System for harvesting oriented light—water splitting

• US 8,936,734 B2
• Filed: 03/11/2013
• Issued: 01/20/2015
• Est. Priority Date: 12/20/2012
• Status: Expired due to Fees

• Current Assignee: Sunpower Technologies LLC
• Original Assignee: Sunpower Technologies LLC
• Inventors: Landry, Daniel, Jennings, Travis
• Primary Examiner(s): Mayes, Melvin C
• Assistant Examiner(s): CALL, DOUGLAS BRYANT
• Application Number:
  US13/792,698
• Publication Number:
  US 20140252275A1
• Time in Patent Office: 680 Days
• US Class Current: 252/372
• CPC Class Codes: B01J 19/127 Sunlight; Visible light
• CPC Class Codes: C01B 3/042 Decomposition of water
• CPC Class Codes: C01B 3/06 by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by electrolysis of water C25B1/04
• CPC Class Codes: G02B 26/0816 by means of one or more reflecting elements
• CPC Class Codes: G02B 5/3066 involving the reflection of light at a particular angle of incidence, e.g. Brewster's angle
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

A system and method for splitting water to produce hydrogen and oxygen employing focused polarized sunlight energy is disclosed. Hydrogen and oxygen may then be stored for later use as fuels. The system and method use inorganic capping agents that cap the surface of semiconductor nanocrystals to form photocatalytic capped colloidal nanocrystals, which may be deposited and oriented on a substrate to form an oriented photoactive material. The oriented photoactive material may be employed in the system to harvest sunlight and produce energy necessary for water splitting. The system may also include a light polarization system and elements necessary to collect, transfer, and store hydrogen and oxygen, for subsequent transformation into electrical energy.

Claims

1. A method of water splitting comprising:

forming photocatalytic capped colloidal nanocrystals, wherein each photocatalytic capped colloidal nanocrystal includes a first semiconductor nanocrystal capped with a first inorganic capping agent;

depositing the formed photocatalytic capped colloidal nanocrystals onto a substrate;

orienting the photocatalytic capped colloidal nanocrystals, wherein the oriented photocatalytic capped colloidal nanocrystals are included in a reaction vessel;

linearly polarizing irradiated sunlight with at least one reflective surface kept at a Brewster'"'"'s angle relative to the irradiated sunlight;

absorbing the irradiated sunlight with an energy equal to or greater than the band gap of the semiconductor nanocrystals by the photocatalytic capped colloidal nanocrystals to create charge carriers in a conduction band of the photocatalytic capped colloidal nanocrystals and holes in a valence band of the photocatalytic capped colloidal nanocrystals;

passing water through the reaction vessel so that the water reacts with the photocatalytic capped colloidal nanocrystals and forms hydrogen gas and oxygen gas, wherein the charge carriers in the conduction band reduce hydrogen molecules from the water and the holes oxidize oxygen molecules from the water; and

collecting the hydrogen gas and the oxygen gas in a reservoir that includes a hydrogen permeable membrane and an oxygen permeable membrane.

2. The method of claim 1, wherein the at least one reflective surface is at least one mirror, the method further comprising:

polarizing the irradiated sunlight with the at least one mirror before the photocatalytic capped colloidal nanocrystals absorb the irradiated sunlight.

3. The method of claim 2, further comprising:

steering the at least one mirror so that the at least one mirror maintains the Brewster'"'"'s angle relative to the irradiated sunlight.

4. The method of claim 3, wherein the at least one mirror is steered using a sun tracking system.

5. The method of claim 3, further comprising focusing the polarized sunlight with a focusing mirror.

6. The method of claim 3, further comprising:

steering a second mirror so that the polarized sunlight is directed at the oriented photocatalytic capped colloidal nanocrystals at an angle that facilitates optimal absorption.

7. The method of claim 1, wherein forming photocatalytic capped colloidal nanocrystals comprises:

growing semiconductor nanocrystals by employing a template-driven seeded growth method; and

capping the semiconductor nanocrystals with an inorganic capping agent in a polar solvent to form photocatalytic capped colloidal nanocrystals.

8. The method of claim 7, wherein growing semiconductor nanocrystals by employing the template-driven seeded growth method comprises:

depositing a seed crystal on a substrate; and

growing the semiconductor nanocrystal from the seed crystal using molecular beam epitaxy or chemical beam epitaxy so that the semiconductor nanocrystal grows according to the seed crystal'"'"'s structure.

9. The method of claim 7, wherein capping the semiconductor nanocrystals with an inorganic capping agent in the polar solvent to form the photocatalytic capped colloidal nanocrystals comprises:

reacting semiconductor nanocrystals precursors in the presence of an organic capping agent to form organic capped semiconductor nanocrystals;

reacting the organic capped semiconductor nanocrystals with an inorganic capping agent;

adding immiscible solvents causing the dissolution of the organic capping agents and the inorganic capping agents so that organic caps on the semiconductor nanocrystals are replaced by inorganic caps to form inorganic capped semiconductor nanocrystals; and

performing an isolation procedure to purify the inorganic capped semiconductor nanocrystals and remove the organic capping agent.

