Implantable battery having thermal shutdown separator

• US 8,945,753 B2
• Filed: 01/26/2005
• Issued: 02/03/2015
• Est. Priority Date: 01/26/2005
• Status: Active Grant

• Current Assignee: Medtronic Incorporated (Medtronic Plc)
• Original Assignee: Medtronic Incorporated (Medtronic Plc)
• Inventors: Chen, Kaimin, Schmidt, Craig L., Skarstad, Paul M.
• Primary Examiner(s): Gilliam, Barbara
• Assistant Examiner(s): ROE, CLAIRE LOUISE
• Application Number:
  US11/043,301
• Publication Number:
  US 20060166078A1
• Time in Patent Office: 3,660 Days
• Field of Search: 429/48, 429/120, 429144-145, 428/315.7, 428/315.9, 428/316.6, 428/516, 427/115, 361/303, 361/508, 296231-6235, 29/250.3
• US Class Current: 429/129
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/4235 Safety or regulating additives or arrangements in electrodes, separators or electrolyte H01M10/4242 takes precedence
• CPC Class Codes: H01M 50/417 Polyolefins
• CPC Class Codes: H01M 50/457 comprising three or more layers
• CPC Class Codes: H01M 50/463 Separators, membranes or diaphragms characterised by their shape
• CPC Class Codes: H01M 50/489 Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
• CPC Class Codes: H01M 50/491 Porosity
• CPC Class Codes: H01M 6/16 with organic electrolyte H01M6/18 takes precedence
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y10T 428/24998 Composite has more than two layers

Abstract

The present teachings include an electrochemical cell including an anode, a cathode, an electrolyte, a separator disposed between the cathode and anode, and a housing containing the anode, cathode, electrolyte, and separator. The separator can include a first sheet consisting essentially of a single layer material and a second sheet distinct from the first sheet. The second sheet can include an inner microporous layer laminated between two more outer layers. In some cells, the inner layer can have a transition temperature between a porous configuration and a substantially non-porous configuration that is between about 80 degrees C. and 150 degrees C., and in which the two more outer layers maintain their structural integrity to at least about 10 degrees C. greater than the first layer transition temperature.

Claims

1. An electrode assembly comprising:

a first electrode;

a second electrode;

an electrolyte; and

a separator located between the first and second electrodes to prevent contact therebetween;

the separator comprising;

a first separator sheet disposed between the first electrode and the second electrode, the first separator sheet comprising two permeable outer layers each adhered to a microporous inner layer; and

a second separator sheet disposed between the first and second electrodes, the second sheet consisting essentially of a single permeable layer,

wherein the first separator sheet is separated from the second separator sheet by the electrolyte, and

wherein the first separator sheet microporous inner layer has a first configuration porous to ion flow and a second configuration less porous to ion flow than the first configuration, and a first transition temperature between about 80 and 150 degrees C. at which the microporous inner layer transforms from the first configuration to the second configuration, and in which the permeable outer layers maintain their structural integrity to a temperature of about 10 degrees C. higher than the first transition temperature.

2. The electrode assembly of claim 1, in which the first electrode comprises a cathode active material, the second electrode comprises an active anode material, and in which the first separator sheet microporous inner and permeable outer layers and the second separator sheet single permeable layer comprises a polymeric material.

3. The electrode assembly of claim 2, in which the first sheet is interposed between the first electrode and the second sheet.

4. The electrode assembly of claim 2, in which the first sheet is interposed between the second electrode and the second sheet.

5. The electrode assembly of claim 2, in which the first and second electrodes are rolled such that the first and second sheets form a spiral shape.

6. The electrode assembly of claim 2, in which the first electrode includes a plurality of electrode plates and the second electrode includes a plurality of electrode plates, in which the first and second separator sheets include a plurality of discrete sheet pairs interposed between the first and second electrodes.

7. An electrochemical cell comprising:

an anode including an active anode material in contact with an anode current collector;

a cathode including an active cathode material in contact with a cathode current collector;

a separator disposed between the anode and the cathode;

an electrolyte; and

a housing containing the anode, cathode, separator, and electrolyte, the separator comprising a first sheet consisting essentially of a single layer material and a second sheet distinct from the first sheet,

wherein the second sheet consists essentially of an inner microporous layer laminated between two outer layers, and

wherein the first sheet is separated from the second sheet by the electrolyte.

8. The electrochemical cell of claim 7, in which the microporous inner layer has a transition temperature between a porous configuration and a substantially non-porous configuration that is between about 80 degrees C. and 150 degrees C., and in which the two additional permeable outer layers maintain their structural integrity to at least about 10 degrees C. greater than the first layer transition temperature of the microporous inner layer.

9. The electrochemical cell of claim 8, in which the first sheet, and the two outer layers of the second sheet are substantially similar in terms of materials, dimensions, and/or properties independently.

10. The electrochemical cell of claim 8, in which the first sheet, and the two outer layers of the second sheet are substantially different from each other in terms of materials, dimensions, and/or properties independently.

11. The electrochemical cell of claim 8, in which the first sheet, and the two outer layers are all formed of polymeric materials.

12. The electrochemical cell of claim 8, in which the first sheet, and the two outer layers of the second sheet comprise polypropylene.

13. The electrochemical cell of claim 8, in which the second sheet microporous inner layer comprises polyethylene.

14. A battery comprising:

a plurality of anode layers;

a plurality of separator layers;

a plurality of cathode layers;

an electrolyte;

wherein the cathode and anode layers are configured as a stack having one of the plurality of separator layers disposed therebetween,

wherein the one of the plurality of separator layers includes a first sheet and a second sheet, the first sheet consisting essentially of a unitary polymeric material having an electrical resistivity of less than about 500 ohms per square centimeter, wherein the first sheet is separated from the second sheet by the electrolyte.

15. The battery of claim 14, in which the second sheet microporous inner layer comprises a polymeric material.

16. The battery of claim 15, in which the second sheet microporous inner layer polymeric material comprises polyethylene.

17. The battery of claim 14, in which the second separator sheet two additional permeable outer layers comprise polypropylene.

18. The battery of claim 14, in which the first separator sheet comprises a polymeric material.

19. The battery of claim 14, in which the first separator sheet comprises polypropylene.

20. The battery of claim 14, wherein the first separator sheet microporous inner layer has a first configuration porous to ion flow and a second configuration less porous to ion flow than the first configuration, and a first transition temperature between about 80 and 150 degrees C. at which the microporous inner layer transforms from the first configuration to the second configuration, and in which the permeable outer layers maintain their structural integrity to a temperature of about 10 degrees C. higher than the first transition temperature.