Naphthenic-rich liquid crystalline polymer composition with improved flammability performance

• US 8,906,259 B2
• Filed: 11/13/2012
• Issued: 12/09/2014
• Est. Priority Date: 11/15/2011
• Status: Active Grant

• Current Assignee: Ticona LLC (Celanese Corporation)
• Original Assignee: Ticona LLC (Celanese Corporation)
• Inventors: Kim, Young Shin
• Primary Examiner(s): Wu, Shean C
• Application Number:
  US13/674,969
• Publication Number:
  US 20130122272A1
• Time in Patent Office: 756 Days
• Field of Search: 252/299.01, 252/299.5, 524/286, 524/296
• US Class Current: 252/299.01
• CPC Class Codes: C08G 63/605 the hydroxy and carboxylic groups being bound to aromatic rings
• CPC Class Codes: C08G 63/916 Dicarboxylic acids and dihydroxy compounds
• CPC Class Codes: C08K 5/09 Carboxylic acids; Metal salts thereof; Anhydrides thereof
• CPC Class Codes: C08K 5/13 Phenols; Phenolates
• CPC Class Codes: C08L 67/03 the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings
• CPC Class Codes: C09K 19/3809 Polyesters; Polyester derivatives, e.g. polyamides
• CPC Class Codes: C09K 19/542 Macromolecular compounds

Abstract

A thermoplastic composition that comprises a naphthenic-rich, thermotropic liquid crystalline polymer blended with a flow modifier is provided. The flow modifier is an aromatic carboxylic acid that contains or more carboxyl functional groups. Without intending to be limited by theory, it is believed that the functional groups can react with the polymer chain to shorten its length and thus reduce melt viscosity. It is also believed that such acids can combine smaller chains of the polymer together after they have been cut during processing. This helps maintain the mechanical properties of the composition even after its melt viscosity has been reduced. As a result of the present invention, the melt viscosity of the thermoplastic composition is generally low enough so that it can readily flow into the cavity of a mold having small dimensions.

Claims

1. A molded part comprising a thermoplastic composition, wherein the thermoplastic composition comprises at least one aromatic carboxylic acid and at least one thermotropic liquid crystalline polymer having a total amount of repeating units derived from naphthenic hydroxycarboxylic and/or naphthenic dicarboxylic acids of more than 18 mol. %, wherein the thermoplastic composition has a melt viscosity of from about 0.1 to about 80 Pa·

s, as determined in accordance with ISO Test No. 11443 at a shear rate of 1000 seconds<sup>−

1</sup> and temperature that is 15°

C. above the melting temperature of the thermoplastic composition, wherein the molded part exhibits a total flame time of about 50 seconds or less, as determined in accordance with UL94 at a thickness of 0.8 mm after conditioning for 48 hours at 23°

C. and 50% relative humidity.

2. The molded part of claim 1, wherein the molded part exhibits a total flame time of from about 1 to about 40 seconds, as determined in accordance with UL94 at a thickness of 0.8 mm after conditioning for 48 hours at 23°

C. and 50% relative humidity.

3. The molded part of claim 1, wherein the molded part exhibits a total number of drips of 1 or less, as determined in accordance with UL94 at a thickness of 0.8 mm after conditioning for 48 hours at 23°

C. and 50% relative humidity.

4. The molded part of claim 1, wherein the molded part exhibits a V0 rating as determined in accordance with UL94 after conditioning for 48 hours at 23°

C. and 50% relative humidity.

5. The molded part of claim 1, wherein the aromatic carboxylic acid is a phenolic acid, diphenolic acid, naphthenic acid, or a combination thereof.

6. The molded part of claim 1, wherein the aromatic carboxylic acid includes 4-hydroxybenzoic acid, phthalic acid, isophthalic acid, terephthalic acid, 2-methyleneterephthalic acid, or a combination thereof.

7. The molded part of claim 1, wherein the aromatic carboxylic acid includes 4-hydroxy-4′

-biphenylcarboxylic acid, 4′

-hydroxyphenyl-4-benzoic acid, 3′

-hydroxyphenyl-4-benzoic acid, 4,4′

-bibenzoic acid, or a combination thereof.

