light emitting device of claim 9.

14. A surface-emitting lighting system, comprising:

a light-impermeable rectangular support case having an open top;

a diffusion plate fixed on the rectangular support case to cover the open top; and

the light emitting device of claim 9 disposed on a bottom interior surface of the rectangular support case.

15. A light emitting device, comprising:

a cup-shaped portion;

a semiconductor light emitting device that emits visible light; and

a cured product;

wherein;

the semiconductor light emitting device is fixed in the cup-shaped portion;

the cured product covers the semiconductor light emitting device in the cup-shaped portion; and

the cured product is obtained by pouring the composition of claim 1 into the cup-shaped portion and curing the resin.