Formation process for lithium-ion batteries

• US 8,980,453 B2
• Filed: 04/30/2008
• Issued: 03/17/2015
• Est. Priority Date: 04/30/2008
• Status: Active Grant

• Current Assignee: Medtronic Incorporated (Medtronic Plc)
• Original Assignee: Medtronic Incorporated (Medtronic Plc)
• Inventors: Scott, Erik R., Jain, Gaurav
• Primary Examiner(s): Laios, Maria J
• Application Number:
  US12/112,979
• Publication Number:
  US 20090274849A1
• Time in Patent Office: 2,512 Days
• Field of Search: 320155-159
• US Class Current: 429/50
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 10/0569 characterised by the solvents
• CPC Class Codes: H01M 10/446 Initial charging measures
• CPC Class Codes: H01M 2010/4292 Aspects relating to capacity ratio of electrodes/electrolyte or anode/cathode
• CPC Class Codes: H01M 2300/0028 characterised by the solvent
• CPC Class Codes: H01M 4/131 Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
• CPC Class Codes: H01M 4/485 of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy H01M4/505, H01M4/525 take precedence
• CPC Class Codes: H01M 4/583 Carbonaceous material, e.g. graphite-intercalation compounds or CFx
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y10T 29/49108 Electric battery cell making

Abstract

A method for producing a battery includes providing a battery having a positive electrode, a negative electrode, and an electrolyte that includes a solvent and a salt. The capacity of the negative electrode is less than that of the positive electrode and the negative electrode includes an active material having an average potential versus a lithium reference electrode of greater than approximately 0.2 volts. The method also includes applying an initial charge to the battery at a voltage that is greater than a fully charged voltage of the battery for a sufficient amount of time to cause at least a portion of the solvent to undergo a reduction reaction. The step of applying an initial charge to the battery acts to increase the irreversible capacity loss of the battery during the initial charge and provides the battery with enhanced tolerance to deep discharge conditions.

Claims

1. A method for producing a battery comprising:

providing a battery comprising a positive electrode, a negative electrode, and an electrolyte comprising a solvent and a salt, wherein the capacity of the negative electrode is less than that of the positive electrode and the negative electrode comprises an active material having an average potential versus a lithium reference electrode of greater than approximately 1.0 volts; and

applying an initial charge to the battery and continuing the initial charge beyond the point where the battery is fully charged, wherein the initial charge after the battery is fully charged is applied for approximately 4 hours or more at a voltage that is greater than a fully charged voltage of the battery.

2. The method of claim 1, wherein step of applying an initial charge to the battery is performed for a sufficient amount of time to cause the potential of the negative electrode versus a lithium reference electrode to drop to a level such that an irreversible reaction occurs between the electrolyte and the negative electrode.

3. The method of claim 2, wherein the irreversible reaction forms a solid electrolyte interphase (SEI) layer on the negative electrode.

4. The method of claim 1, wherein the fully charged voltage of the battery is between approximately 2.5 and 3.0 volts and the step of applying an initial charge to the battery utilizes a voltage of between approximately 3.4 and 3.8 volts.

5. The method of claim 4, wherein the positive electrode comprises an active material and the step of applying an initial charge to the battery increases the zero volt crossing potential of the battery to a level that is greater than a decomposition potential of the active material of the positive electrode.

6. The method of claim 5, wherein the zero volt crossing potential of the battery after the step of applying the initial charge to the battery is greater than approximately 3.0 volts.

7. The method of claim 4, wherein the step of applying an initial charge to the battery is performed for a sufficient amount of time to cause the potential of the negative electrode versus a lithium reference electrode to drop to a level below approximately 0.9 volts.

8. The method of claim 1, wherein step of applying an initial charge to the battery occurs at a charging rate of approximately C/10 or slower.

9. The method of claim 1, wherein the negative electrode comprises an additive configured to enhance the formation of an SEI layer.

10. The method of claim 9, wherein the additive comprises carbon.

11. The method of claim 1, wherein the electrolyte comprises ethylene carbonate.

12. The method of claim 1, wherein the active material of the negative electrode comprises a lithium titanate material.

13. The method of claim 12, wherein the positive electrode comprises an active material comprising lithium cobalt oxide.

14. The method of claim 1, wherein between approximately 12% and approximately 20% irreversible capacity loss is created during the step of applying an initial charge and continuing the initial charge.

15. The method of claim 1, wherein the initial charge is applied after the negative electrode is saturated with cyclable lithium at a voltage that is greater than the fully charged voltage of the battery.

16. The method of claim 1, wherein after the battery is fully charged, application of the initial charge at the voltage that is greater than the fully charged voltage of the battery causes at least a portion of the solvent to undergo a reduction reaction.

17. The method of claim 16, wherein a passive film is formed on the negative electrode during the reduction reaction.

18. The method of claim 1, wherein during the step of applying an initial charge to the battery and continuing the initial charge, greater than approximately 12% irreversible capacity loss of the battery is created.

19. A method for producing a battery comprising:

providing a battery comprising a positive electrode, a negative electrode, and an electrolyte comprising a solvent and a salt, wherein the capacity of the negative electrode is less than that of the positive electrode and the negative electrode comprises an active material comprising lithium titanate; and

applying an initial charge to the battery and continuing the initial charge beyond the point where the battery is fully charged, wherein the initial charge after the battery is fully charged is applied for approximately 4 hours or more at a voltage that is greater than a fully charged voltage of the battery such that at least a portion of the solvent undergoes a reduction reaction and greater than approximately 12% irreversible capacity loss of the battery is created during the step of applying an initial charge and continuing the initial charge.

20. The method of claim 19, wherein during a deep discharge, the potential of the negative electrode rapidly increases to a zero volt crossing potential that is greater than a decomposition potential of an active material of the positive electrode.

21. The method of claim 20, wherein the zero volt crossing potential is greater than approximately 3.0 volts.

22. The method of claim 19, during the step of applying an initial charge to the battery and continuing the initial charge, a portion of the solvent undergoes a reduction reaction to form a solid electrolyte interphase (SEI) layer on the negative electrode.

23. The method of claim 19, wherein the positive electrode comprises an active material comprising lithium cobalt oxide.

24. A method for producing a battery comprising:

providing a battery comprising a positive electrode, a negative electrode, and an electrolyte comprising a solvent and a salt, wherein the capacity of the negative electrode is less than that of the positive electrode and the negative electrode comprises an active material having an average potential versus a lithium reference electrode of greater than approximately 1.0 volts; and

while the battery is fully charged, applying a charge to the battery at a voltage that is greater than a fully charged voltage of the battery for a period of time greater than or equal to approximately 4 hours.

25. The method of claim 24, wherein the period of time during which the charge is applied while the battery is fully charged is less than or equal to approximately 12 hours.

26. The method of claim 24, wherein the charge applied while the battery is fully charged is greater than or equal to approximately 0.6 volts more than a fully-charged voltage of the battery.

27. The method of claim 26, wherein the charge applied while the battery is fully charged is between approximately 3.4 volts and 3.8 volts.

28. The method of claim 27, wherein the active material of the negative electrode is lithium titanate.

29. The method of claim 28, wherein the positive electrode comprises an active material comprising lithium cobalt oxide.