Fuel cell

• US 8,980,486 B2
• Filed: 06/17/2010
• Issued: 03/17/2015
• Est. Priority Date: 06/17/2010
• Status: Expired due to Fees

• Current Assignee: Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Original Assignee: Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Inventors: Usami, Sho, Araki, Yasushi, Shibata, Kazunori, Ogawa, Tomohiro, Kawahara, Shuya
• Primary Examiner(s): RHEE, JANE J
• Application Number:
  US13/702,242
• Publication Number:
  US 20130089798A1
• Time in Patent Office: 1,734 Days
• Field of Search: 429/414, 429/429, 429/428, 429/433, 429/444
• US Class Current: 429/414
• CPC Class Codes: H01M 2008/1095 Fuel cells with polymeric electrolytes
• CPC Class Codes: H01M 8/0258 characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
• CPC Class Codes: H01M 8/0267 having heating or cooling means, e.g. heaters or coolant flow channels
• CPC Class Codes: H01M 8/04029 Heat exchange using liquids
• CPC Class Codes: H01M 8/04156 with product water removal
• CPC Class Codes: H01M 8/04223 during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
• CPC Class Codes: H01M 8/04225 during start-up
• CPC Class Codes: H01M 8/04253 Means for solving freezing problems
• CPC Class Codes: H01M 8/04302 applied during start-up
• CPC Class Codes: H01M 8/2483 characterised by internal manifolds
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A fuel cell system 10 removes water retaining in a cathode catalyst layer 217 in a fuel cell 20, after a start-up of the fuel cell 20 and before feed of coolant to the fuel cell 20.

Claims

1. A fuel cell system that operates a fuel cell configured to generate electric power through electrochemical reaction of hydrogen with oxygen, the fuel cell system comprising:

a cooling pump configured to feed a coolant to the fuel cell;

a determining unit configured to determine, after start-up of the fuel cell, whether the fuel cell is located in a cold environment that freezes water in the fuel cell if feeding the coolant is started in starting up the fuel cell; and

a water remover configured to remove water retaining in a cathode catalyst layer formed on a cathode side of an electrolyte membrane in the fuel cell when the fuel cell located in the cold environment is determined by the determining unit, after a start-up of the fuel cell and before feed of the coolant by the cooling pump,

further comprising;

a melt detector configured to detect melt of water frozen in the cathode catalyst layer, wherein

the water remover starts removal of the water retaining in the cathode catalyst layer when the melt of frozen water is detected by the melt detector, after the start-up of the fuel cell and before the feed of the coolant by the cooling pump.

2. The fuel cell system according to claim 1, wherein

the melt detector detects the melt of the water frozen in the cathode catalyst layer, based on an internal resistance of the fuel cell.

3. The fuel cell system according to claim 1, wherein

the fuel cell includes a cathode flow channel configured to make a flow of an oxidizing gas toward the cathode side of the electrolyte membrane, and

the water remover removes the water retaining in the cathode catalyst layer by introducing the oxidizing gas into the cathode flow channel in a state that electric current of the fuel cell is suspended, after the start-up of the fuel cell and before the feed of the coolant by the cooling pump.

4. The fuel cell system according to claim 1, further comprising:

a remaining water detector configured to detect an amount of remaining water in the cathode catalyst layer, wherein

the water remover terminates removal of the water retaining in the cathode catalyst layer, based on the amount of remaining water detected by the remaining water detector.

5. The fuel cell system according to claim 4, wherein

the fuel cell includes a cathode flow channel configured to make a flow of an oxidizing gas toward the cathode side of the electrolyte membrane, and

the remaining water detector detects the amount of remaining water in the cathode catalyst layer, based on a pressure loss of the oxidizing gas flowing through the cathode flow channel.

6. The fuel cell system according to claim 4, wherein

the remaining water detector detects the amount of remaining water in the cathode catalyst layer, based on an internal resistance of the fuel cell.

7. The fuel cell system according to claim 1, wherein

the fuel cell includes:

an anode catalyst layer formed on an anode side of the electrolyte membrane; and

an anode flow channel configured to make a flow of hydrogen gas toward the anode side of the electrolyte membrane, wherein

the water remover removes the water retaining in the cathode catalyst layer by increasing at least one of a stoichiometric ratio and temperature of the hydrogen gas flowing through the anode flow channel and thereby increasing an amount of water moving from the cathode catalyst layer toward the anode catalyst layer.

8. A method of operating a fuel cell configured to generate electric power through electrochemical reaction of hydrogen with oxygen, comprising:

determining, after start-up of the fuel cell, whether the fuel cell is located in a cold environment that freezes water in the fuel cell if feeding the coolant is started in starting up the fuel cell;

detecting melt of water frozen in the cathode catalyst layer; and

removing water retaining in a cathode catalyst layer formed on a cathode side of an electrolyte membrane in the fuel cell when the fuel cell located in the cold environment is determined and melt of water frozen in the cathode catalyst layer is detected, after a start-up of the fuel cell and before feed of a coolant to the fuel cell.