Heat transfer compositions

• US 8,926,856 B2
• Filed: 07/19/2013
• Issued: 01/06/2015
• Est. Priority Date: 02/16/2010
• Status: Active Grant

• Current Assignee: Mexichem, S.A.B. De C.V. (Orbia Advance Corporation, S.A.B. de C.V.)
• Original Assignee: Mexichem, S.A.B. De C.V. (Orbia Advance Corporation, S.A.B. de C.V.)
• Inventors: Low, Robert E.
• Primary Examiner(s): MC GINTY, DOUGLAS J
• Application Number:
  US13/946,697
• Publication Number:
  US 20130325732A1
• Time in Patent Office: 536 Days
• Field of Search: 252/67, 252/68, 252/69, 252/364, 521/131, 621/14, 134/36, 605/31
• US Class Current: 252/67
• CPC Class Codes: A23L 27/11 obtained by solvent extraction
• CPC Class Codes: C08J 9/146 only fluorine as halogen atoms
• CPC Class Codes: C09K 2205/126 Unsaturated fluorinated hydrocarbons
• CPC Class Codes: C09K 2205/22 All components of a mixture being fluoro compounds
• CPC Class Codes: C09K 3/00 Materials not provided for elsewhere
• CPC Class Codes: C09K 3/30 for aerosols aerosol containers B65D83/14
• CPC Class Codes: C09K 5/045 containing only fluorine as halogen
• CPC Class Codes: C11B 9/025 Recovery by solvent extraction
• CPC Class Codes: C11D 3/43 Solvents
• CPC Class Codes: F01K 25/08 using special vapours
• CPC Class Codes: F25B 45/00 Arrangements for charging or discharging refrigerant
• CPC Class Codes: F28C 3/06 the heat-exchange media being a liquid and a gas or vapour temperators for cooling steam F22
• CPC Class Codes: G06Q 30/018 Certifying business or products
• CPC Class Codes: Y02A 40/963 Off-grid food refrigeration

Abstract

A heat transfer composition comprising trans-1,3,3,3-tetrafluoropropene (R-1234ze(E)), difluoromethane (R-32) and 1,1-difluoroethane (R-152a).

Claims

1. A heat transfer composition comprising trans-1,3,3,3-tetrafluoropropene (R-12342e(E)), difluoromethane (R-32) and 1,1-difluoroethane (R-152a), wherein the composition has a fluorine ratio (F/(F+H)) of from about 0.42 to about 0.65 wherein the composition comprises substantially no pentafluoropropene (R-1225).

2. A composition according to claim 1 wherein the fluorine ratio is greater than about 0.44.

3. A composition according to claim 1 comprising from about 2 to about 25 by weight R-32, from about 5 to about 45% by weight of R-152a and from about 60 to about 95 by weight R-1234ze(E).

4. A composition according to claim 1 consisting essentially of R-32, R-152a and R-1234ze(E).

5. A composition according to claim 1 further comprising 1,1,1,2-tetrafluoroethane (R-134a).

6. A composition according to claim 5 comprising up to about 50% by weight of R-134a.

7. A composition according to claim 6 comprising from about 2 to about 15 by weight R-32, from about 5 to about 45% by weight R-152a, from about 25 to about 50% R-134a, and from about 5 to about 70% by weight R-1234ze(E).

8. A composition according to claim 6 consisting essentially of R-32, R-152a, R-12342e(E) and R-134a.

9. A composition according to claim 1 wherein the composition is less flammable than R-1234yf alone.

10. A composition according to claim 9 wherein the composition has:

(a) a higher flammable limit;

(b) a higher ignition energy; and

/or

(c) a lower flame velocity

compared to R-1234yf alone.

11. A composition according to claim 9 which is non-flammable at 23°

C.

12. A composition comprising a lubricant and a composition according to claim 1.

13. A composition according to claim 12, wherein the lubricant is selected from mineral oil, silicone oil, polyalkyl benzenes (PABs), polyol esters (POEs), polyalkylene glycols (PAGs), polyalkylene glycol esters (PAG esters), polyvinyl ethers (PVEs), poly (alpha-olefins) and combinations thereof.

14. A composition according to claim 12 further comprising a stabiliser.

15. A composition according to claim 14, wherein the stabiliser is selected from diene-based compounds, phosphates, phenol compounds and epoxides, and mixtures thereof.

