Method of fabricating structured particles composed of silicon or a silicon-based material and their use in lithium rechargeable batteries

• US 8,940,437 B2
• Filed: 07/17/2008
• Issued: 01/27/2015
• Est. Priority Date: 07/17/2007
• Status: Active Grant

• Current Assignee: Nexeon Limited
• Original Assignee: Nexeon Limited
• Inventors: Green, Mino, Liu, Feng-Ming
• Primary Examiner(s): Crepeau, Jonathan
• Assistant Examiner(s): Buchanan, Jacob
• Application Number:
  US12/669,216
• Publication Number:
  US 20100178565A1
• Time in Patent Office: 2,385 Days
• Field of Search: 429/209, 429/218.1, 429/231.9, 429/231.95
• US Class Current: 429/218.1
• CPC Class Codes: H01M 10/52 Removing gases inside the secondary cell, e.g. by absorption vent plugs or other mechanical arrangements for facilitating escape of gases H01M50/30
• CPC Class Codes: H01M 2004/027 Negative electrodes
• CPC Class Codes: H01M 4/0492 Chemical attack of the support material
• CPC Class Codes: H01M 4/134 Electrodes based on metals, Si or alloys
• CPC Class Codes: H01M 4/1395 of electrodes based on metals, Si or alloys
• CPC Class Codes: H01M 4/386 Silicon or alloys based on silicon
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y10T 117/102 for forming a platelet shape or a small diameter, elongate, generally cylindrical shape [e.g., whisker, fiber, needle, filament]
• CPC Class Codes: Y10T 29/49108 Electric battery cell making
• CPC Class Codes: Y10T 428/2982 Particulate matter [e.g., sphere, flake, etc.]

Abstract

Pillared particles of silicon or silicon-comprising material and a method of fabricating the same are disclosed. These particles may be used to create both a composite anode structure with a polymer binder, a conductive additive and a metal foil current collector, and an electrode structure. The structure of the particles overcomes the problems of charge/discharge capacity loss.

Claims

1. A plurality of discrete particles, wherein each particle comprises silicon, including a silicon-comprising particle core, and a plurality of silicon-comprising pillars extending outwardly therefrom from a first end to a second end, wherein each pillar in the plurality of pillars is attached to the core at the first end of the pillar, and the second end of each pillar is an unattached free end, wherein in each particle, the fraction of the surface area of the particle core occupied by the pillars is in the range of 0.10 to 0.50.

2. A plurality of discrete particles as claimed in claim 1 in which each pillar has a diameter in the range of 0.08 to 0.70 microns.

3. A plurality of discrete particles as claimed in claim 1 in which each pillar has a length from the first end to the second end in the range of 4 to 100 microns.

4. A plurality of discrete particles as claimed in claim 1 in which the pillars have an aspect ratio of greater than 20:

1.

5. A plurality of discrete particles as claimed in claim 1 in which the pillars have a substantially non-circular cross-section and/or are irregular.

6. A plurality of discrete particles as claimed in claim 1 in which the particles and/or pillars comprise n-type silicon, p-type silicon, undoped silicon or a silicon germanium mixture.

7. A plurality of discrete particles as claimed in claim 1 wherein the silicon content is 90.00 to 99.95% by mass.

8. A plurality of discrete particles as claimed in claim 1 wherein the fraction of the surface area of the particle core occupied by pillars is in the range of 0.20 to 0.40.

9. A plurality of discrete particles as claimed in claim 1 in which the pillars in the plurality of pillars coat one or more surfaces of the particle.

10. A plurality of discrete particles as claimed in claim 1 wherein the particles comprise metallurgical grade silicon.

11. A plurality of discrete particles as claimed in claim 1 wherein the plurality of pillars extending outwardly from the particle core are defined in an array which is one of regular and irregular.

12. A composite electrode for a lithium-ion battery comprising a plurality of discrete particles as claimed in claim 1 and further comprising at least one of a conductive additive and a binder.

13. A battery comprising the plurality of discrete particles as claimed in claim 1.

14. A plurality of discrete particles as claimed in claim 1 wherein the plurality of particles is in the form of a powder.

15. A plurality of discrete particles as claimed in claim 1, wherein each particle consists essentially of the particle core and the plurality of silicon-comprising pillars.

16. A plurality of discrete particles as claimed in claim 1, wherein in each particle the pillars are capable of being lithiated and delithiated.

17. A plurality of discrete particles as claimed in claim 1, wherein each particle has a diameter of at least 0.5 μ

m.

18. A plurality of discrete particles wherein each particle comprises silicon and includes a particle core and a plurality of silicon-comprising pillars fabricated on the particle core and extending outwardly therefrom from a first end to a second end, wherein each pillar in the plurality of pillars is attached to the core at the first end of the pillar, and the second end of each pillar is an unattached free end, wherein in each particle, the fraction of the surface area of the particle core occupied by the pillars is in the range of 0.10 to 0.50.

19. A plurality of discrete particles as claimed in claim 18 wherein the particles have a first dimension in the range of 10 μ

m to 1 mm.

20. A composite electrode for a lithium-ion battery comprising a plurality of discrete particles as claimed in claim 18 and further comprising at least one of a conductive additive and a binder.

21. A plurality of discrete particles wherein each particle comprises silicon and includes a particle core and a plurality of silicon-comprising pillars extending outwardly therefrom from a first end to a second end, wherein each pillar in the plurality of pillars is attached to the core at the first end of the pillar, and the second end of each pillar is an unattached free end, wherein in each particle, the fraction of the surface area of the particle core occupied by the pillars is in the range of 0.10 to 0.50.

22. A plurality of discrete particles as claimed in claim 21 wherein the pillars are integral with the core.

23. A composite electrode for a lithium-ion battery comprising a plurality of discrete particles as claimed in claim 21 and further comprising at least one of a conductive additive and binder.