10. The method of claim 1, wherein orienting the photocatalytic capped colloidal nanocrystals is performed by applying an electric field, and the direction of the electric field is substantially parallel with a desired electric dipole moment of the photocatalytic capped colloidal nanocrystals.

11. The method of claim 4, wherein the photocatalytic capped colloidal nanocrystals include charged ligands that assist in controlling the orientation of the photocatalytic capped colloidal nanocrystals.

12. The method of claim 1, wherein orienting the photocatalytic capped colloidal nanocrystals is performed by a combing deposition technique.

13. The method of claim 1, wherein orienting the photocatalytic capped colloidal nanocrystals is performed by employing a Langmuir Blodgett method to form a Langmuir Blodgett film.

14. The method of claim 1, wherein the photocatalytic capped colloidal nanocrystals comprises one compound selected from a group consisting of ZnS.TiO2, TiO2.CuO, ZnS.RuOx, ZnS.ReOx, Au.AsS3, Au.Sn2S6, Au.SnS4, Au.Sn2Se6, Au.In2Se4, Bi2S3.Sb2Te5, Bi2S3.Sb2Te7, Bi2Se3.Sb2Te5, Bi2Se3.Sb2Te7, CdSe.Sn2S6, CdSe.Sn2Te6, CdSe.In2Se4, CdSe.Ge2S6, CdSe.Ge2Se3, CdSe.HgSe2, CdSe.ZnTe, CdSe.Sb2S3, CdSe.SbSe4, CdSe.Sb2Te7, CdSe.In2Te3, CdTe.Sn2S6, CdTe.Sn2Te6, CdTe.In2Se4, Au/PbS.Sn2S6, Au/PbSe.Sn2S6, Au/PbTe.Sn2S6, Au/CdS.Sn2S6, Au/CdSe.Sn2S6, Au/CdTe.Sn2S6, FePt/PbS.Sn2S6, FePt/PbSe.Sn2S6, FePt/PbTe.Sn2S6, FePt/CdS.Sn2S6, FePt/CdSe.Sn2S6, FePt/CdTe.Sn2S6, Au/PbS.SnS4, Au/PbSe.SnS4, Au/PbTe.SnS4, Au/CdS.SnS4, Au/CdSe.SnS4, Au/CdTe.SnS4, FePt/PbS.SnS4 FePt/PbSe.SnS4, FePt/PbTe.SnS4, FePt/CdS.SnS4, FePt/CdSe.SnS4, FePt/CdTe.SnS4, Au/PbS.In2Se4 Au/PbSe.In2Se4, Au/PbTe.In2Se4, Au/CdS.In2Se4, Au/CdSe.In2Se4, Au/CdTe.In2Se4, FePt/PbS.In2Se4 FePt/PbSe.In2Se4, FePt/PbTe.In2Se4, FePt/CdS.In2Se4, FePt/CdSe.In2Se4, FePt/CdTe.In2Se4, CdSe/CdS.Sn2S6, CdSe/CdS.SnS4, CdSe/ZnS.SnS4,CdSe/CdS.Ge2S6, CdSe/CdS.In2Se4, CdSe/ZnS.In2Se4, Cu.In2Se4, Cu2Se.Sn2S6, Pd.AsS3, PbS.SnS4, PbS.Sn2S6, PbS.Sn2Se6, PbS.In2Se4, PbS.Sn2Te6, PbS.AsS3, ZnSe.Sn2S6, ZnSe.SnS4, ZnS.Sn2S6, and ZnS.SnS4.

15. The method of claim 1, wherein a shape of the photocatalytic capped colloidal nanocrystals is chosen based on a desired wavelength of the irradiated sunlight usable by the semiconductor nanocrystals.

16. The method of claim 1, further comprising:

recycling the unreacted water by passing unreacted water in the reservoir back into the reaction vessel.

17. The method of claim 1, further comprising:

heating the water entering the reaction vessel so that the water boils and is in a gaseous state when reacting with the photocatalytic capped colloidal nanocrystals in the reaction vessel.

18. The method of claim 1, further comprising:

filtering the unreacted water, the hydrogen gas, and the oxygen gas leaving the reaction vessel.

19. The method of claim 1, wherein each photocatalytic capped colloidal nanocrystals includes a second semiconductor nanocrystal capped with a second inorganic capping agent, the first inorganic capping agent acts as a reduction photocatalyst, and the second inorganic capping agent acts as an oxidation photocatalyst.