Process to enhance mixing of dry sorbents and flue gas for air pollution control

• US 8,974,756 B2
• Filed: 07/25/2013
• Issued: 03/10/2015
• Est. Priority Date: 07/25/2012
• Status: Active Grant

• Current Assignee: ARQ Solutions Incorporated
• Original Assignee: ADA-ES, Inc. (Advanced Emissions Solutions, Inc.)
• Inventors: Martin, Cameron E.
• Primary Examiner(s): VANOY, TIMOTHY C
• Application Number:
  US13/951,167
• Publication Number:
  US 20140030178A1
• Time in Patent Office: 593 Days
• Field of Search: 423/210, 423/220, 423/239.1, 423/240.S, 423/244.03, 423/244.07, 423/215.5, 422/168, 422/177
• US Class Current: 423/210
• CPC Class Codes: B01D 2251/108 Halogens or halogen compounds hydrogen halides B01D2251/50
• CPC Class Codes: B01D 2251/404 of calcium
• CPC Class Codes: B01D 2253/102 Carbon
• CPC Class Codes: B01D 2253/25 Coated, impregnated or composite adsorbents
• CPC Class Codes: B01D 2257/204 Inorganic halogen compounds
• CPC Class Codes: B01D 2257/302 Sulfur oxides
• CPC Class Codes: B01D 2257/404 Nitrogen oxides other than dinitrogen oxide
• CPC Class Codes: B01D 2257/602 Mercury or mercury compounds
• CPC Class Codes: B01D 2257/70 Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
• CPC Class Codes: B01D 2258/0283 Flue gases
• CPC Class Codes: B01D 53/40 Acidic components B01D53/44 takes precedence
• CPC Class Codes: B01D 53/508 by treating the gases with solids
• CPC Class Codes: B01D 53/52 Hydrogen sulfide
• CPC Class Codes: B01D 53/565 by treating the gases with solids
• CPC Class Codes: B01D 53/64 Heavy metals or compounds thereof, e.g. mercury
• CPC Class Codes: B01D 53/685 by treating the gases with solids
• CPC Class Codes: B01D 53/83 with moving reactants
• CPC Class Codes: Y02C 20/30 of perfluorocarbons [PFC], hydrofluorocarbons [HFC] or sulfur hexafluoride [SF6]

Abstract

The disclosure provides an improved means of controlling mercury emissions from coal-fired boiler applications. Specifically, the disclosure comprises a static mixing device placed in the flue gas stream. The static mixing device can enhance dispersion of injected sorbents in the flue gas, resulting in improved mercury capture at a lower sorbent injection rate.

Claims

1. A method, comprising:

introducing an additive to a contaminated gas stream to form an additive-containing gas stream, the additive at least partially removing or causing the removal of the contaminant;

passing the contaminated gas stream through an air heater to transfer thermal energy from the contaminated gas stream to air prior to introduction of the air into the thermal unit;

passing the additive-containing gas stream through a static mixing device, positioned in the gas stream, to form a mixed gas stream, wherein energy for mixing by the static mixing device is from a loss in pressure as the additive-containing gas stream flows through the static mixing device; and

removing, by a particulate control device, particulates from the mixed gas stream, wherein the particulates comprise at least some of the contaminant and/or a derivative thereof.

5. The method of claim 1, wherein the static mixing device comprises an arrangement of substantially stationary mixing elements that induce turbulence in the additive-containing gas stream, wherein the mixing elements are one or more of static fan-type blades, baffles, and/or plates, wherein the additive-containing gas stream has substantially non-laminar flow, and wherein the static mixing device simultaneously causes flow division and radial mixing in the additive-containing gas stream.

6. The method of claim 5, wherein the mixing elements are curved and/or helically shaped, wherein the mixing elements are stationary and/or non-moving, wherein the static mixing device has from about 2 to about 25 mixing elements, wherein a flue gas velocity of the additive-containing gas stream ranges from about 5 to about 50 m/s, wherein the static mixing device is positioned upstream from the particulate control device, and wherein the distance is from about one to about ten times a hydraulic diameter of a duct carrying the mixed gas stream.

