Two stage cathodic protection system using impressed current and galvanic action

• US 8,968,549 B2
• Filed: 07/19/2012
• Issued: 03/03/2015
• Est. Priority Date: 07/19/2012
• Status: Active Grant

• Current Assignee: Vector Corrosion Technologies Incorporated (Vector Corrosion Technologies)
• Original Assignee: Vector Corrosion Technologies Incorporated (Vector Corrosion Technologies)
• Inventors: Sergi, George, Seneviratne, Attanayake Mudiyanselage Gamini, Whitmore, David
• Primary Examiner(s): Van, Luan
• Assistant Examiner(s): Keeling, Alexander W
• Application Number:
  US13/553,514
• Publication Number:
  US 20140021063A1
• Time in Patent Office: 957 Days
• Field of Search: 205/724, 205/734, 205/735, 204/196.01, 204/196.02, 204/196.04
• US Class Current: 205/734
• CPC Class Codes: C23F 13/04 Controlling or regulating desired parameters
• CPC Class Codes: C23F 13/06 Constructional parts, or assemblies of cathodic-protection apparatus
• CPC Class Codes: C23F 13/10 Electrodes characterised by the structure C23F13/16 takes precedence
• CPC Class Codes: C23F 13/20 Conducting electric current to electrodes
• CPC Class Codes: C23F 2201/02 Concrete, e.g. reinforced
• CPC Class Codes: C23F 2213/21 combining at least two types of anodic or cathodic protection
• CPC Class Codes: C23F 2213/22 characterized by the ionic conductor, e.g. humectant, hydratant or backfill
• CPC Class Codes: E04C 5/015 Anti-corrosion coatings or treating compositions, e.g. containing waterglass or based on another metal coating of discrete reinforcing elements C04B20/10

Abstract

Cathodic protection of steel in concrete is provided by locating an anode assembly including both a sacrificial anode and an impressed current anode in contact with the concrete and providing an impressed current from a power supply to the anode. The impressed current anode forms a perforated sleeve surrounding a rod of the sacrificial anode material with an activated ionically-conductive filler material between. The system can be used without the power supply in sacrificial mode or when the power supply is connected, the impressed current anode can be powered to provide an impressed current system and/or to recharge the sacrificial anode from sacrificial anode corrosion products.

Claims

1. A method for corrosion protection of a metal section in an ionically conductive material comprising:

locating a sacrificial anode of a material which is less noble than the metal section in contact with the ionically conductive material;

temporarily placing an impressed current anode in ionic connection with a surface of the ionically conductive material;

providing a DC power supply;

providing a connection of the DC power supply across the impressed current anode and the metal section so as to create a current between the metal section and the impressed current anode to provide cathodic protection of the metal section by communication of ions between the impressed current anode and the metal section through the ionically conductive material;

and providing an electrically conductive connection between the sacrificial anode and the metal section to form a circuit with communication of ions between the sacrificial anode and the metal section through the ionically conductive material so that the sacrificial anode acts to provide cathodic protection of the metal section.

2. The method according to claim 1 wherein the metal section is steel and the ionically conductive material is a concrete or mortar material, the method further comprising:

absorbing corrosion products from the sacrificial anode into a porous or deformable material at the sacrificial anode within the ionically conductive concrete or mortar material;

and ensuring continued corrosion of the sacrificial anode by providing at least one activator at the sacrificial anode.

3. The method according to claim 1 wherein the application of the DC power supply between the impressed current anode and the metal section provides an initial impressed current and, when the initial impressed current is terminated, the connection of the sacrificial anode and the metal section continues to provide cathodic protection of the metal section.

4. The method according to claim 1 wherein cathodic protection of the metal section is provided by connection of the sacrificial anode and the metal section and, subsequent to a period of cathodic protection provided by the sacrificial anode, the DC power supply is applied between the impressed current anode and the metal section causing the metal section to be further protected.

5. The method according to claim 1 wherein at least once the DC power supply is connected across the impressed current anode and the metal section while the electrically conductive connection provides said connection between the sacrificial anode and the metal section.

6. The method according to claim 1 including passivating the metal section by the impressed current.

7. The method according to claim 1 wherein the current provided by the impressed current anode is applied until a minimum total charge of 20,000 Coulombs per square meter is applied to the metal section.

8. The method according to claim 1 wherein the current provided by the impressed current anode is applied until a minimum total charge of 70,000 Coulombs per square meter is applied to the metal section.

9. The method according to claim 1 including raising the pH of the ionically conductive material in contact with the metal section by the impressed current.

