Multilayer polyurethane protective films

• US 8,927,106 B2
• Filed: 04/02/2014
• Issued: 01/06/2015
• Est. Priority Date: 04/29/2005
• Status: Active Grant

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Ho, Charlie C., Halford, Kenneth J.
• Primary Examiner(s): Shah, Samir
• Application Number:
  US14/243,335
• Publication Number:
  US 20140212674A1
• Time in Patent Office: 279 Days
• Field of Search: 428/343, 428/423.3, 428/412, 428/354, 524/589, 524/590
• US Class Current: 428/423.3
• CPC Class Codes: B32B 2250/03 3 layers
• CPC Class Codes: B32B 2250/24 All layers being polymeric
• CPC Class Codes: B32B 2307/402 Coloured
• CPC Class Codes: B32B 2307/412 Transparent
• CPC Class Codes: B32B 2405/00 Adhesive articles, e.g. adhesive tapes
• CPC Class Codes: B32B 2571/00 Protective equipment
• CPC Class Codes: B32B 2571/02 defensive, e.g. armour plates or anti-ballistic clothing
• CPC Class Codes: B32B 2605/00 Vehicles
• CPC Class Codes: B32B 2605/12 Ships
• CPC Class Codes: B32B 2605/18 Aircraft
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/16 specially treated, e.g. irradiated
• CPC Class Codes: B32B 27/34 comprising polyamides
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: B32B 27/40 comprising polyurethanes
• CPC Class Codes: B32B 37/15 with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
• CPC Class Codes: B32B 37/153 at least one layer is extruded and immediately laminated while in semi-molten state
• CPC Class Codes: B32B 37/24 with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate B32B37/15 takes precedence
• CPC Class Codes: B32B 38/0008 Electrical discharge treatment, e.g. corona, plasma treatment; wave energy or particle radiation heat treatment B32B38/0036
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: C09J 2203/306 : for protecting painted surfaces, e.g. of cars
• CPC Class Codes: C09J 2301/162 : the carrier being a laminate constituted by plastic layers only
• CPC Class Codes: C09J 2475/006 : in the substrate
• CPC Class Codes: C09J 7/25 : based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
• CPC Class Codes: C09J 7/255 : Polyesters
• CPC Class Codes: C09J 7/29 : Laminated material metallised plastics C09J7/22
• CPC Class Codes: Y10T 156/10 : Methods of surface bonding and/or assembly therefor
• CPC Class Codes: Y10T 428/2848 : Three or more layers
• CPC Class Codes: Y10T 428/31507 : Of polycarbonate
• CPC Class Codes: Y10T 428/31554 : Next to second layer of polyamidoester

Abstract

A multilayer protective film comprising a first layer, a second layer and a PSA layer. The first layer at least comprises a polyester-based polyurethane, a polycarbonate-based polyurethane or a combination or blend of both. The second layer at least comprises a polycaprolactone-based thermoplastic polyurethane. The PSA layer comprises a pressure sensitive adhesive. One major surface of the first layer is bonded to one major surface of the second layer, and the PSA layer is bonded to an opposite major surface of the second layer such that the second layer is sandwiched between the first layer and the PSA layer.

Claims

1. A vehicle comprising a body part having a painted surface, with said painted surface being protected by a multilayer protective film comprising:

a first layer comprising a polyurethane, said polyurethane being a polyester-based polyurethane, a polycarbonate-based polyurethane or a combination of both;

a second layer comprising a polycaprolactone-based thermoplastic polyurethane; and

a PSA layer comprising a pressure sensitive adhesive,

wherein said first layer is bonded to one major surface of said second layer and said PSA layer is bonded to an opposite major surface of said second layer such that said second layer is sandwiched between said first layer and said PSA layer.

2. The vehicle according to claim 1, wherein said polyurethane is the reaction product of a polyol and a mixture of a diisocyanate and an aliphatic triisocyanate.

3. The vehicle according to claim 2, wherein said diisocyanate is an aliphatic diisocyanate.

4. The vehicle according to claim 1, wherein said polyurethane is said polyester-based polyurethane.

5. The vehicle according claim 1, wherein said polyurethane is an aliphatic polyurethane.

6. The vehicle according claim 1, wherein said polyurethane is a slightly crosslinked polyurethane.

7. The vehicle according to claim 1, wherein said polyurethane is a water-based polyurethane.

8. The vehicle according to claim 1, wherein said polyurethane is a solvent-based polyurethane.

9. The vehicle according to claim 1, wherein the opposite major surface of said second layer is corona treated.

10. The vehicle according to claim 1, wherein said multilayer protective film is colored.

11. A method of making a multilayer protective film, said method comprising:

(a) forming a first layer comprising a polyurethane, the polyurethane being a polyester-based polyurethane, a polycarbonate-based polyurethane or a combination of both;

(b) forming a second layer comprising a polycaprolactone-based thermoplastic polyurethane;

(c) forming a PSA layer comprising a pressure sensitive adhesive;

(d) bonding one major surface of the first layer to one major surface of the second layer; and

(e) bonding the PSA layer to an opposite major surface of the second layer,

wherein the second layer is sandwiched between the first layer and the PSA layer.

12. The method according to claim 11, wherein said forming the first layer further comprises:

coating an aqueous-based polyurethane dispersion onto a releasable carrier web.

13. The method according to claim 11, wherein said forming the first layer further comprises:

coating a solvent-based polyurethane solution onto a releasable carrier web.

14. The method according to claim 11, wherein said forming the second layer further comprises:

extruding the polycaprolactone-based thermoplastic polyurethane at an elevated temperature through a die to form the second layer.

15. The method according to claim 14, wherein said bonding the first layer further comprises:

laminating the one major surface of the first layer to the one major surface of the second layer, after said extruding and while the one major surface of the second layer is at an elevated temperature that is sufficiently higher than room temperature to facilitate adequate bonding between the first layer and the second layer.

16. The method according to claim 14, wherein said bonding the first layer further comprises:

laminating one major surface of the first layer to one major surface of the second layer after said extruding and with at least the one major surface of the first layer and the second layer being at a temperature that is too low to facilitate adequate bonding between the first layer and the second layer; and

heating the one major surface of the second layer to an elevated temperature that is sufficiently higher than room temperature to facilitate adequate bonding between the first layer and the second layer during said laminating,

wherein said heating occurs before or during said laminating.

17. The method according to claim 16, further comprising:

releasably laminating an opposite major surface of the second layer to a releasable carrier web after said extruding.

18. The method according to claim 11, further comprising:

corona treating the opposite major surface of the second layer.

19. The method according to claim 11, wherein the first layer and the second layer are bonded so that the one major surface of the first layer contacts the one major surface of the second layer.