11. The method of claim 1, wherein the additive is introduced into the contaminated gas stream upstream of an air heater, wherein the mixing elements are stationary and/or non-moving, wherein the static mixing device has from about 2 to about 25 mixing elements, wherein a flue gas velocity of the additive-containing gas stream ranges from about 5 to about 50 m/s, wherein the static mixing device is positioned upstream from the particulate control device, and wherein the distance is from about one to about ten times a hydraulic diameter of a duct carrying the mixed gas stream.

12. The method of claim 11, wherein the static mixing device is positioned upstream of the air heater, wherein the mixing elements are stationary and/or non-moving, wherein the static mixing device has from about 2 to about 25 mixing elements, wherein a flue gas velocity of the additive-containing gas stream ranges from about 5 to about 50 m/s, wherein the static mixing device is positioned upstream from the particulate control device, and wherein the distance is from about one to about ten times a hydraulic diameter of a duct carrying the mixed gas stream.

13. The method of claim 12, wherein the additive is an alkaline sorbent and wherein a mercury capture sorbent is introduced into the mixed gas stream downstream of the static mixing device and air heater.

14. The method of claim 11, wherein the static mixing device is positioned downstream of the air heater.

15. The method of claim 12, wherein the additive is an alkaline sorbent and wherein a mercury capture sorbent is introduced into the mixed gas stream downstream of the static mixing device and air heater.

33. The method of claim 1, wherein the contaminant comprises one or more of nitrogen oxides (NO_x), sulfur oxides (SOx), hydrochloric acid (HC1), hydrogen sulfide, and hydrofluoric acid (HF) and wherein the additive is one or more of lime, an alkaline earth metal sesquicarbonate, an alkali metal sesquicarbonate, a metal oxide, an alkaline earth metal carbonate, an alkali earth metal carbonate, an alkaline earth metal bicarbonate, and an alkali earth metal bicarbonate.

2. A method, comprising:

introducing an additive to a contaminated gas stream to form an additive-containing gas stream, the additive at least partially removing or causing the removal of the contaminant;

passing the additive-containing gas stream through a static mixing device, positioned in the gas stream, to form a mixed gas stream, wherein energy for mixing by the static mixing device is from a loss in pressure as the additive-containing gas stream flows through the static mixing device; and

removing, by a particulate control device, particulates from the mixed gas stream, wherein the particulates comprise at least some of the contaminant and/or a derivative thereof, wherein the at least one contaminant comprises mercury, and wherein the additive is one or more of a halogen, halide, and powdered activated carbon.

34. The method of claim 2, wherein the contaminant comprises one or more of nitrogen oxides (NO_x), sulfur oxides (SOx), hydrochloric acid (HC1), hydrogen sulfide, and hydrofluoric acid (HF) and wherein the additive is one or more of lime, an alkaline earth metal sesquicarbonate, an alkali metal sesquicarbonate, a metal oxide, an alkaline earth metal carbonate, an alkali earth metal carbonate, an alkaline earth metal bicarbonate, and an alkali earth metal bicarbonate.

3. A method, comprising:

introducing an additive to a contaminated gas stream to form an additive-containing gas stream, the additive at least partially removing or causing the removal of the contaminant;

passing the additive-containing gas stream through a static mixing device, positioned in the gas stream, to form a mixed gas stream; and

removing, by a particulate control device, particulates from the mixed gas stream, wherein the particulates comprise at least some of the contaminant and/or a derivative thereof and wherein the at least one contaminant comprises one or more of nitrogen oxides (NO_x), sulfur oxides (SOx), hydrochloric acid (HC1), hydrogen sulfide, and hydrofluoric acid (HF) and wherein the additive is one or more of lime, an alkaline earth metal sesquicarbonate, an alkali metal sesquicarbonate, a metal oxide, an alkaline earth metal carbonate, an alkali earth metal carbonate, an alkaline earth metal bicarbonate, and an alkali earth metal bicarbonate.

