Apparatus and methods for producing charged fluid droplets

• US 8,973,851 B2
• Filed: 06/18/2010
• Issued: 03/10/2015
• Est. Priority Date: 07/01/2009
• Status: Active Grant

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Gartstein, Vladimir, Willey, Alan David, Yates, Claire Rebecca, Horney, James C
• Primary Examiner(s): Ganey, Steven J
• Application Number:
  US12/818,494
• Publication Number:
  US 20110000975A1
• Time in Patent Office: 1,726 Days
• Field of Search: 239/3, 239/145, 239/690, 239/690.1, 239/696, 128/200.14
• US Class Current: 239/690
• CPC Class Codes: A61P 1/02 Stomatological preparations, e.g. drugs for caries, aphtae, periodontitis
• CPC Class Codes: A61P 11/00 Drugs for disorders of the respiratory system
• CPC Class Codes: A61P 27/02 Ophthalmic agents
• CPC Class Codes: B03C 3/16 wet type

Abstract

Disclosed herein is the apparatus that produces very small or nano-sized, charged droplets and the methods for producing such charged fluid droplets. This apparatus avoids the problems known to exist with using spray nozzles having very small orifices to produce such small fluid droplets, those problems including clogging of the nozzles.

Claims

1. An apparatus for production of very small electrically charged fluid droplets comprising:

a. an electrically chargeable fluid;

b. an electrical fluid charger in fluid communication with the chargeable fluid;

c. a fluid emitter in fluid communication with the chargeable fluid comprising a substrate having evenly spaced filaments of approximately equal length affixed thereto; and

d. a counter electrode;

where upon the electrically chargeable fluid reaches an apex of the filament and is electrically charged, the distance between the filament apex and the counter electrode is sufficient to create an electrical field intensity wherein the electrically charged fluid is converted into a stream of very fine and charged fluid droplets moving from the filament'"'"'s apex in the direction of the counter electrode along the electrostatic field'"'"'s force lines formed between the filament'"'"'s apex and the counter electrode, wherein the electrically chargeable fluid has a viscosity of less than 1000 centistokes, and is selected from the group consisting of water-based fluid and oil-based fluids whose selection is based upon the fluid'"'"'s compatibility relative to the material comprising the fluid emitter so to create a fluid flux between the fluid moving from the layer of the substrate and the apex of the filament of a sufficient level to form a sustainable stream of very fine and charged fluid droplets at the filament'"'"'s apex as the fluid is electrically drawn towards the counter electrode.

2. The apparatus of claim 1 wherein the electrically chargeable fluid is oil-based and selected from fluids that are is immiscible in water and do not dissolve in water.

3. The apparatus of claim 2 wherein the electrical fluid charger comprises a high voltage electrode comprising material compatible with the chargeable fluid, selected from the group consisting of metals, carbon, conductive plastics, carbon containing conductive plastics and combinations thereof.

4. The apparatus of claim 2 wherein the electrically chargeable fluid is a non-aqueous composition comprising low basis weight polymer films to provide hair styling adhesive polymers.

5. The apparatus of claim 1 wherein the electrically chargeable fluid is water-based and selected from fluids that are miscible in water and dissolve in water.

6. The apparatus of claim 5 wherein the electrically chargeable fluid is water.

7. The apparatus of claim 6 wherein the electrically chargeable fluid further comprises solutions, dispersions and emulsions of materials selected from the group consisting of salts especially isotonic salt solutions, bioactive materials including antimicrobials, bleaches, catalysts, amine and aldehyde reactive species, perfuming raw materials, formulated perfumes, surfactants, waxes, oils, polymers, bioavailable, over-the-counter and prescriptive, ingredients including antitussives, decongestants, analgesics, vitamins, and other topical medicinal compounds and agents, coloring materials, color cosmetics, keratinous tissue cleansing, sanitizing, exfoliating, conditioning, styling, toning and moisturizing agents and combinations thereof.

