Light emitting device having strontium oxyorthosilicate type phosphors

• US 8,963,173 B2
• Filed: 12/20/2010
• Issued: 02/24/2015
• Est. Priority Date: 12/21/2009
• Status: Active Grant

• Current Assignee: Litec-LP GmbH, Seoul Semiconductor Co., Ltd.
• Original Assignee: Litec-LP GmbH, Seoul Semiconductor Co., Ltd.
• Inventors: Lee, Chung Hoon, Tews, Walter, Roth, Gundula, Starick, Detlef
• Primary Examiner(s): Vu, David
• Assistant Examiner(s): FOX, BRANDON C
• Application Number:
  US12/972,996
• Publication Number:
  US 20120001205A1
• Time in Patent Office: 1,527 Days
• Field of Search: 257/89
• US Class Current: 257/89
• CPC Class Codes: C09K 11/77342 Silicates
• CPC Class Codes: H01L 2224/32257 the layer connector connecting to a bonding area disposed in a recess of the surface of the item
• CPC Class Codes: H01L 2224/48091 Arched
• CPC Class Codes: H01L 2224/48247 connecting the wire to a bond pad of the item
• CPC Class Codes: H01L 2224/73265 Layer and wire connectors
• CPC Class Codes: H01L 2924/00012 Relevant to the scope of the group, the symbol of which is combined with the symbol of this group
• CPC Class Codes: H01L 2924/00014 the subject-matter covered by the group, the symbol of which is combined with the symbol of this group, being disclosed without further technical details
• CPC Class Codes: H01L 2924/181 Encapsulation
• CPC Class Codes: H01L 33/50 Wavelength conversion elements
• CPC Class Codes: H01L 33/647 the elements conducting electric current to or from the semiconductor body

Abstract

Exemplary embodiments of the present invention relate to light emitting devices including strontium oxyorthosilicate-type phosphors. The light emitting device includes a light emitting diode, which emits light in the UV or visible range, and phosphors disposed around the light emitting diode to absorb light emitted from the light emitting diode and emit light having a different wavelength from the absorbed light. The phosphors include an oxyorthosilicate phosphor having a general formula of Sr_3-x-y-zCa_xM^II_ySiO₅: Eu_z with a calcium molar fraction in the range of 0<x≦0.05.

Claims

1. A light emitting device, comprising:

a light emitting diode; and

phosphors to absorb light emitted from the light emitting diode and emit light having a different wavelength from the absorbed light, the phosphors having the general formula M^I_3-x-y-zCa_xM^II_ySiO₅;

Eu_z, wherein,

M^I is at least one element selected from Sr and Ba;

M^II is at least one element selected from Mg, Ba, Cu, Zn, and Mn;

0<

x≦

0.05;

0≦

y≦

0.5; and

0<

z≦

0.25,

wherein y does not equal x, and

wherein the light emitted from the light emitting diode is mixed with the light emitted from the phosphors, to output a desired color of light.

2. The light emitting device of claim 1, wherein M^I is Ba.

3. The light emitting device of claim 2, wherein M^II is a divalent metal ion and comprises at least two of the divalent metal ions.

4. The light emitting device of claim 1, wherein the phosphors further comprise divalent rare earth metal ions or trivalent rare earth metal ions as an activator.

5. The light emitting device of claim 4, wherein the divalent rare earth metal ions comprise Sm ions or Yb ions.

6. The light emitting device of claim 4, wherein the trivalent rare earth metal ions comprise Ce³⁺.

7. The light emitting device of claim 1, wherein the phosphors emit light having an emission peak wavelength in the range of 560˜

620 nm.

8. The light emitting device of claim 1, wherein the light emitting diode and the phosphors are combined in a single package.

9. The light emitting device of claim 8, further comprising:

another light emitting diode in the package, wherein the other light emitting diode emits light having a longer emission peak wavelength than that of the phosphors.

10. The light emitting device of claim 9, further comprising a plurality of heat sinks, wherein each light emitting diode is respectively disposed on a heat sink of the plurality of heat sinks.

11. The light emitting device of claim 8, wherein the package further comprises a substrate, on which the light emitting diode is mounted.

12. The light emitting device of claim 11, wherein the substrate comprises a printed circuit board or a lead frame.

13. The light emitting device of claim 12, further comprising a molding member encapsulating the light emitting diode,

wherein the phosphors are distributed within the molding member.

14. The light emitting device of claim 8, wherein the package comprises a heat sink on which the light emitting diode is mounted.

15. The light emitting device of claim 1, wherein the light emitting diode comprises a plurality of light emitting cells.

16. The light emitting device of claim 1, wherein M^II comprises Cu.

17. The light emitting device of claim 1, wherein M^II comprises Zn.

18. The light emitting device of claim 1, wherein M^II comprises Mn.

19. A light emitting device, comprising:

a light emitting diode; and

phosphors to absorb light emitted from the light emitting diode and emit light having a different wavelength from the absorbed light, the phosphors having the general formula M^I_3-x-y-zCa_xM^II_ySiO₅;

Eu_z, wherein,

M^I is at least one element selected from Sr and Ba;

M^II is at least one element selected from Mg, Ba, Cu, Zn, and Mn;

0<

x≦

0.05;

0≦

y≦

0.5; and

0<

z≦

0.25,

wherein y does not equal x, and

wherein the light emitting diode and the phosphors are combined in a single package.

20. A light emitting device, comprising:

a light emitting diode; and

phosphors to absorb light emitted from the light emitting diode and emit light having a different wavelength from the absorbed light, the phosphors having the general formula M^I_3-x-y-zCa_xM^II_ySiO₅;

Eu_z, wherein,

M^I is at least one element selected from Sr and Ba;

M^II is at least one element selected from Mg, Ba, Cu, Zn, and Mn;

0<

x≦

0.05;

0≦

y≦

0.5; and

0<

z≦

0.25,

wherein y does not equal x, and

wherein the light emitting diode comprises a plurality of light emitting cells.