Sorbent compositions, sorbent articles, methods for preparing sorbent articles, and methods for capturing target gases using the sorbent articles

• US 8,974,577 B2
• Filed: 04/23/2013
• Issued: 03/10/2015
• Est. Priority Date: 04/23/2013
• Status: Active Grant

• Current Assignee: Corning Incorporated
• Original Assignee: Corning Incorporated
• Inventors: Jiang, Dayue David, Ogunwumi, Steven Bolaji
• Primary Examiner(s): LAWRENCE JR, FRANK M
• Application Number:
  US13/868,332
• Publication Number:
  US 20140311341A1
• Time in Patent Office: 686 Days
• Field of Search: 961/53, 961/54, 951/29, 95135-137, 951/39, 959/00, 502/401, 502/402, 423/230, 423/239.1, 423/244.01, 423/244.02, 427/244
• US Class Current: 95/129
• CPC Class Codes: B01D 2253/102 Carbon
• CPC Class Codes: B01D 2253/202 Polymeric adsorbents
• CPC Class Codes: B01D 2253/25 Coated, impregnated or composite adsorbents
• CPC Class Codes: B01D 2257/302 Sulfur oxides
• CPC Class Codes: B01D 2257/304 Hydrogen sulfide
• CPC Class Codes: B01D 2257/306 Organic sulfur compounds, e.g. mercaptans
• CPC Class Codes: B01D 2257/402 Dinitrogen oxide
• CPC Class Codes: B01D 2257/404 Nitrogen oxides other than dinitrogen oxide
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: B01D 53/04 with stationary adsorbents B01D53/025 takes precedence
• CPC Class Codes: B01D 53/0407 Constructional details of adsorbing systems
• CPC Class Codes: B01D 53/50 Sulfur oxides B01D53/60 takes precedence
• CPC Class Codes: B01D 53/52 Hydrogen sulfide
• CPC Class Codes: B01D 53/56 Nitrogen oxides B01D53/60 takes precedence
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: B01J 20/22 comprising organic material
• CPC Class Codes: B01J 20/265 modified or post-treated polymers polymer carriers or substrates subjected to further impregnating or coating B01J20/3208
• CPC Class Codes: B01J 20/28033 Membrane, sheet, cloth, pad, lamellar or mat
• CPC Class Codes: B01J 20/28045 Honeycomb or cellular structures; Solid foams or sponges
• CPC Class Codes: B01J 20/3242 : Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
• CPC Class Codes: Y02C 20/10 : of nitrous oxide (N2O)
• CPC Class Codes: Y02C 20/40 : of CO2

Abstract

Articles for capturing or separating a target gas from a gas stream may include a porous substrate such as a flexible sheet or mat, or a rigid ceramic monolith impregnated or coated with a sorbent composition. The sorbent composition may include a polyamine and a coexistent polymer chemically bonded to the polyamine. The polyamine may include a polyethylenimine. The coexistent polymer may include a polyurethane, a polyolefin-acrylic acid copolymer, or a combination thereof. The sorbent composition may be substantially less water-insoluble than compositions containing only a polyamine and may have high durability and good adsorption capacity for acidic target gases such as carbon dioxide. Methods for preparing the articles using aqueous polymer solutions are provided. Methods for capturing or separating target gases using the articles are provided.

Claims

1. An article for capturing or separating a target gas from a gas stream, the article comprising a porous substrate impregnated or coated with a sorbent composition, the sorbent composition comprising a polyamine and a coexistent polymer chemically bonded to the polyamine, wherein the coexistent polymer is chosen from polyurethanes, polyolefin-acrylic acid copolymers, and combinations thereof.

2. The article of claim 1, wherein the polyamine is chosen from polyethylenimines, polyamidoamines, polyvinylamines, alkylaminoalkoxysilanes, tetraethylenepentamine, diethanolamine, diethylenetriamine, pentaethylenehexamine, tetraethylenepentamine-acrylonitrile, N-[(3-trimethoxysilyl)propyl]-ethylenediamine, N-[(3-trimethoxysilyl)propyl]diethylenetriamine, polyaziridine, and combinations thereof.

3. The article of claim 1, wherein the polyamine comprises a polyethylenimine.

4. The article of claim 1, wherein the coexistent polymer comprises a polyolefin-acrylic acid copolymer and the polyolefin-acrylic acid copolymer comprises a copolymer of ethylene and acrylic acid ammonium salt.

5. The article of claim 1, wherein the coexistent polymer comprises a polyurethane.

6. The article of claim 1, wherein the porous substrate comprises a nonwoven or woven sheet or mat containing fibers chosen from cellulosic materials, polypropylene, carbon, or activated carbon.

7. The article of claim 1, wherein the coexistent polymer is chemically bonded to both the polyamine and the porous substrate.

8. The article of claim 1, wherein:

the polyamine comprises a polyethylenimine;

the coexistent polymer comprises a polyurethane; and

the polyethylenimine is chemically bonded to the polyurethane through urea linkages.

9. The article of claim 1, wherein the target gas is hydrogen sulfide, carbon dioxide, carbon disulfide, nitric oxide, nitrogen dioxide, sulfur dioxide, sulfur trioxide, mercaptans, or mixtures thereof.

10. The article of claim 1, wherein the polyamine is a polyethylenimine having a weight-average molecular weight of from about 600 Dalton to about 15,000 Dalton.

11. The article of claim 1, wherein the weight ratio of the polyethylenimine to the coexistent polymer in the sorbent composition is from about 1:

1 to about 10;

1.

12. A method for preparing an article for capturing or separating a target gas from a gas stream, the method comprising:

applying an aqueous solution to a first porous substrate, the aqueous solution comprising a polyamine and a coexistent polymer chosen from polyurethanes, polyolefin-acrylic acid copolymers, and combinations thereof; and

drying the first porous substrate having the aqueous solution thereon to form a sorbent composition impregnated in or coated on the first porous substrate that is a reaction product of the polyamine and the coexistent polymer.

13. The method of claim 12, wherein the polyamine is a polyethylenimine.

14. The method of claim 12, further comprising:

applying the aqueous solution to at least one additional porous substrate;

drying each additional porous substrate having the aqueous solution thereon; and

stacking the additional porous substrates over the first porous substrate to form a stacked article.

15. The method of claim 14, wherein stacking the additional porous substrates comprises including at least one spacer sheet between adjacent porous substrates.

16. The method of claim 14, further comprising shaping the stacked article to form a tubular sorbent article.

17. A method for capturing or separating a target gas from a gas stream, the method comprising:

flowing the gas stream through a porous substrate of an article, the porous substrate being impregnated or coated with a sorbent composition comprising a polyamine and a coexistent polymer chosen from polyurethanes, polyolefin-acrylic acid copolymers, and combinations thereof.

18. The method of claim 17, wherein the polyamine is a polyethylenimine.

19. The method of claim 17, wherein the target gas is hydrogen sulfide, carbon dioxide, carbon disulfide, nitric oxide, nitrogen dioxide, sulfur dioxide, sulfur trioxide, mercaptans, or mixtures thereof.

20. The method of claim 17, wherein the flowing is conducted at a temperature of from about 100°

C. to about 400°

C.