Catalyst compositions and process for oxychlorination

• US 8,956,993 B2
• Filed: 08/10/2009
• Issued: 02/17/2015
• Est. Priority Date: 11/14/2005
• Status: Active Grant

• Current Assignee: OXY Vinyls LP (Occidental Petroleum Corporation)
• Original Assignee: OXY Vinyls LP (Occidental Petroleum Corporation)
• Inventors: Kramer, Keith S., Cowfer, Joseph A.
• Primary Examiner(s): Olsen, Kaj K
• Assistant Examiner(s): DARJI, PRITESH D
• Application Number:
  US12/538,163
• Publication Number:
  US 20090298682A1
• Time in Patent Office: 2,017 Days
• Field of Search: 502/240, 502/243, 502/244, 502/300, 502/60, 502/73, 502/263, 502 77- 80, 502/87, 502/355, 501/6
• US Class Current: 502/244
• CPC Class Codes: B01J 21/12 Silica and alumina
• CPC Class Codes: B01J 23/83 with rare earths or actinides
• CPC Class Codes: B01J 27/122 of copper
• CPC Class Codes: B01J 27/138 with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
• CPC Class Codes: B01J 35/19 Catalysts containing parts with different compositions
• CPC Class Codes: B01J 35/30 characterised by their physical properties
• CPC Class Codes: B01J 35/31 Density
• CPC Class Codes: B01J 35/40 characterised by dimensions, e.g. grain size in a colloidal state B01J35/23; crystallite size B01J35/77
• CPC Class Codes: B01J 35/60 characterised by their surface properties or porosity
• CPC Class Codes: B01J 35/613 10-100 m2/g
• CPC Class Codes: B01J 35/615 100-500 m2/g
• CPC Class Codes: C07C 17/152 of hydrocarbons
• CPC Class Codes: C07C 17/154 of saturated hydrocarbons
• CPC Class Codes: C07C 17/156 of unsaturated hydrocarbons
• CPC Class Codes: C07C 19/045 Dichloroethanes

Abstract

Oxychlorination catalyst compositions which include a catalytically effective amount of an oxychlorination catalyst and a diluent having certain chemical composition and/or physical properties are disclosed. Processes using such oxychlorination catalyst compositions are also described. Some oxychlorination catalyst compositions and processes disclosed herein can increase the optimal operating temperature, and thereby increase the production capacity of an existing reactor, such as a fluid-bed reactor, compared to other oxychlorination catalyst compositions.

Claims

1. An oxychlorination catalyst composition comprising:

(i) a catalytically effective amount of an oxychlorination catalyst comprising an active salt composition distributed on a support material; and

(ii) a diluent comprising particles of a dehydroxylated, dehydrated or calcined alumina silicate having a surface area between about 1 m²/g and about 25 m²/g,

wherein the support material and the diluent are different chemically, wherein the support material is selected from the group consisting of alumina, silica, magnesia, kieselguhr, fuller'"'"'s earth, clays, porous rare earth halides and oxyhalides, and combinations thereof, wherein the surface area of the support material is between about 5 m²/g and about 450 m²/g, and wherein the diluent is catalytically and chemically inert.

2. The oxychlorination catalyst composition of claim 1, wherein the alumina silicate comprises meta-kaolin, kaolin calcined through its characteristic exotherm, or a combination thereof.

3. The oxychlorination catalyst composition of claim 1, wherein the oxychlorination catalyst has a surface area between about 50 m²/g and about 250 m²/g.

4. The oxychlorination catalyst composition of claim 1, wherein the average particle size of the diluent is between about 50% and about 150% of the average particle size of the oxychlorination catalyst.

5. The oxychlorination catalyst composition of claim 1, wherein the % attrition of the diluent is between about 50% and about 150% of the % attrition of the oxychlorination catalyst.

6. The oxychlorination catalyst composition of claim 1, wherein the active salt composition comprises a copper salt.

7. The oxychlorination catalyst composition of claim 1, wherein the active salt composition comprises from about 2% to about 12% by weight of copper, from about 0.2% to about 3% by weight of an alkali metal, from about 0.1% to about 14% by weight of a rare earth metal, and from about 0.05% by weight to about 6% by weight of an alkaline metal, all weight percents based upon the total weight of the oxychlorination catalyst.

12. The oxychlorination catalyst composition of claim 1, wherein the diluent is intimately mixed with the oxychlorination catalyst.

14. The oxychlorination catalyst composition of claim 1, wherein the support material is selected from the group consisting of alumina, silica, magnesia, kieselguhr, fuller'"'"'s earth, and porous rare earth halides and oxyhalides.

8. An oxychlorination catalyst composition comprising:

(a) a catalytically effective amount of an oxychlorination catalyst comprising an active salt composition distributed on a support material, wherein the oxychlorination catalyst has a surface area between about 50 m²/g and about 250 m²/g; and

(b) a diluent having a surface area between about 1 m²/g and about 25 m²/g, wherein the support material and the diluent are different chemically, wherein the average particle size of the oxychlorination catalyst is from about 5 microns to about 300 microns and the average particle size of the diluent is from about 5 microns to about 300 microns, and wherein the diluent is catalytically and chemically inert.

9. The oxychlorination catalyst composition of claim 8, wherein the average particle size of the diluent is between from about 50% to about 150% of the average particle size of the oxychlorination catalyst.

10. The oxychlorination catalyst composition of claim 8, wherein the alumina silicate is dehydroxylated, dehydrated or calcined alumina silicate.

11. The oxychlorination catalyst composition of claim 8, wherein the active salt composition comprises from about 2% to about 12% by weight of copper, from about 0.2% to about 3% by weight of an alkali metal, from about 0.1% to about 14% by weight of a rare earth metal, and from about 0.05% by weight to about 6% by weight of an alkaline metal, all weight percents based upon the total weight of the oxychlorination catalyst.

13. The oxychlorination catalyst composition of claim 8, wherein the diluent is intimately mixed with the oxychlorination catalyst.

15. The oxychlorination catalyst composition of claim 8, wherein the support material is selected from the group consisting of alumina, silica, magnesia, kieselguhr, fuller'"'"'s earth, and porous rare earth halides and oxyhalides.