10. The method according to claim 1 wherein the impressed current anode and the sacrificial anode are electrically separated to prevent electrical communication therebetween.

11. The method according to claim 1 wherein there is provided connectors for connection to the positive and negative terminals of the power supply, with a first electrical connector connected to the impressed current anode and with a second electrical connector connected to the sacrificial anode and/or to the metal section.

12. The method according to claim 1 wherein there is provided an ionically conductive filler material different from said ionically conductive material adjacent to the sacrificial anode.

13. The method according to claim 12 wherein the ionically conductive filler material has a pH sufficiently high for corrosion of the sacrificial anode to occur and for passive film formation on the sacrificial anode to be avoided.

14. The method according to claim 1 wherein there is provided a plurality of sacrificial anodes and wherein the impressed current anode is separate from said sacrificial anodes.

15. The method according to claim 1 wherein there is provided a plurality of impressed current anodes and wherein the sacrificial anode is separate from said impressed current anodes.

16. The method according to claim 1 wherein the sacrificial anode is used as a back-up to the impressed current anode when at least one of the DC power supply, the impressed current connections and the impressed current anode is not functional.

17. The method according to claim 1 wherein the DC power supply is intermittent and the sacrificial anode provides galvanic corrosion protection to the metal section when the DC power is not present.

18. The anode apparatus according to claim 1 including a solar cell as the DC power supply.

19. The method according to claim 1 wherein the sacrificial anode and the impressed current anode are in ionically conductive communication with each other.

20. A method for corrosion protection of a metal section in an ionically conductive material comprising:

locating an impressed current anode in contact with the ionically conductive material;

locating a sacrificial anode of a material which is less noble than the metal section in contact with the ionically conductive material;

providing a DC power supply;

providing a first electrically conductive connection of the DC power supply across the impressed current anode and the metal section so as to create a current between the metal section and the impressed current anode to provide cathodic protection of the metal section by communication of ions between the impressed current anode and the metal section through the ionically conductive material;

providing a second electrically conductive connection between the sacrificial anode and the metal section to form a circuit with communication of ions between the sacrificial anode and the metal section through the ionically conductive material;

and at least once connecting said first electrically conductive connection and said second electrically conductive connection simultaneously.

21. The method according to claim 20 including passivating the metal section by the impressed current.

22. The method according to claim 20 wherein the current provided by the impressed current anode is applied until a minimum total charge of 20,000 Coulombs per square meter is applied to the metal section.

23. The method according to claim 20 wherein the current provided by the impressed current anode is applied until a minimum total charge of 70,000 Coulombs per square meter is applied to the metal section.

24. The method according to claim 20 including raising the pH of the ionically conductive material in contact with the metal section by the impressed current.

25. The method according to claim 20 wherein the sacrificial anode and the impressed current anode comprise common components of a common anode assembly.

26. The method according to claim 20 wherein the impressed current anode and the sacrificial anode are electrically separated to prevent electrical communication therebetween.

27. The method according to claim 20 wherein there is provided an ionically conductive filler material different from said ionically conductive material adjacent to the sacrificial anode.

28. The method according to claim 27 wherein the ionically conductive filler material has a pH sufficiently high for corrosion of the sacrificial anode to occur and for passive film formation on the sacrificial anode to be avoided.

29. The method according to claim 20 wherein there is provided a plurality of sacrificial anodes and wherein the impressed current anode is separate from said sacrificial anodes.

30. The method according to claim 20 wherein there is provided a plurality of impressed current anodes and wherein the sacrificial anode is separate from said impressed current anodes.

31. The method according to claim 20 wherein the impressed current anode is placed in ionic connection with a surface of the ionically conductive material temporarily.

32. The method according to claim 20 wherein the impressed current anode is mounted on a surface of the ionically conductive material to provide current through the surface of the ionically conductive material.

33. The method according to claim 20 wherein the impressed current anode is temporarily placed in ionic connection with a surface of the ionically conductive material for re-charging of the sacrificial anode.

34. The method according to claim 20 wherein the sacrificial anode is used as a back-up to the impressed current anode when at least one of the DC power supply, the impressed current connections and the impressed current anode is not functional.

35. The method according to claim 20 wherein the DC power supply is intermittent and the sacrificial anode provides galvanic corrosion protection to the metal section when the DC power is not present.

36. The method according to claim 20 including a solar cell as the DC power supply.

37. The method according to claim 20 wherein the sacrificial anode and the impressed current anode are in ionically conductive communication with each other.