4. A method, comprising:

introducing an additive to a contaminated gas stream to form an additive-containing gas stream, the additive at least partially removing or causing the removal of the contaminant;

passing the additive-containing gas stream through a static mixing device, positioned in the gas stream, to form a mixed gas stream, wherein energy for mixing by the static mixing device is from a loss in pressure as the additive-containing gas stream flows through the static mixing device; and

removing, by a particulate control device, particulates from the mixed gas stream, wherein the particulates comprise at least some of the contaminant and/or a derivative thereof and wherein a distance from an output of the static mixing device to an input of the downstream particulate control device is at least about one times the hydraulic diameter of a conduit positioned between the static mixing device and particulate control device.

35. The method of claim 4, wherein the contaminant comprises one or more of nitrogen oxides (NO_x), sulfur oxides (SOx), hydrochloric acid (HC1), hydrogen sulfide, and hydrofluoric acid (HF) and wherein the additive is one or more of lime, an alkaline earth metal sesquicarbonate, an alkali metal sesquicarbonate, a metal oxide, an alkaline earth metal carbonate, an alkali earth metal carbonate, an alkaline earth metal bicarbonate, and an alkali earth metal bicarbonate.

7. A method, comprising:

introducing an additive to a contaminated gas stream to form an additive-containing gas stream, the additive at least partially removing or causing the removal of the contaminant;

passing the additive-containing gas stream through a static mixing device, positioned in the gas stream, to form a mixed gas stream, wherein energy for mixing by the static mixing device is from a loss in pressure as the additive-containing gas stream flows through the static mixing device; and

removing, by a particulate control device, particulates from the mixed gas stream, wherein the particulates comprise at least some of the contaminant and/or a derivative thereof and wherein a distance from a point of introduction of the additive into the contaminated gas stream to an input to the static mixing device is at least about one times the hydraulic diameter of a conduit positioned between the point of introduction and the input.

36. The method of claim 7, wherein the contaminant comprises one or more of nitrogen oxides (NO_x), sulfur oxides (SOx), hydrochloric acid (HC1), hydrogen sulfide, and hydrofluoric acid (HF) and wherein the additive is one or more of lime, an alkaline earth metal sesquicarbonate, an alkali metal sesquicarbonate, a metal oxide, an alkaline earth metal carbonate, an alkali earth metal carbonate, an alkaline earth metal bicarbonate, and an alkali earth metal bicarbonate.

8. A method, comprising:

introducing an additive to a contaminated gas stream to form an additive-containing gas stream, the additive at least partially removing or causing the removal of the contaminant;

passing the additive-containing gas stream through a static mixing device, positioned in the gas stream, to form a mixed gas stream, wherein energy for mixing by the static mixing device is from a loss in pressure as the additive-containing gas stream flows through the static mixing device; and

removing, by a particulate control device, particulates from the mixed gas stream, wherein the particulates comprise at least some of the contaminant and/or a derivative thereof, wherein the additive is introduced into the contaminated gas stream downstream of an air heater, and wherein the static mixing device is positioned downstream of both the air heater and the point of introduction of the additive.

9. The method of claim 8, wherein the additive is an alkaline sorbent and wherein a mercury capture sorbent is introduced into the mixed gas stream downstream of the static mixing device.

10. The method of claim 9, wherein the alkaline sorbent is introduced into the contaminated gas stream downstream of a first particulate control device and upstream of a second particulate control device.

