Metal-air low temperature ionic liquid cell

• US 8,895,197 B2
• Filed: 05/10/2010
• Issued: 11/25/2014
• Est. Priority Date: 05/11/2009
• Status: Active Grant

• Current Assignee: Arizona Board of Regents (University of Arizona)
• Original Assignee: Arizona Board of Regents (University of Arizona)
• Inventors: Friesen, Cody A., Buttry, Daniel A.
• Primary Examiner(s): Ruddock, Ula C.
• Assistant Examiner(s): Parsons, Thomas H.
• Application Number:
  US12/776,962
• Publication Number:
  US 20100285375A1
• Time in Patent Office: 1,660 Days
• Field of Search: 429/402, 429/403, 429/405, 429/406
• US Class Current: 429/403
• CPC Class Codes: H01M 12/06 with one metallic and one gaseous electrode
• CPC Class Codes: H01M 12/08 composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
• CPC Class Codes: H01M 2300/0025 Organic electrolyte
• CPC Class Codes: H01M 2300/0045 Room temperature molten salts comprising at least one organic ion
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

The present application relates to an electrochemical metal-air cell in which a low temperature ionic liquid is used.

Claims

1. An electrochemical metal-air cell, comprising:

a flexible fuel electrode for oxidizing a metal fuel;

a flexible air electrode for absorbing and reducing gaseous oxygen;

an ionically conductive medium comprising a low temperature ionic liquid having a melting point at or below 150°

C. at 1 atm. and contained in a space between the flexible fuel electrode and the air electrode for conducting ions for supporting the electrochemical reactions at the fuel and air electrodes, the ionic liquid positioned to contact both the flexible fuel electrode and the air electrode; and

one or more seal members along a periphery of the fuel and air electrodes for sealing the space between the fuel and air electrodes to contain the ionic liquid therein, said seal members being electrically insulating to prevent electrical conduction between the fuel and air electrodes;

wherein the flexible fuel electrode and the flexible air electrode are arranged in a compacted non-linear configuration with an external surface of the air electrode exposed for absorbing gaseous oxygen, and

wherein the flexible fuel electrode and the flexible air electrode each further comprise a backing attached thereto in which the backing is impermeable to the ionic liquid.

2. An electrochemical metal air cell according to claim 1, further comprising an electrically insulating flexible separator;

wherein the flexible fuel electrode, the flexible air electrode, and the flexible separator are wound in a roll in the non-linear compact configuration with the flexible separator positioned between the external surfaces of the fuel electrode and the air electrode to prevent electrically conducting contact between the external surfaces of the fuel and air electrodes, said flexible separator being configured to permit exposure of the external surface of the air electrode to gaseous oxygen.

3. An electrochemical metal-air cell according to claim 2, further comprising a flexible internal separator that is electrochemically inert in the ionic liquid and electrically insulating, the flexible internal separator being wound in the roll and positioned in the space between the internal surfaces of the fuel and air electrodes to prevent electrically conducting contact between the internal surfaces of the fuel and air electrodes.

4. An electrochemical metal-air cell according to claim 2, further comprising a housing in which the roll is received.

5. An electrochemical metal-air cell according to claim 4, wherein the housing has an open axial airflow receiving end and an axial airflow receiving end of the roll faces the open axial airflow receiving end of the housing, the cell further comprising an airflow generator for forcing airflow into the open axial airflow receiving end of the housing and the axial airflow receiving end of the roll between the external surfaces of the fuel and air electrodes.

6. An electrochemical metal-air cell according to claim 5, wherein the housing has an open axial airflow exit end opposite the open axial airflow receiving end, and the roll has an axial airflow exit end facing the open axial airflow exit end of the housing, wherein the airflow generator is configured to force the airflow axially through the roll between the external surfaces of the fuel and air electrodes and axially outward from the axial airflow exit end of the roll for exit through the open axial airflow exit end of the housing.

7. An electrochemical metal-air cell according to claim 2, further comprising an airflow generator configured to force airflow into the roll between the external surfaces of the fuel and air electrodes.

