Detection of one or more interstitial constituents in a polycrystalline diamond element by neutron radiographic imaging

• US 8,888,879 B1
• Filed: 10/06/2011
• Issued: 11/18/2014
• Est. Priority Date: 10/20/2010
• Status: Expired due to Fees

• Current Assignee: US Synthetic Corporation (ChampionX Corporation)
• Original Assignee: US Synthetic Corporation (ChampionX Corporation)
• Inventors: Mukhopadhyay, Debkumar, Bertagnolli, Kenneth E.
• Primary Examiner(s): MCDONOUGH, JAMES E
• Application Number:
  US13/267,026
• Time in Patent Office: 1,139 Days
• Field of Search: 513/09, 512/93, 513/07
• US Class Current: 51/309
• CPC Class Codes: B24D 18/0009 using moulds or presses
• CPC Class Codes: C04B 35/52 based on carbon, e.g. graphite
• CPC Class Codes: C04B 41/009 characterised by the material treated
• CPC Class Codes: C04B 41/5353 Wet etching, e.g. with etchants dissolved in organic solvents
• CPC Class Codes: C04B 41/91 involving the removal of part of the materials of the treated articles, e.g. etching
• CPC Class Codes: G01N 23/005 by using neutrons G01N23/02 - G01N23/227 take precedence
• CPC Class Codes: G01N 23/05 using neutrons
• CPC Class Codes: G01N 33/385 Crystals
• CPC Class Codes: G01N 33/40 Grinding-materials

Abstract

In an embodiment, a method of non-destructively testing a polycrystalline diamond (“PCD”) element includes providing a PCD element including a plurality of bonded diamond grains defining a plurality of interstitial regions, at least a portion of the plurality of interstitial regions including one or more interstitial constituents disposed therein. The method further includes exposing the PCD element to neutron radiation from a neutron radiation source, receiving a portion of the neutron radiation that passes through the PCD element, and determining at least one characteristic of the PCD element at least partially based on the portion of the neutron radiation received. For example, the at least one characteristic may be the presence and distribution of metal-solvent catalyst, residual metal-solvent catalyst, an infiltrant, residual infiltrant, or other interstitial constituents within a PCD element.

Claims

1. A method of non-destructively testing a polycrystalline diamond element, comprising:

providing an at least partially leached polycrystalline diamond element including a plurality of bonded diamond grains defining a plurality of interstitial regions, at least a portion of the plurality of interstitial regions including one or more interstitial constituents comprising at least one leaching by-product disposed therein;

exposing the at least partially leached polycrystalline diamond element to neutron radiation from a neutron radiation source;

receiving a portion of the neutron radiation that passes through the at least partially leached polycrystalline diamond element; and

determining at least one characteristic of the at least partially leached polycrystalline diamond element at least partially based on the portion of the neutron radiation received, the at least one characteristic including a presence of the at least one leaching by-product.

2. The method of claim 1 wherein determining at least one characteristic of the at least partially leached polycrystalline diamond element at least partially based on the portion of the neutron radiation received comprises determining the presence of clusters of metal-solvent catalyst or infiltrant disposed within a portion of the interstitial regions.

3. The method of claim 1 wherein determining at least one characteristic of the at least partially leached polycrystalline diamond element at least partially based on the portion of the neutron radiation received comprises determining the presence of one or more light chemical elements and/or light chemical molecules.

4. The method of claim 3 wherein the light chemical elements and/or light chemical molecules are selected from hydrogen, oxygen, nitrogen, water, and combinations thereof.

5. The method of claim 1 wherein the at least partially leached polycrystalline diamond element comprises an at least partially leached polycrystalline diamond table, and wherein determining at least one characteristic of the at least partially leached polycrystalline diamond element at least partially based on the portion of the neutron radiation received comprises determining a location of an interface between a first region that extends inwardly from an exterior working surface of the at least partially leached polycrystalline diamond table and is substantially free of metal-solvent catalyst, and a second region of the at least partially leached polycrystalline diamond table that comprises the metal-solvent catalyst.

6. The method of claim 1 wherein the at least partially leached polycrystalline diamond element comprises an at least partially leached polycrystalline diamond table, and wherein determining at least one characteristic of the at least partially leached polycrystalline diamond element at least partially based on the portion of the neutron radiation received comprises determining a location of an interface between a first region that extends inwardly from an exterior working surface of the at least partially leached polycrystalline diamond table and is substantially free of an infiltrant, and a second region of the at least partially leached polycrystalline diamond table that comprises the infiltrant.

7. The method of claim 1 wherein the neutron radiation is provided by a cold neutron beam source.

8. The method of claim 1 wherein the neutron radiation is provided by a thermal neutron beam source.

9. The method of claim 1 wherein the neutron radiation is provided by a fast neutron beam source.

10. The method of claim 1 wherein the one or more interstitial constituents comprise metal-solvent catalyst, an infiltrant, residual metal-solvent catalyst, residual infiltrant, one or more light chemical elements, one or more light chemical molecules, or combinations thereof.

11. The method of claim 1 wherein the at least partially leached polycrystalline diamond element is freestanding.

12. The method of claim 1 wherein the at least partially leached polycrystalline diamond element is attached to a substrate.

13. The method of claim 1 wherein the at least partially leached polycrystalline diamond element is integrally or preformed and attached to a substrate.

14. The method of claim 1, further comprising modifying a manufacturing process used to fabricate the at least partially leached polycrystalline diamond element in response to the determined at least one characteristic.

15. The method of claim 1 wherein modifying a manufacturing process used to fabricate the at least partially leached polycrystalline diamond element in response to the determined at least one characteristic comprises modifying a high-pressure/high-temperature process condition used to fabricate the at least partially leached polycrystalline diamond element.

16. The method of claim 15 wherein the high-pressure/high-temperature process condition comprises pressure, temperature, time, or combinations thereof.

17. The method of claim 1 wherein modifying a manufacturing process used to fabricate the at least partially leached polycrystalline diamond element in response to the determined at least one characteristic comprises modifying a leaching acid composition, leaching time, diamond particle size, or combinations thereof.

19. The method of claim 1, further comprising:

correlating the presence of the at least one leaching by-product in the at least partially leached polycrystalline diamond element to at least one performance characteristic of the at least partially leached polycrystalline diamond element; and

modifying a manufacturing process used to fabricate the at least partially leached polycrystalline diamond element in response to the at least one performance characteristic.

18. A method of non-destructively testing a polycrystalline diamond element, comprising:

providing an at least partially leached polycrystalline diamond element including a plurality of bonded diamond grains defining a plurality of interstitial regions, at least a portion of the plurality of interstitial regions including one or more interstitial constituents disposed therein; and

exposing the at least partially leached polycrystalline diamond element to neutron radiation from a neutron radiation source;

receiving a portion of the neutron radiation that passes through the at least partially leached polycrystalline diamond element; and

at least partially based on the portion of the neutron radiation received, determining a presence of one or more interstitial constituents including at least one leaching by-product within a portion of the interstitial regions of the at least partially leached polycrystalline diamond element; and

correlating the determined presence of the at least one leaching by-product within the portion of the interstitial regions with at least one performance characteristic of the at least partially leached polycrystalline diamond table.

20. The method of claim 18, further comprising modifying a manufacturing process used to fabricate the at least partially leached polycrystalline diamond element in response to the at least one performance characteristic.