Articles incorporating thermographic phosphors, and methods and apparatus for authenticating such articles

• US 8,975,598 B2
• Filed: 01/09/2013
• Issued: 03/10/2015
• Est. Priority Date: 01/17/2012
• Status: Active Grant

• Current Assignee: Honeywell International Inc.
• Original Assignee: Honeywell International Inc.
• Inventors: Rapoport, William Ross, Kane, James, Lau, Carsten, Patel, Chirag, Croiter, Jack Steven
• Primary Examiner(s): Porta, David
• Assistant Examiner(s): VALENTINER, JEREMY SCOTT
• Application Number:
  US13/737,594
• Publication Number:
  US 20130181144A1
• Time in Patent Office: 790 Days
• Field of Search: 250/458.1, 250/459.1
• US Class Current: 250/459.1
• CPC Class Codes: B42D 15/00 Printed matter of special format or style not otherwise provided for
• CPC Class Codes: B42D 25/355 Security threads
• CPC Class Codes: B42D 25/36 comprising special materials
• CPC Class Codes: C09D 11/50 Sympathetic, colour changing or similar inks
• CPC Class Codes: C09D 11/52 Electrically conductive inks
• CPC Class Codes: C09K 11/7701 Chalogenides
• CPC Class Codes: C09K 11/7769 Oxides C09K11/7768 takes precedence
• CPC Class Codes: G01K 11/20 using thermoluminescent materials G01K11/32 takes precedence
• CPC Class Codes: G01N 21/64 Fluorescence; Phosphorescence
• CPC Class Codes: G01N 25/00 Investigating or analyzing materials by the use of thermal means G01N3/00 - G01N23/00 take precedence
• CPC Class Codes: G07D 7/12 Visible light, infrared or ultraviolet radiation
• CPC Class Codes: G07D 7/1205 Testing spectral properties
• CPC Class Codes: G07D 7/15 using heating means

Abstract

Embodiments include methods and apparatus for identifying a thermographic phosphor (e.g., Er:YIG) incorporated on or within an article. The method and apparatus embodiments include an excitation energy generator selectively exposing the article to excitation energy in an absorption band of the thermographic phosphor. An emitted radiation detector detects first emission characteristics of first emitted radiation from the article within an emission band of the thermographic phosphor when the article has a first temperature, and detects second emission characteristics of second emitted radiation from the article within the emission band when the article has a second temperature that is different from the first temperature. A temperature adjustment element is configured to adjust the temperature of the article. Embodiments further include a processing system determining whether the first emission characteristics are sufficiently different from the second emission characteristics.

Claims

1. A method for identifying a luminescent material incorporated on or within an article, the method comprising the steps of:

selectively exposing the article to excitation energy in an absorption band of the luminescent material;

detecting first emission characteristics of first emitted radiation from the article within an emission band of the luminescent material when the article has a first temperature;

detecting second emission characteristics of second emitted radiation from the article within the emission band when the article has a second temperature that is different from the first temperature; and

determining whether the first emission characteristics are sufficiently different from the second emission characteristics, wherein determining whether the first emission characteristics are sufficiently different from the second emission characteristics comprises determining whether a first intensity of the first emitted radiation is at least about 1 percent different from a second intensity of the second emitted radiation for each degree of difference between the first and second temperatures.

2. The method of claim 1, wherein selectively exposing the article to the excitation energy comprises:

first exposing a portion of the article to the excitation energy during a first period of time that coincides with the portion of the article having the first temperature;

discontinuing the first exposing prior to detecting the first emission characteristics;

second exposing the portion of the article to the excitation energy during a second period of time that coincides with the portion of the article having the second temperature; and

discontinuing the second exposing prior to detecting the second emission characteristics.

3. The method of claim 1, wherein at least one of the first temperature and the second temperature is a temperature that is achieved through active control of a temperature adjustment element, and wherein the method further comprises:

actively controlling the temperature adjustment element to achieve the at least one of the first temperature or the second temperature.

4. The method of claim 3, wherein both the first temperature and the second temperature are temperatures that are achieved through active control of the temperature adjustment element, and wherein actively controlling the temperature adjustment element comprises:

prior to detecting the first emission characteristics, actively controlling the temperature adjustment element to achieve the first temperature; and

after detecting the first emission characteristics but prior to detecting the second emission characteristics, actively controlling the temperature adjustment element to achieve the second temperature.

5. The method of claim 3, wherein one of the first temperature or the second temperature is achieved through active control of the temperature adjustment element, and another one of the first temperature or the second temperature is ambient temperature, and wherein the method further comprises:

sensing the ambient temperature.

6. The method of claim 1, wherein the first temperature and the second temperature are different from each other by a temperature difference in a range of about +/−

5 degrees Celsius to about +/−

15 degrees Celsius.

7. The method of claim 1, wherein detecting the first emissions and detecting the second emissions comprises sequentially detecting emissions from a same portion of the article.

8. The method of claim 1, wherein determining whether the first emission characteristics are sufficiently different from the second emission characteristics comprises determining whether intensities of the first and second emitted radiation exhibit an inversely proportional relationship to temperature.

9. The method of claim 1, wherein determining whether the first emission characteristics are sufficiently different from the second emission characteristics comprises determining whether decay time constants for the first and second emitted radiation exhibit an inversely proportional relationship to temperature.

10. The method of claim 1, wherein the absorption band is an absorption band of iron, and wherein the emission band is an emission band of erbium.

11. The method of claim 1, further comprising:

when the first emission characteristics are not sufficiently different from the second emission characteristics, designating the article as being not authentic; and

when the first emission characteristics are sufficiently different from the second emission characteristics, designating the article as being authentic.

12. A method for identifying a luminescent material incorporated on or within an article, the method comprising the steps of:

selectively exposing the article to excitation energy in an absorption band of the luminescent material;

detecting first emission characteristics of first emitted radiation from the article within an emission band of the luminescent material when the article has a first temperature;

detecting second emission characteristics of second emitted radiation from the article within the emission band when the article has a second temperature that is different from the first temperature; and

determining whether the first emission characteristics are sufficiently different from the second emission characteristics, wherein determining whether the first emission characteristics are sufficiently different from the second emission characteristics comprises determining whether a first decay time constant of the first emitted radiation is at least about 1 percent different from a second decay time constant of the second emitted radiation for each degree of difference between the first and second temperatures.