37. The method of claim 8, wherein the contaminant comprises one or more of nitrogen oxides (NO_x), sulfur oxides (SOx), hydrochloric acid (HC1), hydrogen sulfide, and hydrofluoric acid (HF) and wherein the additive is one or more of lime, an alkaline earth metal sesquicarbonate, an alkali metal sesquicarbonate, a metal oxide, an alkaline earth metal carbonate, an alkali earth metal carbonate, an alkaline earth metal bicarbonate, and an alkali earth metal bicarbonate.

16. A method, comprising:

introducing an additive to a contaminated gas stream to form an additive-containing gas stream, the additive at least partially removing or causing the removal of the contaminant;

passing the additive-containing gas stream through a static mixing device, positioned in the gas stream, to form a mixed gas stream, wherein energy for mixing by the static mixing device is from a loss in pressure as the additive-containing gas stream flows through the static mixing device; and

removing, by a particulate control device, particulates from the mixed gas stream, wherein the particulates comprise at least some of the contaminant and/or a derivative thereof, wherein the additive comprises both an alkaline sorbent and a mercury capture sorbent, and wherein both the alkaline and mercury capture sorbents are introduced into the contaminated gas stream upstream of the static mixing device.

38. The method of claim 16, wherein the contaminant comprises one or more of nitrogen oxides (NO_x), sulfur oxides (SOx), hydrochloric acid (HC1), hydrogen sulfide, and hydrofluoric acid (HF) and wherein the additive is one or more of lime, an alkaline earth metal sesquicarbonate, an alkali metal sesquicarbonate, a metal oxide, an alkaline earth metal carbonate, an alkali earth metal carbonate, an alkaline earth metal bicarbonate, and an alkali earth metal bicarbonate.

17. A method, comprising:

introducing an additive to a contaminated gas stream to form an additive-containing gas stream, the additive at least partially removing or causing the removal of the contaminant;

passing the additive-containing gas stream through a static mixing device, positioned in the gas stream, to form a mixed gas stream, wherein energy for mixing by the static mixing device is from a loss in pressure as the additive-containing gas stream flows through the static mixing device; and

removing, by a particulate control device, particulates from the mixed gas stream, wherein the particulates comprise at least some of the contaminant and/or a derivative thereof, wherein the static mixing device comprises an arrangement of substantially stationary mixing elements that induce turbulence in the additive-containing gas stream, wherein the mixing elements are one or more of static fan-type blades, baffles, and/or plates, wherein the additive-containing gas stream has substantially non-laminar flow, and wherein the static mixing device simultaneously causes flow division and radial mixing in the additive-containing gas stream, and wherein the arrangement of mixing elements comprises from about 1 to about 5 mixing elements.

39. The method of claim 17, wherein the contaminant comprises one or more of nitrogen oxides (NO_x), sulfur oxides (SOx), hydrochloric acid (HC1), hydrogen sulfide, and hydrofluoric acid (HF) and wherein the additive is one or more of lime, an alkaline earth metal sesquicarbonate, an alkali metal sesquicarbonate, a metal oxide, an alkaline earth metal carbonate, an alkali earth metal carbonate, an alkaline earth metal bicarbonate, and an alkali earth metal bicarbonate.

18. A contaminated gas treatment system, comprising:

a thermal unit to combust a contaminated feed material and produce a contaminated gas stream;

an air heater to transfer thermal energy from the contaminated gas stream to air prior to introduction of the air into the thermal unit;

an additive injection system to introduce an additive into the contaminated gas stream, the additive controlling a contaminate level in a treated gas stream prior to discharge of the treated gas stream into the environment;

a static mixing device positioned downstream of the additive injection system to form a mixed gas stream comprising a substantially homogeneous distribution of the additive in the mixed gas stream, wherein energy for mixing by the static mixing device is from a loss in pressure as the additive-containing gas stream flows through the static mixing device; and

a downstream particulate control device to remove particulates from the mixed gas stream and form the treated gas stream.

19. The system of claim 18, wherein a distance from an output of the static mixing device to an input of the downstream particulate control device is at least about one times the hydraulic diameter of a conduit positioned between the static mixing device and particulate control device.