8. An electrochemical metal-air cell according to claim 7, wherein the roll has an axial airflow receiving end and the airflow generator is configured to force the airflow into the axial airflow receiving end between the external surfaces of the fuel and air electrodes.

9. An electrochemical metal-air cell according to claim 8, wherein the roll has an axial airflow exit end opposite the axial airflow receiving end, and the airflow generator is configured to force the airflow into the axial airflow receiving end of the roll between the external surfaces of the fuel and air electrodes and outwardly from the axial airflow exit end.

10. An electrochemical metal-air cell according to claim 8, wherein the roll has a circumferential airflow exit defined by ends of the fuel and air electrodes on an outermost lap of the roll, and wherein the airflow generator is configured to force the airflow into the axial airflow receiving end of the roll between the external surface of the fuel and air electrodes and outwardly from the axial airflow exit.

11. An electrochemical cell according to claim 2, wherein the ionic liquid has a vapor pressure at or below 1 mm Hg at 20°

C. above its melting point; and

wherein a ratio of combined electrode thickness to ionic liquid thickness is greater than or equal to 1;

1.

12. An electrochemical metal-air cell according to claim 11, wherein the metal fuel comprises a metal selected from the group consisting of an alkaline earth metal, a transition metal and a post-transition metal.

13. An electrochemical metal-air cell according to claim 11, wherein the metal fuel comprises a metal selected from the group consisting of zinc, aluminum, gallium, manganese, and magnesium.

14. An electrochemical metal-air cell according to claim 1, wherein the ionic liquid has a vapor pressure at or below 1 mm Hg at 20°

C. above its melting point.

15. An electrochemical metal-air cell according to claim 14, wherein the ionic liquid has a vapor pressure that is essentially immeasurable at 20°

C. above its melting point.

16. An electrochemical metal-air cell according to claim 15, wherein a distance of the space between the fuel and air electrodes is in the range of 10 microns to 300 microns.

17. An electrochemical metal-air cell according to claim 16, wherein the distance of the space between the fuel and air electrodes is in the range of 10 microns to 100 microns.

18. An electrochemical metal-air cell according to claim 15, wherein a ratio of combined electrode thickness to ionic liquid thickness is in the range of 1:

10 to 10;

1.

19. An electrochemical metal-air cell according to claim 15, wherein a ratio of combined electrode thickness to ionic liquid thickness is greater than or equal to 1:

1.

20. An electrochemical metal-air cell according to claim 14, wherein a distance of the space between the fuel and air electrodes is in the range of 10 microns to 300 microns.

21. An electrochemical metal-air cell according to claim 20, wherein the distance of the space between the fuel and air electrodes is in the range of 10 microns to 100 microns.

22. An electrochemical metal-air cell according to claim 14, wherein a ratio of combined electrode thickness to ionic liquid thickness is in the range of 1:

10 to 10;

1.

23. An electrochemical metal-air cell according to claim 14, wherein a ratio of combined electrode thickness to ionic liquid thickness is greater than or equal to 1:

1.

24. An electrochemical metal-air cell according to claim 1, wherein a distance of the space between the fuel and air electrodes is in the range of 10 microns to 300 microns.

25. An electrochemical metal-air cell according to claim 24, wherein the distance of the space between the fuel and air electrodes is in the range of 10 microns to 100 microns.

26. An electrochemical metal-air cell according to claim 1, wherein a ratio of combined electrode thickness to ionic liquid thickness is in the range of 1:

10 to 10;

1.

27. An electrochemical metal-air cell according to claim 26, wherein a ratio of combined electrode thickness to ionic liquid thickness is greater than or equal to 1:

1.

28. An electrochemical metal-air cell according to claim 1, wherein the ionically conductive medium consists essentially of the low temperature ionic liquid.

29. An electrochemical metal-air cell according to claim 28, wherein the low temperature ionic liquid is a room temperature ionic liquid.

30. An electrochemical metal-air cell according to claim 1, wherein the ionically conductive medium consists of the low temperature ionic liquid.

31. An electrochemical metal-air cell according to claim 30, wherein the low temperature ionic liquid is a room temperature ionic liquid.

