Cement composition containing an additive of a pozzolan and a strength retrogression inhibitor

• US 8,944,165 B2
• Filed: 01/11/2013
• Issued: 02/03/2015
• Est. Priority Date: 01/11/2013
• Status: Expired due to Fees

• Current Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Original Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Inventors: Patil, Rahul C., Muthusamy, Ramesh, Singh, Sheetal, Deshpande, Abhimanyu
• Primary Examiner(s): DiTrani, Angela M
• Assistant Examiner(s): SUE-AKO, ANDREW B.
• Application Number:
  US13/739,992
• Publication Number:
  US 20140196901A1
• Time in Patent Office: 753 Days
• Field of Search: None
• US Class Current: 166/292
• CPC Class Codes: C04B 14/00 Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone expanding or defibrillating materials C04B20/00
• CPC Class Codes: C04B 18/025 Grog
• CPC Class Codes: C04B 2103/0088 Compounds chosen for their latent hydraulic characteristics, e.g. pozzuolanes
• CPC Class Codes: C04B 2111/00215 Mortar or concrete mixtures defined by their oxide composition
• CPC Class Codes: C04B 28/04 Portland cements
• CPC Class Codes: C09K 8/467 containing additives for specific purposes
• CPC Class Codes: E21B 33/13 Methods or devices for cementing, for plugging holes, crevices or the like

Abstract

A cement composition comprises: cement; water; and an additive, wherein the additive is a pozzolan and a strength-retrogression inhibitor, and wherein a mixture consisting essentially of: the additive; water; and a source of calcium develops a compressive strength of at least 500 psi at a time of 24 hours, a temperature of 190° F., and a pressure of 3,000 psi. A method of cementing in a subterranean formation comprises: introducing the cement composition into the subterranean formation and allowing the cement composition to set. The compressive strength of the test cement composition consisting essentially of: the cement; the water; and the additive at a final time of 72 hours has a percent change greater than −5% from the compressive strength of the test cement composition at an initial time of 24 hours when tested at a temperature of 300° F. and a pressure of 3,000 psi.

Claims

1. A method of cementing in a subterranean formation comprising:

introducing a cement composition into the subterranean formation, wherein the cement composition comprises;

cement;

water; and

an additive, wherein the additive;

is a pozzolan and a strength-retrogression inhibitor;

is a red brick powder; and

comprises at least the compounds silicon dioxide (SiO₂), iron III oxide (Fe₂O₃), and aluminum oxide (Al₂O₃), wherein the SiO₂ is in a concentration in the range of about 40% to about 60% of the total chemical composition of the additive;

the Fe₂O₃ is in a concentration in the range of about 15% to about 25% of the total chemical composition of the additive; and

the Al₂O₃ is in a concentration in the range of about 5% to about 15% of the total chemical composition of the additive,

wherein a mixture consisting essentially of;

the additive;

water; and

a source of calcium develops a compressive strength of at least 500 psi (3.4 MPa) at a time of 24 hours, a temperature of 190°

F. (88°

C.), and a pressure of 3,000 psi (20.7 MPa); and

allowing the cement composition to set, wherein the step of allowing is performed after the step of introducing.

2. The method according to claim 1, wherein the cement is selected from the group consisting of Portland cements, gypsum cements, high alumina content cements, slag cements, high magnesia content cements, and combinations thereof.

3. The method according to claim 1, wherein the water is selected from the group consisting of freshwater, brackish water, saltwater, and any combination thereof.

4. The method according to claim 1, wherein the SiO₂, Fe₂O₃, and Al₂O₃ comprise at least 70% of the total chemical composition of the additive.

5. The method according to claim 1, wherein the concentration of the SiO₂, Fe₂O₃, and Al₂O₃ is a percentage such that the additive is a pozzolan and a strength retrogression inhibitor.

6. The method according to claim 1, wherein the ratio of SiO₂ to Fe₂O₃ to Al₂O₃ is in the range of 1:

0.2;

0.2 to 1;

0.35;

0.3.

7. The method according to claim 1, wherein the ratio of SiO₂ to Fe₂O₃ to Al₂O₃ is a ratio such that the additive is a pozzolan and a strength retrogression inhibitor.