20. The system of claim 18, wherein the static mixing device comprises an arrangement of substantially rigid and stationary mixing elements that induce turbulence in the additive-containing gas stream, wherein the mixing elements are one or more of static fan-type blades, baffles, and/or plates, wherein the additive-containing gas stream has substantially non-laminar flow, wherein the arrangement of mixing elements comprises from about 1 to about 25 mixing elements, and wherein the static mixing device simultaneously causes flow division and radial mixing in the additive-containing gas stream.

21. The system of claim 20, wherein the mixing elements are curved and/or helically shaped, wherein the mixing elements are stationary and/or non-moving, wherein the static mixing device has from about 2 to about 5 mixing elements, wherein a flue gas velocity of the additive-containing gas stream ranges from about 5 to about 50 m/s, wherein the static mixing device is positioned upstream from the particulate control device, and wherein the distance is from about one to about ten times a hydraulic diameter of a duct carrying the mixed gas stream.

22. The system of claim 18, wherein a distance from a point of introduction of the additive into the contaminated gas stream to an input to the static mixing device is at least about one times the hydraulic diameter of a conduit positioned between the point of introduction and the input.

23. The system of claim 18, wherein the additive is introduced into the contaminated gas stream downstream of the air heater, wherein the static mixing device is positioned downstream of both the air heater and the point of introduction of the additive, wherein the mixing elements are stationary and/or non-moving, wherein the static mixing device has from about 2 to about 25 mixing elements, wherein a flue gas velocity of the additive-containing gas stream ranges from about 5 to about 50 m/s, wherein the static mixing device is positioned upstream from the particulate control device, and wherein the distance is from about one to about ten times a hydraulic diameter of a duct carrying the mixed gas stream.

24. The system of claim 23, wherein the additive is an alkaline sorbent and wherein a mercury capture sorbent is introduced into the mixed gas stream downstream of the static mixing device.

25. The system of claim 24, wherein the alkaline sorbent is introduced into the contaminated gas stream downstream of a first particulate control device and upstream of the downstream particulate control device.

26. The system of claim 18, wherein the additive is introduced into the contaminated gas stream upstream of the air heater.

27. The system of claim 26, wherein the static mixing device is positioned upstream of the air heater, wherein the mixing elements are stationary and/or non-moving, wherein the static mixing device has from about 2 to about 25 mixing elements, wherein a flue gas velocity of the additive-containing gas stream ranges from about 5 to about 50 m/s, wherein the static mixing device is positioned upstream from the particulate control device, and wherein the distance is from about one to about ten times a hydraulic diameter of a duct carrying the mixed gas stream.

28. The system of claim 27, wherein the additive is an alkaline sorbent and wherein a mercury capture sorbent is introduced into the mixed gas stream downstream of the static mixing device and air heater.

29. The system of claim 26, wherein the static mixing device is positioned downstream of the air heater.

30. The system of claim 26, wherein the additive is an alkaline sorbent and wherein a mercury capture sorbent is introduced into the mixed gas stream downstream of the static mixing device and air heater.

31. The system of claim 18, wherein the additive comprises both an alkaline sorbent and a mercury capture sorbent and wherein both the alkaline and mercury capture sorbents are introduced into the contaminated gas stream upstream of the static mixing device.

32. The system of claim 20, wherein the arrangement of mixing elements comprises from about 1 to about 5 mixing elements.

40. The system of claim 18, wherein the contaminant comprises one or more of nitrogen oxides (NO_x), sulfur oxides (SOx), hydrochloric acid (HC1), hydrogen sulfide, and hydrofluoric acid (HF) and wherein the additive is one or more of lime, an alkaline earth metal sesquicarbonate, an alkali metal sesquicarbonate, a metal oxide, an alkaline earth metal carbonate, an alkali earth metal carbonate, an alkaline earth metal bicarbonate, and an alkali earth metal bicarbonate.