Removal of carbon dioxide from gases by aqueous amine solutions containing a sterically hindered amine

• US 8,920,544 B2
• Filed: 12/21/2010
• Issued: 12/30/2014
• Est. Priority Date: 01/05/2010
• Status: Active Grant

• Current Assignee: Thyssenkrupp Uhde GmbH (Thyssenkrupp AG)
• Original Assignee: Thyssenkrupp Uhde GmbH (Thyssenkrupp AG)
• Inventors: Menzel, Johannes, Von Morstein, Olaf
• Primary Examiner(s): Smith, Duane
• Assistant Examiner(s): HOLECEK, CABRENA L
• Application Number:
  US13/519,498
• Publication Number:
  US 20120279393A1
• Time in Patent Office: 1,470 Days
• Field of Search: 951/60, 951/61, 951/63, 951/65, 951/66, 951/73, 951/74, 951/78, 951/83, 952/36, 423/228, 423/229, 252/60
• US Class Current: 95/159
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/1475 Removing carbon dioxide
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

A method for removing acid gases from a fluid flow using an absorbent including an aqueous solution with at least two different amines. An amine in a proportion of greater than 50 wt. % of the total amine amount in the aqueous solution is the first amine component in the aqueous solution, and a sterically hindered amine in a proportion of less than 50 wt. % is the second amine component in the aqueous solution. The fluid flow is brought into contact with the absorbent at a partial pressure of <200 mbar.

Claims

1. A method for absorbing sour gases from a fluid stream comprising:

providing an absorbent aqueous solution with an amine component, the amine component consisting essentially of,

a first amine component selected from the group consisting of piperazine, 1,3-diaminopropane, and mixtures thereof, the first amine component being 70-85 wt. % of the total amine content of the aqueous solution, and

a second amine component consisting of one or more sterically hindered amines in an amount of from 15-30 wt. % of the total amine content of the aqueous solution, and

bringing the fluid stream into contact with the absorbent at a partial pressure of the sour gases of <

200 mbar in the fluid stream, absorbing the sour gases and producing an absorbent laden with sour gases.

2. The method of claim 1, wherein the sterically hindered amine is selected from the group consisting of:

(i) amines with a primary amino group which is bound to a tertiary carbon atom,

(ii) amines with a secondary amino group which is bound to a secondary or tertiary carbon atom,

(iii) amines in which a tertiary or quaternary carbon atom is in a position β

to the amino group,

and mixtures thereof.

3. The method of claim 1, wherein the sterically hindered amine is 2-amino-2-methyl-1-propanol (AMP).

4. The method of claim 1, further comprising regenerating the laden absorbent by:

heating,

depressurizing,

stripping with the aid of stripping vapours produced by internal evaporation of the aqueous solution,

stripping with the aid of an inert fluid, or a combination of at least two of these measures.

5. The method of claim 2, further comprising regenerating the laden absorbent by:

heating,

depressurizing,

stripping with the aid of stripping vapours produced by internal evaporation of the aqueous solution,

stripping with the aid of an inert fluid, or

a combination of at least two of these measures.

6. The method of claim 3, further comprising regenerating the laden absorbent by:

heating,

depressurizing,

stripping with the aid of stripping vapours produced by internal evaporation of the aqueous solution,

stripping with the aid of an inert fluid, or

a combination of at least two of these measures.

8. The method of claim 1, wherein the fluid stream is flue gas.

9. The method of claim 1, wherein the first amine component consists of 1,3-diaminopropane.

11. The method of claim 8, wherein the first amine component consists of 1,3-diaminopropane.

12. The method of claim 1, wherein the fluid stream contacts the absorbent at a temperature of about 40°

C.

13. The method of claim 4, wherein the sour gases are liberated from the absorbent liquid during regenerating.

14. The method of claim 1, wherein the fluid stream contacts the absorbent at a temperature of 40°

C.

15. The method of claim 1, wherein the first amine compound is present in an amount of 72-76 wt. % of the total amine compound and the second amine compound is present in an amount of 26-28 wt. % of the total amine compound.

16. The method of claim 1, wherein the first amine compound is present in an amount of 72-85 wt. %.

17. The method of claim 1, wherein the first amine compound is present in an amount of 76-85 wt. %.

7. A method for removing sour gases from a fluid stream comprising:

a) providing an absorbent in an aqueous solution with an amine component, the amine component consisting of

ai) a first amine component selected from the group consisting of piperazine, 1,3 diaminopropane, and mixtures thereof, the first amine component being 70-85 wt. % of the total amine content of the aqueous solution, and

aii) a second amine component consisting of one or more sterically hindered amines in an amount of from 15-30 wt. % of the total amine content in the aqueous solution,

b) bringing the fluid stream into contact with the absorbent at a partial pressure of the sour gases of <

200 mbar in the fluid stream, absorbing the sour gases and producing an absorbent laden with sour gases,

c) heating the absorbent laden with sour gases to remove sour gases from the absorbent, and cooling

d) recycling the cooled absorbent to step a).

10. The method of claim 7, wherein the first amine component consists of 1,3-diaminopropane.