Noble metal fine particle supported catalyst and method for producing the catalyst, and purifying catalyst

• US 8,951,931 B2
• Filed: 02/28/2011
• Issued: 02/10/2015
• Est. Priority Date: 03/02/2010
• Status: Expired due to Fees

• Current Assignee: Nippon Sheet Glass Company Limited
• Original Assignee: Nippon Sheet Glass Company Limited
• Inventors: Ogawa, Ryohei, Miyashita, Kiyoshi
• Primary Examiner(s): Hailey, Patricia L
• Application Number:
  US13/581,866
• Publication Number:
  US 20120329643A1
• Time in Patent Office: 1,443 Days
• Field of Search: 502/182, 502/185, 502/240, 502/242, 502/261, 502/304, 502/327, 502/332, 502/350, 423/213.5, 423/239.1
• US Class Current: 502/182
• CPC Class Codes: B01D 2253/304 Linear dimensions, e.g. particle shape, diameter
• CPC Class Codes: B01D 2255/1021 Platinum
• CPC Class Codes: B01D 2255/1023 Palladium
• CPC Class Codes: B01D 2255/1026 Ruthenium
• CPC Class Codes: B01D 2255/106 Gold
• CPC Class Codes: B01D 53/944 Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts three-way-catalysts [TWC] B01D53/9445
• CPC Class Codes: B01J 21/06 Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
• CPC Class Codes: B01J 21/063 Titanium; Oxides or hydroxides thereof
• CPC Class Codes: B01J 23/40 of the platinum group metals
• CPC Class Codes: B01J 35/23 in a colloidal state
• CPC Class Codes: B01J 35/56 Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
• CPC Class Codes: B01J 37/038 to form slurries or suspensions, e.g. a washcoat
• CPC Class Codes: C02F 1/725 by catalytic oxidation
• CPC Class Codes: H01M 4/8605 Porous electrodes
• CPC Class Codes: H01M 4/8814 Temporary supports, e.g. decal
• CPC Class Codes: H01M 4/8828 Coating with slurry or ink
• CPC Class Codes: H01M 4/8842 Coating using a catalyst salt precursor in solution followed by evaporation and reduction of the precursor
• CPC Class Codes: H01M 4/92 Metals of platinum group H01M4/94 , H01M4/9058 take precedence
• CPC Class Codes: H01M 4/925 supported on carriers, e.g. powder carriers
• CPC Class Codes: H01M 4/926 on carbon or graphite
• CPC Class Codes: Y02E 60/50 : Fuel cells

Abstract

The noble metal fine particle supported catalyst of the present invention includes a substrate, and a porous membrane formed on the substrate. The porous membrane contains support particles, noble metal fine particles, and an inorganic binder. In the porous membrane, the noble metal fine particles are supported on surfaces of the support particles, and the support particles form secondary particles each having a porous structure. The porous membrane is formed by binding, with the inorganic binder, the secondary particles formed of the support particles so that a gap is present at least partly between the secondary particles adjacent to each other.

Claims

1. A noble metal fine particle supported catalyst comprising a substrate;

and a porous membrane formed on the substrate,

wherein the porous membrane comprises support particles, noble metal fine particles, and an inorganic binder,

in the porous membrane, the noble metal fine particles are supported on surfaces of the support particles, and a plurality of the support particles on which the noble metal fine particles are supported form a secondary particle having a porous structure, and

the porous membrane is formed by binding, with the inorganic binder, a plurality of the secondary particles formed of the support particles on which the noble metal fine particles are supported so that a gap is present at least partly between the secondary particles adjacent to each other.

2. The noble metal fine particle supported catalyst according to claim 1, wherein the noble metal fine particles each are composed of at least one material selected from the group consisting of Pt, Pd, Au, Ru, and Rh, and have a particle diameter from 1 nm to 20 nm.

3. The noble metal fine particle supported catalyst according to claim 1, wherein the noble metal fine particles each have a particle diameter from 1 nm to 5.5 nm.

4. The noble metal fine particle supported catalyst according to claim 1, wherein the noble metal fine particles each comprise Pt and have a particle diameter from 1 nm to 5.5 nm.

5. The noble metal fine particle supported catalyst according to claim 1, wherein the noble metal fine particles each comprise Pd and have a particle diameter from 5 nm to 15 nm.

