Apparatus, systems and methods for reducing foaming downstream of a submerged combustion melter producing molten glass

• US 8,973,405 B2
• Filed: 10/03/2012
• Issued: 03/10/2015
• Est. Priority Date: 06/17/2010
• Status: Active Grant

• Current Assignee: Johns Manville Corporation (Berkshire Hathaway Incorporated)
• Original Assignee: Johns Manville Corporation (Berkshire Hathaway Incorporated)
• Inventors: Charbonneau, Mark William, McHugh, Kevin Patrick
• Primary Examiner(s): HERRING, LISA L
• Application Number:
  US13/633,998
• Publication Number:
  US 20140090419A1
• Time in Patent Office: 888 Days
• Field of Search: 651341-1364, 653/46
• US Class Current: 65/134.5
• CPC Class Codes: C03B 5/193 using gas, e.g. bubblers
• CPC Class Codes: C03B 5/202 Devices for blowing onto the melt surface, e.g. high momentum burners
• CPC Class Codes: C03B 5/225 Refining C03B5/18 takes precedence ; Refining agents C03C1/004
• CPC Class Codes: C03B 5/2356 Submerged heating, e.g. by using heat pipes, hot gas or submerged combustion burners bubblers C03B5/193
• CPC Class Codes: C03B 7/02 Forehearths, i.e. feeder channels

Abstract

Apparatus including a flow channel defined by a floor, roof, and sidewall structure connecting the floor and roof. One or more combustion burners is positioned in either the roof, the sidewall structure, or both, and transfer heat to a molten mass of glass containing bubbles having a bubble atmosphere flowing through the flow channel. The burners contribute to formation of a channel atmosphere above the molten glass. Apparatus includes a device, at least a portion of which is positionable under a level of the molten glass in the flow channel, configured to emit a composition into the molten glass under the level to intimately contact the composition with the molten glass and bubbles therein. The composition diffuses into the bubbles to form modified atmosphere bubbles sufficiently different from the channel atmosphere to increase diffusion of a species in the channel atmosphere into the modified atmosphere bubbles.

Claims

1. An apparatus comprising:

a flow channel defined by a floor, a roof, and a sidewall structure connecting the floor and roof;

one or more combustion burners positioned in either the roof, the sidewall structure, or both, and positioned to transfer heat to a molten mass of glass containing bubbles having a bubble atmosphere flowing through the flow channel, the burners contributing to formation of a channel atmosphere above the molten glass; and

a device, at least a portion of which is positionable sufficiently under a level of the molten glass in the flow channel and configured to emit a composition into the molten glass under the level so as to intimately contact the composition with the molten glass and at least some of the bubbles therein, at least some of the composition diffusing into the intimately contacted bubbles to form modified atmosphere bubbles sufficiently different from the channel atmosphere to increase diffusion of a species in the channel atmosphere into the modified atmosphere bubbles, the device comprising a substantially horizontal retractable extension conduit having at least one aperture for emitting the composition,

wherein when at least some of the modified atmosphere bubbles are subsequently exposed to the channel atmosphere, a portion of the channel atmosphere diffuses into the modified atmosphere bubbles;

wherein the roof, floor, and sidewall structure defining the flow channel define a substantially linear structure having a length, a width, a proximal end, a distal end, and a longitudinal axis, wherein the length is more than five times the width, wherein the roof comprises a molten glass inlet port near the proximal end and a vent port near the distal end, and wherein the sidewall structure comprises a third port for inserting and removing the device; and

wherein the third port is positioned in the sidewall near the molten glass inlet port, and the flow channel comprises a primary flow dam positionable to block and unblock flow through the flow channel, the apparatus further comprising a distribution channel fluidly connecting a submerged combustion melter with the flow channel, the distribution channel comprising a first flow channel and a first retractable dam positionable to block and unblock the first flow channel, and a second flow channel having a second retractable dam positionable to block and unblock the second flow channel.

2. The apparatus of claim 1 wherein one or more of the burners are high momentum burners.

3. The apparatus of claim 2 wherein one or more of the high momentum combustion burners are positioned along a centerline of the flow channel in the roof, wherein the high momentum burners have a fuel velocity ranging from about 150 ft./second to about 1000 ft./second (about 46 meters/second to about 305 meters/second) and an oxidant velocity ranging from about 150 ft./second to about 1000 ft./second (about 46 meters/second to about 305 meters/second).