8. The apparatus of claim 7 wherein the materials are bioactive materials selected from the group consisting of antimicrobials, bleaches, catalysts, amine and aldehyde reactive species and combinations thereof.

9. The apparatus of claim 8 wherein the bioactive materials are selected from the group consisting of keratinous tissue cleansing, sanitizing, exfoliating, conditioning, styling, toning and moisturizing agents and combinations thereof.

10. The apparatus of claim 1 wherein the electrically chargeable fluid has a resistivity from about 1 kΩ

/cm to about 1000 MΩ

/cm.

11. The apparatus of claim 10 wherein the electrically chargeable fluid has a resistivity from about 100 kΩ

/cm to about 500 MΩ

/cm.

12. The apparatus of claim 1 wherein the filaments are formed from the material comprising the substrate displaced in a direction perpendicular to the substrate'"'"'s X-Y -plane.

13. The apparatus of claim 1 wherein the filaments are selected from the group consisting of free-ended fibers, looped fibers, molded protrusions of fluid transport material, embroidered tuffs, apertured polymer films, sewn tuffs and combinations thereof.

14. The apparatus of claim 13 wherein the filaments of the fluid emitter comprise an average of about 1 to about 50 distinct fibers.

15. The apparatus of claim 14 wherein the filaments of the fluid emitter comprise an average of about 5 to about 20 distinct fibers.

16. The apparatus of claim 1 wherein the array of filaments is of a length (L) to form charged fluid droplets in the presence of the counter electrode, the droplets having an average diameter from about 1.0 nm to about 5000 nm.

17. The apparatus of claim 16 fluid wherein the array of filaments is of a length (L) to form charged fluid droplets in the presence of the counter electrode, the droplets having an average droplet diameter from about 5.0 nm to about 500 nm.

18. The apparatus of claim 17 wherein the array of filaments is of a length (L) to form charged fluid droplets in the presence of the counter electrode, the droplets having an average droplet diameter from about 10.0 nm to about 50.0 nm.

19. The apparatus of claim 18 wherein the fluid emitter has a distance (D) between filaments at the surface of the substrate equal to the average length (L).

20. The apparatus of claim 18 wherein the fluid emitter has a distance (D) at the surface of the substrate one and a half times the average length (L).

21. The fluid emitter of claim 18 wherein the distance (D) at the surface of the substrate is twice the average length (L).

22. The apparatus of claim 1 wherein the substrate additionally comprises a top sheet having a filament array protruding through the top sheet in the direction of the counter electrode.

23. The apparatus of claim 1 wherein the electrically chargeable fluid is held within a fluid reservoir in fluid communication with the electrical fluid charger.

24. The apparatus of claim 1 wherein the electrical fluid charger is in proximity sufficient to charge fluid saturating the emitter substrate.

25. The apparatus of claim 24 wherein the proximity is direct contact of the adjacent surfaces of the charging electrode and the emitter substrate.

26. The apparatus of claim 24 wherein the electrical fluid charger has an electric field strength voltage gradient capable of transferring the electrical charge to the electrically chargeable fluid to produce electrical field strength in the range from about 500 volts per centimeter (V/cm) to about 5000 V/cm.

27. The apparatus of claim 26 wherein the electric fluid charger comprises a plurality of electrodes one being at a point in the fluid reservoir to remain in fluid communication with the fluid in the reservoir.

28. The apparatus of claim 24 wherein the electrical fluid charger has an electric field strength voltage gradient capable of transferring the electrical charge to the electrically chargeable fluid to produce electrical field strength in the range from about 1000 V/cm to about 3000 V/cm.

29. The apparatus of claim 1 wherein the counter electrode is selected from the group of animate objects, inanimate objects and combinations thereof.

30. The apparatus of claim 29 wherein the inanimate objects are selected from the group consisting of household surfaces, fabrics, car interiors, convertible tops and combinations thereof.

31. The apparatus of claim 29 wherein the animate objects are selected from the group consisting of skin, hair, moist tissue, finger nails and combinations thereof