6. The noble metal fine particle supported catalyst according to claim 1, wherein the support particles each comprise at least one material selected from the group consisting of titanium oxide, aluminum oxide, cerium oxide, zirconium oxide, silica, and carbon, and the support particles have an average particle diameter from 10 nm to 100 nm.

7. The noble metal fine particle supported catalyst according to claim 1, wherein the inorganic binder comprises at least one metal oxide selected from the group consisting of aluminum oxide, titanium oxide, cerium oxide, zirconium oxide, and silica.

8. The noble metal fine particle supported catalyst according to claim 1, wherein a weight of the inorganic binder in the porous membrane is 70% or less relative to a weight of the support particles in the porous membrane.

9. The noble metal fine particle supported catalyst according to claim 1, wherein a weight of the inorganic binder in the porous membrane is from 15% to 50% relative to a weight of the support particles in the porous membrane.

10. The noble metal fine particle supported catalyst according to claim 1, wherein the porous membrane has a thickness from 0.1 μ

m to 10 μ

m.

11. The noble metal fine particle supported catalyst according to claim 1, wherein the porous membrane has a thickness from 0.5 μ

m to 5 μ

m.

12. A purifying catalyst for purifying exhaust gas or wastewater, comprising the noble metal fine particle supported catalyst according to claim 1.

13. The noble metal fine particle supported catalyst according to claim 1,

wherein the secondary particle is an aggregate of the plurality of the support particles on which the noble metal fine particles are supported, and

the secondary particle has fine pores each formed of a gap between the support particles forming the aggregate.

14. A method for producing a noble metal fine particle supported catalyst, comprising steps of:

bringing a dispersion of noble metal fine particles into contact with support particles having an average particle diameter from 10 nm to 100 nm so that the noble metal fine particles are supported on the support particles;

mixing the support particles on which the noble metal fine particles are supported with a solvent so as to form a mixture, and stirring the resultant mixture so as to produce a dispersion of the support particles so that a plurality of the support particles on which the noble metal fine particles are supported form a secondary particle having an average particle diameter from 10 nm to 1000 nm;

producing a coating liquid by mixing the dispersion of the support particles with a metal oxide forming sol that forms an inorganic binder;

applying the coating liquid to a substrate; and

drying and heat-treating the substrate on which the coating liquid is applied,

wherein a porous membrane comprises the noble metal fine particle;

the support particles; and

the inorganic binder,

the porous membrane is formed on the substrate by binding, with the inorganic binder, the secondary particles that are formed of the support particles on which the noble metal fine particles are supported and are adjacent to each other, and binding the support particles to the substrate with the inorganic binder, so that a gap is present at least partly between the secondary particles adjacent to each other.

15. The method for producing a noble metal fine particle supported catalyst according to claim 14, wherein the dispersion of the support particles is mixed with the metal oxide forming sol so that a weight of the inorganic binder formed of the metal oxide forming sol is 70% or less relative to a weight of the support particles.

16. The method for producing a noble metal fine particle supported catalyst according to claim 14, wherein the dispersion of the support particles is mixed with the metal oxide forming sol so that a weight of the inorganic binder formed of the metal oxide forming sol is from 15% to 50% relative to a weight of the support particles.

17. The method for producing a noble metal fine particle supported catalyst according to claim 14, wherein the dispersion of the support particles is subjected to with at least one treatment selected from the group consisting of a crushing treatment and/or a dispersing treatment, at a time after the support particles on which the noble metal fine particles are supported are mixed with the solvent and the resultant mixture is stirred and before the dispersion of the support particles is mixed with the metal oxide forming sol.

18. The method for producing a noble metal fine particle supported catalyst according to claim 14, wherein the dispersion of the support particles is treated with a crushing treatment, at a time after the support particles on which the noble metal fine particles are supported are mixed with the solvent and the resultant mixture is stirred and before the dispersion of the support particles is mixed with the metal oxide forming sol.

19. The method for producing a noble metal fine particle supported catalyst according to claim 14,

wherein the secondary particle is an aggregate of the plurality of the support particles on which the noble metal fine particles are supported, and

the secondary particle has fine pores each formed of a gap between the support particles forming the aggregate.