4. The apparatus of claim 1 wherein the flow channel comprises first and second sections arranged in series, each section having a flow channel width W, wherein W1>

W2, wherein W1 is the width of the first section, and the first section includes the molten glass inlet port near the proximal end, and wherein W2 is the width of the second section, and second section includes the vent port near the distal end.

5. A system comprising:

a submerged combustion melter comprising a floor, a roof, a wall structure connecting the floor and roof, a melting zone being defined by the floor, roof and wall structure, and one or more a burners, at least some of which are positioned to direct combustion products into the melting zone under a level of molten glass in the melting zone and form a turbulent molten glass, the melter comprising a batch feeder attached to the wall or roof above the level, and an exit end comprising a melter exit structure for discharging the molten glass, the melter exit structure fluidly and mechanically connecting the melter to a flow channel downstream of the melter, the melter configured to produce an initial foamy molten glass comprising bubbles having a bubble atmosphere, at least some of the bubbles forming a bubble layer on top of the foamy molten glass;

the flow channel defined by a flow channel floor, a flow channel roof, and a flow channel sidewall structure connecting the flow channel floor and flow channel roof;

one or more flow channel combustion burners positioned in either the flow channel roof, the flow channel sidewall structure, or both, and positioned to transfer heat to the foamy molten glass containing bubbles flowing through the flow channel, the flow channel burners contributing to formation of a channel atmosphere above the molten glass; and

a device, at least a portion of which is positionable sufficiently under a level of the molten glass in the flow channel and configured to emit a composition into the foamy molten glass under the level so as to intimately contact the composition with the foamy molten glass and at least some of the bubbles therein, at least some of the composition diffusing into the intimately contacted bubbles to form modified atmosphere bubbles, wherein when at least some of the modified atmosphere bubbles are subsequently exposed to the channel atmosphere, a portion of the channel atmosphere diffuses into the modified atmosphere bubbles, the device comprising a substantially horizontal retractable extension conduit having at least one aperture for emitting the composition;

wherein the roof, floor, and sidewall structure defining the flow channel define a substantially linear structure having a length, a width, a proximal end, a distal end, and a longitudinal axis, wherein the length is more than five times the width, wherein the flow channel roof comprises a molten glass inlet port near the proximal end and a vent port near the distal end, and wherein the flow channel sidewall structure comprises a third port for inserting and removing the device; and

wherein the third port is positioned in the flow channel sidewall near the molten glass inlet port, and the flow channel comprises a primary flow dam positionable to block and unblock flow through the flow channel, the apparatus further comprising a distribution channel fluidly connecting the submerged combustion melter with the flow channel, the distribution channel comprising a first flow channel and a first retractable dam positionable to block and unblock the first flow channel, and a second flow channel having a second retractable dam positionable to block and unblock the second flow channel.

6. The system of claim 5 wherein the device comprises materials substantially inert to molten glass compositions and to gases selected from the group consisting of hydrogen, helium, steam, nitrogen, oxides of nitrogen, oxides of carbon, oxides of sulfur, argon, xenon, krypton, and mixtures and combinations thereof.

7. The system of claim 5 wherein at least a portion of the substantially horizontal retractable extension conduit is substantially parallel to a longitudinal axis of the channel.

8. The system of claim 5 wherein at least a portion of the substantially horizontal retractable extension conduit is adjacent the flow channel floor.

9. A process comprising:

a) routing an initial foamy molten glass into a flow channel downstream of a submerged combustion melter, the initial foamy molten glass comprising bubbles having a bubble atmosphere, at least some of the bubbles forming a bubble layer on top of the initial foamy molten glass, the flow channel defined by a floor, a roof, and a sidewall structure connecting the floor and roof, wherein the roof, floor, and sidewall structure defining the flow channel define a substantially linear structure having a length, a width, a proximal end, a distal end, and a longitudinal axis, wherein the length is more than five times the width, wherein the roof comprises a molten glass inlet port near the proximal end and a vent port near the distal end, and wherein the sidewall structure comprises a third port for inserting and removing a device, the device comprising a substantially horizontal retractable extension conduit having at least one aperture for emitting a composition, and wherein the third port is positioned in the sidewall near the molten glass inlet port, and the flow channel comprises a primary flow dam positionable to block and unblock flow through the flow channel, the apparatus further comprising a distribution channel fluidly connecting the submerged combustion melter with the flow channel, the distribution channel comprising a first flow channel and a first retractable dam positionable to block and unblock the first flow channel, and a second flow channel having a second retractable dam positionable to block and unblock the second flow channel;