8. The molded part of claim 1, wherein the aromatic carboxylic acid includes 1-naphthoic acid, 2-naphthoic acid, 2-hydroxy-6-naphtoic acid, 2-hydroxy-5-naphthoic acid, 3-hydroxy-2-naphthoic acid, 2,6-naphthalenedicarboxylic acid, 2,3-naphthelenedicarboxylic acid, or a combination thereof.

9. The molded part of claim 8, wherein the aromatic carboxylic acid includes 2,6-naphthalenedicarboxylic acid.

10. The molded part of claim 1, wherein aromatic carboxylic acids constitute from about 1 wt. % to about 10 wt. % of the thermoplastic composition.

11. The molded part of claim 1, wherein the weight ratio of thermotropic liquid crystalline polymers to aromatic carboxylic acids in the thermoplastic composition is from about 10 to about 60.

12. The molded part of claim 11, wherein the thermotropic liquid crystalline polymer further contains monomer units derived from 6-hydroxy-2-naphthoic acid in an amount of more than about 18 mol. %.

13. The molded part of claim 12, wherein the thermotropic liquid crystalline polymer contains monomer units derived from 4-hydroxybenzoic acid, terephthalic acid, isophthalic acid, hydroquinone, 4,4′

-biphenol, acetaminophen, or a combination thereof.

14. The molded part of claim 11, wherein the they thermotropic liquid crystalline polymer further contains monomer units derived from 2,6-naphthalenedicarboxylic acid in an amount of more than about 18 mol. %.

15. The molded part of claim 14, wherein the thermotropic liquid crystalline polymer contains monomer units derived from 4-hydroxybenzoic acid, terephthalic acid, isophthalic acid, hydroquinone, 4,4′

-biphenol, acetaminophen, or a combination thereof.

16. The molded part of claim 1, wherein the thermoplastic composition has a melt viscosity of from about 0.5 to about 50 Pa·

s, as determined in accordance with ISO Test No. 11443 at a shear rate of 1000 seconds<sup>−

1</sup> and temperature that is 15°

C. above the melting temperature of the thermoplastic composition.

17. The molded part of claim 1, wherein the thermoplastic composition further comprises glass fibers.

18. The molded part of claim 1, wherein the molded part has at least one dimension of about 500 micrometers or less.

19. The molded part of claim 1, wherein the molded part exhibits a blister free temperature of about 240°

C. or greater.

20. An electrical connector that comprises opposing walls between which a passageway is defined for receiving a contact pin, wherein at least one of the walls contains the molded part of claim 1.

21. The molded part of claim 1, wherein one or more conductive elements are applied to the molded part.

22. The molded part of claim 21, wherein the conductive elements are resonating antenna elements, inverted-F antenna structures, closed and open slot antenna structures, loop antenna structures, monopoles, dipoles, planar inverted-F antenna structures, or a combination thereof.

23. A handheld device that comprises an antenna structure, wherein the antenna structure comprises the molded part of claim 22.

24. An integrated circuit comprising the molded part of claim 1.

25. An electronic component that comprises the molded part of claim 1.

26. The electronic component of claim 25, wherein the electronic component is a cellular telephone, laptop computer, small portable computer, wrist-watch device, pendant device, headphone or earpiece device, media player with wireless communications capabilities, handheld computer, remote controller, global positioning system, handheld gaming device, battery cover, speaker, integrated circuit, electrical connector, camera module, or a combination thereof.

27. The electronic component of claim 26, wherein the electronic component is an electrical connector.

28. The electronic component of claim 26, wherein the electronic component is a camera module.

29. The electronic component of claim 26, wherein the electronic component is a cellular telephone.

30. A printer part comprising the molded part of claim 1.

31. A molded part comprising a thermoplastic composition, wherein the thermoplastic composition comprises at least one aromatic carboxyiic acid and at least one thermotropic liquid crystalline polymer having a total amount of repeating units derived from naphthenic hydroxycarboxylic and/or naphthenic dicarboxylic acids of more than 15 mol. %, wherein the thermoplastic composition has a melt viscosity of from about 0.1 to about 80 Pa·

s, as determined in accordance with ISO Test No. 11443 at a shear rate of 1000 seconds<sup>−

1</sup> and temperature that is 15°

C. above the melting temperature of the thermoplastic composition, wherein the molded part exhibits a total flame time of about 50 seconds or less, as determined in accordance with UL94 at a thickness of 0.8 mm after conditioning for 48 hours at 23°

C. and 50% relative humidity.