32. An electrochemical metal-air cell according to claim 1, wherein the ionically conductive medium is devoid of a solvent for dissolving the low temperature ionic liquid.

33. An electrochemical metal-air cell according to claim 32, wherein the low temperature ionic liquid is a room temperature ionic liquid.

34. An electrochemical metal-air cell according to claim 1, wherein the low temperature ionic liquid is a room temperature ionic liquid.

35. An electrochemical metal-air cell according to claim 1, wherein the ionically conductive medium consists essentially of the low temperature ionic liquid.

36. An electrochemical metal-air cell according to claim 35, wherein the low temperature ionic liquid is a room temperature ionic liquid.

37. An electrochemical metal-air cell according to claim 1, wherein the ionically conductive medium consists of the low temperature ionic liquid.

38. An electrochemical metal-air cell according to claim 37, wherein the low temperature ionic liquid is a room temperature ionic liquid.

39. An electrochemical metal-air cell according to claim 1, wherein the ionically conductive medium is devoid of a solvent for dissolving the low temperature ionic liquid.

40. An electrochemical metal-air cell according to claim 39, wherein the low temperature ionic liquid is a room temperature ionic liquid.

41. An electrochemical metal-air cell according to claim 1, wherein the low temperature ionic liquid is a room temperature ionic liquid.

42. An electrochemical metal-air cell according to claim 1, wherein the compact configuration is the flexible fuel electrode and the flexible air electrode being folded in an alternating manner with portions of the air electrode'"'"'s external surface facing one another and portions of the fuel electrode'"'"'s external surface facing one another.

43. An electrochemical metal-air cell according to claim 42, further comprising a plurality of separators positioned between at least the portions of the air electrode'"'"'s external surfaces facing one another, the separators being configured to permit exposure of the portions of the air electrodes external surface to gaseous oxygen.

44. An electrochemical metal air cell according to claim 1,

wherein the flexible fuel electrode and the flexible air electrode are wound in a roll as the non-linear compact configuration,

wherein the cell further comprises a retainer structure for positioning fuel electrode and the air electrode such that the external surfaces of the fuel electrode and the air electrode are maintained in spaced apart relation to prevent electrically conducting contact between the external surfaces of the fuel and air electrodes and permit exposure of the external surface of the air electrode to gaseous oxygen.

45. An electrochemical cell according to claim 1,

wherein the ionic liquid has a vapor pressure at or below 1 mm Hg at 20°

C. above its melting point; and

wherein a ratio of combined electrode thickness to ionic liquid thickness is greater than or equal to 1;

1.

46. An electrochemical metal-air cell according to claim 45, wherein the metal fuel comprises a metal selected from the group consisting of an alkaline earth metal, a transition metal and a post-transition metal.

47. An electrochemical metal-air cell according to claim 45, wherein the metal fuel comprises a metal selected from the group consisting of zinc, aluminum, gallium, manganese, and magnesium.

48. An electrochemical metal-air cell according to claim 1, wherein the metal fuel comprises a metal selected from the group consisting of an alkaline earth metal, a transition metal and a post-transition metal.

49. An electrochemical metal-air cell according to claim 1, wherein the metal fuel comprises a metal selected from the group consisting of zinc, aluminum, gallium, manganese, and magnesium.

50. An electrochemical metal-air cell, comprising:

a flexible fuel electrode for oxidizing a metal fuel;

a flexible air electrode for absorbing and reducing gaseous oxygen;

an ionically conductive medium comprising a low temperature ionic liquid having a melting point at or below 150°

C. at 1 atm., the ionic liquid being contained in a space between the fuel electrode and the air electrode for conducting ions for supporting the electrochemical reactions at the fuel and air electrodes;

wherein the ionic liquid contacts both the fuel electrode and the air electrode; and

one or more seal members along a periphery of the fuel and air electrodes for sealing the space between the fuel and air electrodes to contain the ionic liquid therein, said seal members being electrically insulating to prevent electrical conduction between the fuel and air electrodes;

wherein the ionically conductive medium further comprises a dissolved metal-containing additive.

51. An electrochemical metal-air cell according to claim 50, wherein said fuel and air electrodes are configured to essentially prevent liquid permeation of the low temperature ionic liquid therethrough via the external surfaces thereof.

