Aluminum alloys, aluminum alloy products and methods for making the same

• US 8,950,465 B2
• Filed: 12/03/2012
• Issued: 02/10/2015
• Est. Priority Date: 01/16/2009
• Status: Active Grant

• Current Assignee: Alcoa USA Corp. (Alcoa Corp.)
• Original Assignee: Alcoa Incorporated (Howmet Aerospace, Inc.)
• Inventors: Lin, Jen C., Fields, James R., Askin, Albert L., Yan, Xinyan, Sawtell, Ralph R., Sullivan, Shawn Patrick, Abbott, Janell Lyn
• Primary Examiner(s): Kerns, Kevin P
• Application Number:
  US13/694,457
• Publication Number:
  US 20130160963A1
• Time in Patent Office: 799 Days
• Field of Search: 164/69.1, 164/76.1, 164/113
• US Class Current: 164/113
• CPC Class Codes: B22D 17/00 Pressure die casting or injection die casting, i.e. casting in which the metal is forced into a mould under high pressure
• CPC Class Codes: B22D 17/20 Accessories: Details
• CPC Class Codes: B22D 21/007 with low melting point, e.g. Al 659 degrees C, Mg 650 degrees C
• CPC Class Codes: B22D 25/00 Special casting characterised by the nature of the product B22D15/02, B22D17/16, B22D19/00 take precedence; casting stereotype plates B41D3/00
• CPC Class Codes: C22C 21/00 Alloys based on aluminium
• CPC Class Codes: C25D 11/022 Anodisation on selected surface areas
• CPC Class Codes: C25D 11/04 of aluminium or alloys based thereon
• CPC Class Codes: C25D 11/16 Pretreatment , e.g. desmutting
• CPC Class Codes: C25D 11/18 After-treatment, e.g. pore-sealing
• CPC Class Codes: C25D 5/02 Electroplating of selected surface areas
• CPC Class Codes: C25D 9/06 by anodic processes
• CPC Class Codes: Y10T 428/12736 Al-base component
• CPC Class Codes: Y10T 428/26 Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension

Abstract

Decorative shape cast products and methods, systems, compositions and apparatus for producing the same are described. In one embodiment, the decorative shape cast products are produced from an Al—Ni or Al—Ni—Mn alloy, with a tailored microstructure to facilitate production of anodized decorative shape cast product having the appropriate finish and mechanical properties.

Claims

1. A method comprising:

(a) selecting a product application for a shape cast aluminum alloy product;

(b) selecting a finishing style for the shape cast aluminum alloy product;

wherein the finishing style includes a visually apparent defect free surface;

(c) selecting, based on at least one of steps (a) and (b);

(i) a predetermined microstructure of the shape cast aluminum alloy product;

wherein the predetermined microstructure comprises a layered microstructure, wherein the layered microstructure comprises an outer layer having alpha aluminum phase and eutectic microstructure; and

(ii) an alloy for use in producing the shape cast aluminum alloy product, wherein the alloy is one of;

(A) an Al—

Ni casting alloy comprising from about 0.5 wt. % to about 8.0 wt. % Ni; and

(B) an Al—

Ni—

Mn casting alloy comprising from about 0.5 wt. % to about 8.0 wt. % Ni and from about 0.5 wt. % to about 3.5 wt. % Mn;

(d) producing the shape cast aluminum alloy product in response to the selection step (c), wherein the producing comprises;

(i) die casting the shape cast aluminum alloy product from either the Al—

Ni or the Al—

Ni—

Mn alloy;

wherein the shape cast aluminum alloy product realizes the layered microstructure, wherein the outer layer has a thickness of not greater than about 400 microns;

(ii) removing at least a portion of the outer layer from the shape cast aluminum alloy product; and

(iii) anodizing the shape cast aluminum alloy product, wherein the anodizing comprises forming a uniform oxide layer from a portion of the shape cast aluminum alloy product;

wherein after the anodizing step (iii), the shape cast aluminum alloy product realizes both (A) a CIELAB L-value of at least about 55 and (B) an ISO brightness of at least about 20.

2. The method of claim 1, wherein after the anodizing step (iii), the shape cast aluminum alloy product realizes a Delta-E of not greater than about 5.0.

3. The method of claim 1, wherein the selecting step (c) comprises selecting a hypereutectic alloy composition.

4. The method of claim 3, wherein the alloy is the Al—

Ni—

Mn alloy.

5. The method of claim 3, wherein the uniform oxide layer is associated with an intended viewing surface of the product, wherein the method comprises:

applying a colorant to at least a portion of the uniform oxide layer, wherein after the applying step, the intended viewing surface of the shape east aluminum alloy product has a Delta-E of not greater than about 5.0 due to, at least in part, the uniformity of the oxide layer, and wherein the intended viewing surface is substantially free of visually apparent surface defects.

6. A method comprising:

(a) selecting a product application for a shape cast aluminum alloy product;

(b) selecting a finishing style for the shape cast aluminum alloy product;

wherein the finishing style is a marbled surface;

(c) selecting, based on at least one of steps (a) and (b);

(i) a predetermined microstructure of the shape cast aluminum alloy product;

wherein the predetermined microstructure comprises a layered microstructure, wherein the layered microstructure comprises an outer layer having a fairly regular distribution of alpha aluminum phase and eutectic microstructure; and

(ii) an alloy for use in producing the shape cast aluminum alloy product, wherein the alloy is one of;

(A) an Al—

Ni casting alloy comprising from about 0.5 wt. % to about 8.0 wt. % Ni; and

(B) an Al—

Ni—

Mn casting alloy comprising from about 0.5 wt, % to about 8.0 wt. % Ni and from about 0.5 wt. % to about 3.5 wt. % Mn; and

(d) producing the shape cast aluminum alloy product in response to the selection step (c), wherein the producing comprises;

(i) die casting the shape cast aluminum alloy product having the layered microstructure from either the Al—

Ni or the Al—

Ni—

Mn alloy;

(ii) anodizing the shape cast aluminum alloy product, wherein the anodizing comprises forming a uniform oxide layer from a portion of the shape cast aluminum alloy product; and

(iii) applying a colorant to the uniform oxide layer, wherein, after the applying step, the shape cast aluminum alloy product realizes a marbled intended viewing surface due, at least in part, to the alpha aluminum phase and eutectic microstructure;

wherein after the anodizing step (ii), the shape cast aluminum alloy product realizes both (A) a CIELAB L-value of at least about 55 and (B) an ISO brightness of at least about 20.

7. The method of claim 6, wherein the selecting step (c) comprises selecting a hypoeutectic alloy composition.

8. The method of claim 7, wherein the alloy is the Al—

Ni—

Mn alloy.