8. The method according to claim 1, wherein the particle size of the additive is selected such that the mixture consisting essentially of:

the additive;

water; and

the source of calcium develops a compressive strength of at least 500 psi (3.4 MPa) at a time of 24 hours, a temperature of 190°

F. (88°

C.), and a pressure of 3,000 psi (20.7 MPa).

9. The method according to claim 1, wherein the particle size of the additive is selected such that the cement composition develops a compressive strength of at least 2,000 psi (13.8 MPa) at a time of 24 hours, a temperature of 190°

F. (88°

C.), and a pressure of 3,000 psi (20.7 MPa).

10. The method according to claim 1, wherein the additive has a particle size distribution such that at least 90% of the additive has a particle size in the range of about 30 microns to 75 microns.

11. The method according to claim 1, wherein the cement composition has a compressive strength in the range of −

20% to +20% compared to a control cement composition consisting of cement and water at any time, a temperature of 300°

F. (149°

C.), and a pressure of 3,000 psi (20.7 MPa).

12. The method according to claim 1, wherein the compressive strength of a test cement composition consisting of the cement, the water, and the additive, at a final time of 72 hours has a percent change greater than 20% from the compressive strength of the test cement composition at an initial time of 6 hours when tested at a temperature of 300°

F. (149°

C.) and a pressure of 3,000 psi (20.7 MPa).

13. The method according to claim 1, wherein the concentration of the additive is selected such that a percent change of the compressive strength of a test cement composition consisting of the cement, the water, and the additive or of the cement composition is greater than −

5% at a final time of 72 hours and an initial time of 24 hours.

14. The method according to claim 13, wherein the percent change is greater than +2%.

15. The method according to claim 1, wherein the additive is in a concentration in the range of about 2% to about 70% by weight of the cement.

16. The method according to claim 1, wherein the subterranean formation has a bottomhole temperature in the range of about 35°

F. (2°

C.) to about 450°

F. (232°

C.).

17. A method of cementing in a subterranean formation comprising:

introducing a cement composition into the subterranean formation, wherein the cement composition comprises;

cement;

water; and

an additive, wherein the additive;

is a pozzolan and a strength-retrogression inhibitor;

is a red brick powder; and

comprises at least the compounds silicon dioxide (SiO₂), iron III oxide (Fe₂O₃) and aluminum oxide (Al₂O₃), wherein the SiO₂ is in a concentration in the range of about 40% to about 60% of the total chemical composition of the additive;

the Fe₂O₃ is in a concentration in the range of about 15% to about 25% of the total chemical composition of the additive; and

the Al₂O₃ is in a concentration in the range of about 5% to about 15% of the total chemical composition of the additive, wherein a mixture consisting essentially of;

the additive;

water; and

a source of calcium develops a compressive strength of at least 500 psi (3.4 MPa) at a time of 24 hours, a temperature of 190°

F. (88°

C.), and a pressure of 3,000 psi (20.7 MPa),

wherein a test cement composition consisting essentially of;

the cement;

the water; and

the additive, and in the same proportions as in the cement composition develops a compressive strength of at least 1,800 psi (12.4 MPa) when tested at 24 hours, a temperature of 190°

F. (88°

C.), and a pressure of 3,000 psi (20.7 MPa), and wherein the compressive strength of the test cement composition at a final time of 72 hours has a percent change greater than −

5% from the compressive strength of the test cement composition at an initial time of 24 hours when tested at a temperature of 300°

F. (149°

C.) and a pressure of 3,000 psi (20.7 MPa); and

allowing the cement composition to set, wherein the step of allowing is performed after the step of introducing.

18. A method of cementing in a subterranean formation comprising:

introducing a cement composition into the subterranean formation, wherein the cement composition comprises;

cement;

water; and

an additive, wherein the additive is a pozzolan and a strength-retrogression inhibitor, wherein the additive includes at least the compounds silicon dioxide (SiO₂), iron III oxide (Fe₂O₃), and aluminum oxide (Al₂O₃), and wherein the ratio of SiO₂ to Fe₂O₃ to Al₂O₃ is in the range of 1;

0.2;

0.2 to 1;

0.35;

0.3; and

allowing the cement composition to set, wherein the step of allowing is performed after the step of introducing.