Materials and architectures for efficient harvesting of singlet and triplet excitons for white light emitting OLEDs

• US 8,945,722 B2
• Filed: 10/27/2006
• Issued: 02/03/2015
• Est. Priority Date: 10/27/2006
• Status: Active Grant

• Current Assignee: Board of Regents of the University of Michigan (University of Michigan), University of Southern California
• Original Assignee: Board of Regents of the University of Michigan (University of Michigan), University of Southern California
• Inventors: Thompson, Mark E., Forrest, Stephen
• Primary Examiner(s): Bohaty, Andrew K
• Application Number:
  US11/588,619
• Publication Number:
  US 20080102310A1
• Time in Patent Office: 3,021 Days
• Field of Search: None
• US Class Current: 428/690
• CPC Class Codes: H10K 2101/10 Triplet emission
• CPC Class Codes: H10K 50/11 characterised by the electroluminescent [EL] layers
• CPC Class Codes: H10K 50/125 specially adapted for multicolour light emission, e.g. for emitting white light
• CPC Class Codes: Y10S 428/917 Electroluminescent
• CPC Class Codes: Y10T 428/31504 Composite [nonstructural laminate]

Abstract

The present invention relates to organic light emitting devices (OLEDs), and more specifically to OLEDS that emit light using a combination of fluorescent emitters and phosphorescent emitters for the efficient utilization of all of the electrically generated excitons.

Claims

1. An organic light emitting device comprising:

a cathode,

an emissive region, and

an anode

wherein,

the emissive region consists of;

a fluorescent layer comprising a fluorescent emitting dopant, and a charge-transporting dopant in a host material,

one or more phosphorescent layers, each comprising a phosphorescent emitting dopant, and a charge-transporting dopant in a host material, and

an optional spacer layer between the fluorescent layer and a phosphorescent layer comprising a charge-transporting dopant in a host material,

wherein the host material for the fluorescent layer, the host material for the phosphorescent layers and the host material for the spacer layer, if present, are the same material; and

wherein the charge-transporting dopant is a hole-transporting dopant or the charge-transporting dopant is an electron-transporting dopant, wherein if the charge-transporting dopant is a hole-transporting dopant, the HOMO level of the hole-transporting dopant is above and closer to the vacuum energy level than the HOMO level of the fluorescent emitting dopant and the HOMO level of the phosphorescent emitting dopant or if the charge-transporting dopant is an electron-transporting dopant, the LUMO level of the electron-transporting dopant is below the LUMO level of the fluorescent emitting dopant and the LUMO level of the phosphorescent emitting dopant, and wherein the triplet energy of the charge-transporting dopant is higher than the triplet energy of the host material.

2. The organic light emitting device of claim 1, wherein the charge-transporting dopant is a hole-transporting dopant.

3. The organic light emitting device of claim 1, wherein the charge-transporting dopant is the electron-transporting dopant.

4. The organic light emitting device of claim 1, wherein the emissive region consists of the fluorescent layer, the spacer layer and the one or more phosphorescent layers.

5. The organic light emitting device of claim 1, wherein the host material for the fluorescent layer, the host material for the phosphorescent layer and the spacer layer are comprised of CBP.

6. The device of claim 1, wherein the fluorescent emitting dopant is a blue emitting fluorescent material.

7. The organic light emitting device of claim 1, wherein greater than about 75% of the excitons are generated in the fluorescent layer.

8. The organic light emitting device of claim 2, wherein the hole transporting dopant for the fluorescent layer, the hole transporting dopant for the one or more phosphorescent layers and the hole transporting dopant for the optional spacer layer are comprised of the same material.

9. The device of claim 8, wherein the hole transporting dopant is

10. An organic light emitting device comprising:

a cathode,

an emissive region, and

an anode

wherein the emissive region consists of;

a fluorescent layer comprising a first fluorescent emitting dopant and a hole-transporting dopant in a host material,

a phosphorescent-sensitized fluorescent layer comprising a phosphorescent emitting dopant, a second fluorescent emitting dopant, and a hole-transporting dopant in a host material, and

an optional spacer layer between the fluorescent layer and a phosphorescent layer comprising a charge-transporting dopant in a host material; and

wherein the host material for the fluorescent layer, the host material for the phosphorescent-sensitized fluorescent layer and the host material for the space layer, if present, are the same material, wherein the HOMO level of the hole-transporting dopant is above and closer to the vacuum energy level than the HOMO level of the fluorescent emitting dopant and HOMO level of the phosphorescent emitting dopant, and wherein the triplet energy of the hole-transporting dopant is higher than the triplet energy of the host material.

11. The organic light emitting device of claim 10, wherein the emissive region consists of the fluorescent layer, the spacer layer and the phosphorescent-sensitized layer.

12. The organic light emitting device of claim 10, wherein the first fluorescent emitting dopant is a blue emitting fluorescent material.

13. The organic light emitting device of claim 12, wherein the phosphorescent emitting dopant is a green-emitting phosphorescent material and the second fluorescent emitting dopant is a red-emitting fluorescent dopant.