Disposable palladium nanoparticle-modified graphite pencil electrode

• US 8,968,825 B1
• Filed: 08/22/2013
• Issued: 03/03/2015
• Est. Priority Date: 08/22/2013
• Status: Expired due to Fees

• Current Assignee: King Fahd University of Petroleum & Minerals (Government of Saudi Arabia), King Abdul AZIZ City For Science and Technology
• Original Assignee: King Fahd University of Petroleum & Minerals (Government of Saudi Arabia), King Abdul AZIZ City For Science and Technology
• Inventors: Kawde, Abdel-Nasser Metwally Aly, Abdul Aziz, MD
• Primary Examiner(s): Talbot, Brian K
• Application Number:
  US13/973,974
• Publication Number:
  US 20150053554A1
• Time in Patent Office: 558 Days
• Field of Search: 427/113, 427/125, 427/180, 427/383.1
• US Class Current: 427/113
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: G01N 27/30 Electrodes, e.g. test electrodes; Half-cells G01N27/414 takes precedence

Abstract

The disposable palladium nanoparticle-modified graphite pencil electrode (PdNP-GPE) is a graphite pencil electrode having palladium nanoparticles disposed on the surface of the electrode. The electrode is prepared by adding ascorbic acid to an aqueous solution of ammonium tetrachloropalladate(II) [(NH₄)₂PdCl₄] at room temperature to form the palladium nanoparticles (PdNPs), immersing a GPE in the aqueous solution of PdNPs, and heating the solution to about 75° C. to deposit the PdNPs on the GPE. The palladium nanoparticle modified graphite pencil electrode may be used in an electrochemical cell for quantitative analysis of hydrogen peroxide content in an unknown solution.

Claims

1. A method of making a disposable palladium nanoparticle-modified graphite pencil electrode, comprising the steps of:

mixing an aqueous solution of ascorbic acid with an aqueous solution of ammonium tetrachloropalladate (II) to form a solution containing nanoparticles of palladium;

immersing a bare graphite pencil lead in the solution containing nanoparticles of palladium; and

placing a container having the graphite immersed in the solution containing nanoparticles of palladium into a preheated water bath at about 75°

C. to form the disposable palladium nanoparticle-modified graphite pencil electrode.

2. The method of making the disposable palladium nanoparticle-modified graphite pencil electrode according to claim 1, further comprising the steps of washing the palladium nanoparticle-modified graphite electrode in deionized water, and then drying the electrode at 60°

C.

3. The method of making the disposable palladium nanoparticle-modified graphite pencil electrode according to claim 1, wherein the mixing step is performed at room temperature.