b) heating the initial foamy molten glass using one or more combustion burners positioned in either the roof, the sidewall structure, or both, and positioned to transfer heat to the molten mass of glass containing bubbles flowing through the flow channel, the burners contributing to formation of a channel atmosphere above the foamy molten glass;

c) intimately contacting the initial foamy molten glass and at least some of the bubbles therein with the composition discharged from the device, at least a portion of which is positionable sufficiently under a level of the molten glass in the flow channel and configured to emit the composition so that at least some of the composition diffuses into the contacted bubbles to form modified atmosphere bubbles, wherein the intimately contacting the initial molten glass and at least some of the bubbles therein with the composition discharged from the device comprises discharging the composition through the substantially horizontal retractable extension conduit inserted through the sidewall structure,

d) contacting at least some of the modified atmosphere bubbles with the channel atmosphere, at least a portion of the channel atmosphere diffusing into the modified atmosphere bubbles.

10. The process of claim 9 wherein the intimately contacting the initial molten glass and at least some of the bubbles therein with the composition discharged from the device comprises intimately contacting the molten glass with a gas selected from the group consisting of hydrogen, helium, steam, nitrogen, oxides of nitrogen, oxides of carbon, oxides of sulfur, argon, xenon, krypton, and mixtures and combinations thereof.

11. The process of claim 9 comprising positioning the substantially horizontal retractable extension conduit so that at least a portion of the substantially horizontal retractable extension conduit is substantially parallel to the channel.

12. The process of claim 9 comprising positioning the substantially horizontal retractable extension conduit so that at least a portion of the substantially horizontal retractable extension conduit is adjacent the floor of the channel.

13. The process of claim 9 comprising removing the device upon the device becoming damaged, eroded, or plugged without substantially reducing the routing and heating of the foamy molten glass through the channel.

14. A process comprising:

a) routing an initial foamy molten glass into a flow channel downstream of a submerged combustion melter, the initial foamy molten glass comprising bubbles having a bubble atmosphere, at least some of the bubbles forming a bubble layer on top of the initial foamy molten glass, the flow channel defined by a floor, a roof, and a sidewall structure connecting the floor and roof, wherein the roof, floor, and sidewall structure defining the flow channel define a substantially linear structure having a length, a width, a proximal end, a distal end, and a longitudinal axis, wherein the length is more than five times the width, wherein the roof comprises a molten glass inlet port near the proximal end and a vent port near the distal end, and wherein the sidewall structure comprises a third port for inserting and removing a device, the device comprising a substantially horizontal retractable extension conduit having at least one aperture for emitting a composition, and wherein the third port is positioned in the sidewall near the molten glass inlet port, and the flow channel comprises a primary flow dam positionable to block and unblock flow through the flow channel, the apparatus further comprising a distribution channel fluidly connecting the submerged combustion melter with the flow channel, the distribution channel comprising a first flow channel and a first retractable dam positionable to block and unblock the first flow channel, and a second flow channel having a second retractable dam positionable to block and unblock the second flow channel;

b) heating the initial foamy molten glass using one or more combustion burners positioned in either the roof, the sidewall structure, or both, and positioned to transfer heat to the molten mass of glass containing bubbles flowing through the flow channel, the burners contributing to formation of a channel atmosphere above the foamy molten glass;

c) intimately contacting the initial foamy molten glass and at least some of the bubbles therein with a gas selected from the group consisting of hydrogen, helium, steam, nitrogen, oxides of nitrogen, oxides of carbon, oxides of sulfur, argon, xenon, krypton, and mixtures and combinations thereof discharged from the device positioned sufficiently under a level of the molten glass in the flow channel and configured to emit the composition so that at least some of the composition diffuses into the contacted bubbles to form modified atmosphere bubbles; and

d) contacting at least some of the modified atmosphere bubbles with the channel atmosphere, at least a portion of the channel atmosphere diffusing into the modified atmosphere bubbles.

15. The process of claim 14 comprising adjusting fuel velocity of some of the burners to a value ranging from about 150 ft./second to about 1000 ft./second (about 46 meters/second to about 305 meters/second) and adjusting oxidant velocity to a value ranging from about 150 ft./second to about 1000 ft./second (about 46 meters/second to about 305 meters/second), wherein the fuel and oxidant velocities may be the same or different.

16. The process of claim 14 comprising adjusting fuel velocity of some of the burners to a value ranging from about 6 ft./second to about 40 ft./second (about 2 meters/second to about 12 meters/second) and adjusting oxidant velocity to a value ranging from about 6 ft./second to about 40 ft./second (about 2 meters/second to about 12 meters/second), wherein the fuel and oxidant velocities may be the same or different.