52. An electrochemical metal-air cell according to claim 51, wherein the vapor pressure of the ionic liquid is at or below 1 mm Hg at 20°

C. above its melting point.

53. An electrochemical metal-air cell according to claim 52, wherein the vapor pressure of the ionic liquid is at or below 0.1 mm Hg at 20°

C. above its melting point.

54. An electrochemical metal-air cell according to claim 51, wherein a ratio of combined electrode thickness to ionic liquid thickness is in the range of 1:

10 to 10;

1.

55. An electrochemical metal-air cell according to claim 51, wherein a ratio of combined electrode thickness to ionic liquid thickness is greater than or equal to 1:

1.

56. An electrochemical metal-air cell according to claim 55, wherein the ratio is greater than or equal to 2:

1.

57. An electrochemical metal-air cell according to claim 56, wherein the ratio is greater than or equal to 3:

1.

58. An electrochemical metal-air cell according to claim 50, wherein the metal fuel comprises zinc.

59. A method of operating an electrochemical metal-air cell, the cell comprising:

(i) a flexible fuel electrode for oxidizing a metal fuel;

(ii) flexible air electrode for absorbing and reducing gaseous oxygen;

(iii) an ionically conductive medium comprising a low temperature ionic liquid having a melting point at or below 150°

C. at 1 atm.; and

(iv) one or more seal members along a periphery of the fuel and air electrodes for sealing a space between the fuel and air electrodes to contain the ionic liquid therein, said seal members being electrically insulating to prevent electrical conduction between the fuel and air electrodes, and the ionic liquid being contained in the space between the fuel electrode and the air electrode for conducting ions for supporting the electrochemical reactions at the fuel and air electrodes, wherein the ionic liquid contacts both the fuel electrode and the air electrode;

wherein the flexible fuel electrode and the flexible air electrode each further comprise a backing attached thereto in which the backing is impermeable to the ionic liquid; and

wherein the fuel electrode and the air electrode are arranged in a compacted non-linear configuration with an external surface of the air electrode exposed for absorbing gaseous oxygen;

the method comprising;

oxidizing the metal fuel at the fuel electrode;

reducing absorbed gaseous oxygen at the air electrode; and

conducting ions within the ionic liquid for supporting the electrochemical reactions at the fuel electrode and air electrode;

wherein the method is performed with the ionic liquid at a temperature at or above its melting point.

60. A method according to claim 59, wherein the ionic liquid is at a temperature at which the vapor pressure of the ionic liquid is at or below 1 mm Hg.

61. A method according to claim 60, wherein the ionic liquid is at a temperature at which the vapor pressure of the ionic liquid is at or below 0.1 mm Hg.

62. A method according to claim 61, wherein the ionic liquid is at a temperature at which the vapor pressure of the ionic liquid is essentially zero.

63. A method according to claim 59, wherein the metal fuel comprises zinc.

64. An electrochemical metal-air cell, comprising:

a flexible fuel electrode for oxidizing a metal fuel;

a flexible air electrode for absorbing and reducing gaseous oxygen; and

an ionically conductive medium comprising a low temperature ionic liquid having a melting point at or below 150°

C. at 1 atm. and contained in a space between the flexible fuel electrode and the air electrode for conducting ions for supporting the electrochemical reactions at the fuel and air electrodes; and

one or more seal members along a periphery of the fuel and air electrodes for sealing the space between the fuel and air electrodes to contain the ionic liquid therein, said seal members being electrically insulating to prevent electrical conduction between the fuel and air electrodes;

wherein the reduction reaction supported at the air electrode reduces one mole of gaseous oxygen via multiple electrons produced at the flexible fuel electrode for oxidizing the metal fuel, and

wherein the flexible fuel electrode and the flexible air electrode are arranged in a compacted non-linear configuration with an external surface of the air electrode exposed for absorbing gaseous oxygen.

65. An electrochemical metal-air cell according to claim 64, wherein the reduction reaction supported at the air electrode reduces one mole of gaseous oxygen via four electrons produced at the flexible fuel electrode for oxidizing the metal fuel.