16. A composition comprising a flame retardant and a composition according to claim 1.

17. A composition according to claim 16, wherein the flame retardant is selected from the group consisting of tri-(2-chloroethyl)-phosphate, (chloropropyl) phosphate, tri-(2,3-dibromopropyl)-phosphate, tri-(1,3-dichloropropyl)-phosphate, diammonium phosphate, various halogenated aromatic compounds, antimony oxide, aluminium trihydrate, polyvinyl chloride, a fluorinated iodocarbon, a fluorinated bromocarbon, trifluoro iodomethane, perfluoroalkyl amines, bromo-fluoroalkyl amines and mixtures thereof.

18. A heat transfer device containing a composition as defined in claim 1.

19. A heat transfer device according to claim 18 which is a refrigeration device.

20. A heat transfer device according to claim 19 which is selected from group consisting of automotive air conditioning systems, residential air conditioning systems, commercial air conditioning systems, residential refrigerator systems, residential freezer systems, commercial refrigerator systems, commercial freezer systems, chiller air conditioning systems, chiller refrigeration systems, and commercial or residential heat pump systems.

21. A heat transfer device according to claim 19 which contains a compressor.

22. A blowing agent comprising a composition as defined in claim 1.

23. A foamable composition comprising one or more components capable of forming foam and a composition as defined in claim 1, wherein the one or more components capable of forming foam are selected from polyurethanes, thermoplastic polymers and resins, such as polystyrene, and epoxy resins, and mixtures thereof.

24. A foam comprising a composition as defined in claim 1.

25. A sprayable composition comprising material to be sprayed and a propellant comprising a composition as defined in claim 1.

26. A method for cooling an article which comprises condensing a composition as defined in claim 1 and thereafter evaporating the composition in the vicinity of the article to be cooled.

27. A method for heating an article which comprises condensing a composition as defined in claim 1 in the vicinity of the article to be heated and thereafter evaporating the composition.

28. A method for extracting a substance from biomass comprising contacting biomass with a solvent comprising a composition as defined in claim 1, and separating the substance from the solvent.

29. A method of cleaning an article comprising contacting the article with a solvent comprising a composition as defined in claim 1.

30. A method of extracting a material from an aqueous solution or a particulate solid matrix comprising contacting the aqueous solution or the particulate solid matrix with a solvent comprising a composition as defined in claim 1, and separating the material from the solvent.

31. A mechanical power generation device containing a composition as defined in claim 1.

32. A mechanical power generating device according to claim 31 which is adapted to use a Rankine Cycle or modification thereof to generate work from heat.

33. A method of retrofitting a heat transfer device comprising the step of removing an existing heat transfer fluid, and introducing a composition as defined in claim 1.

34. A method of claim 33 wherein the heat transfer device is a refrigeration device.

35. A method according to claim 34 wherein the heat transfer device is an air conditioning system.

36. A method for reducing the environmental impact arising from the operation of a product comprising an existing compound or composition, the method comprising replacing at least partially the existing compound or composition with a composition as defined in claim 1.

37. A method for preparing a composition as defined in claim 1, which composition contains R-134a, the method comprising introducing R-1234ze(E), R-32, and R-152a, and optionally a lubricant, a stabiliser and/or a flame retardant, into a heat transfer device containing an existing heat transfer fluid which is R-134a.

38. A method according to claim 37 comprising the step of removing at least some of the existing R-134a from the composition before introducing the R-1234ze(E), R-32, and R-152a, and optionally the lubricant, the stabiliser and/or the flame retardant.

39. A method for generating greenhouse gas emission credit comprising (i) replacing an existing compound or composition with a composition as defined in claim 1, wherein the composition as defined in claim 1 has a lower GWP than the existing compound or composition;

and (ii) obtaining greenhouse gas emission credit for said replacing step.

40. A method of claim 39 wherein the use of the composition of the invention results in a lower Total Equivalent Warming Impact, and/or a lower Life-Cycle Carbon Production than is be attained by use of the existing compound or composition.

41. A method of claim 39 carried out on a product from the fields of air-conditioning, refrigeration, heat transfer, blowing agents, aerosols or sprayable propellants, gaseous dielectrics, cryosurgery, veterinary procedures, dental procedures, fire extinguishing, flame suppression, solvents, cleaners, air horns, pellet guns, topical anesthetics, and expansion applications.

42. A method according to claim 36 wherein the product is selected from a heat transfer device, a blowing agent, a foamable composition, a sprayable composition, a solvent or a mechanical power generation device.

43. A method according to claim 42 wherein the product is a heat transfer device.

44. A method according to claim 36 wherein the existing compound or composition is a heat transfer composition.

45. A method according to claim 44 wherein the heat transfer composition is a refrigerant selected from R-134a, R-1234yf and R-152a.