Electrophotographic photosensitive member, process cartridge and electrophotographic apparatus, and method for producing electrophotographic photosensitive member

• US 8,980,510 B2
• Filed: 08/21/2013
• Issued: 03/17/2015
• Est. Priority Date: 08/30/2012
• Status: Active Grant

• Current Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Original Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Inventors: Fujii, Atsushi, Tomono, Hiroyuki, Tsuji, Haruyuki
• Primary Examiner(s): Chapman, Mark A
• Application Number:
  US13/972,688
• Publication Number:
  US 20140065529A1
• Time in Patent Office: 573 Days
• Field of Search: 430/63, 430/131, 399/159
• US Class Current: 430/63
• CPC Class Codes: G03G 5/047 characterised by the charge-generation layers or charge transport layers G03G5/0433 and G03G5/0436 take precedence
• CPC Class Codes: G03G 5/104 comprising inorganic material other than metals, e.g. salts, oxides, carbon
• CPC Class Codes: G03G 5/144 comprising inorganic material

Abstract

An electrophotographic photosensitive member in which a leakage hardly occurs, a process cartridge and electrophotographic apparatus having the electrophotographic photosensitive member, and a method for producing the electrophotographic photosensitive member are provided. The conductive layer in the electrophotographic photosensitive member contains metal oxide particle coated with tin oxide doped with niobium or tantalum. The relations: Ia≦6,000 and 10≦Ib are satisfied. The conductive layer before the test is performed has a volume resistivity of not less than 1.0×10⁸ Ω·cm and not more than 5.0×10¹² Ω·cm.

Claims

1. An electrophotographic photosensitive member comprising:

a cylindrical support,

a conductive layer formed on the cylindrical support, and

a photosensitive layer formed on the conductive layer, wherein,

the conductive layer comprises;

a metal oxide particle coated with tin oxide doped with niobium or tantalum, and

a binder material,

Ia and Ib satisfy relations (i) and (ii);

Ia≦

6,000 

 

(i)

10≦

Ib 

 

(ii)

where, in the relation (i), Ia [μ

A] is an absolute value of the largest amount of a current flowing through the conductive layer when a test which continuously applies a voltage having only a DC voltage of −

1.0 kV to the conductive layer is performed, and, in the relation (ii), Ib [μ

A] is an absolute value of an amount of a current flowing through the conductive layer when a decrease rate per minute of the current flowing through the conductive layer reaches 1% or less for the first time, and

the conductive layer before the test is performed has a volume resistivity of not less than 1.0×

10⁸ Ω

·

cm and not more than 5.0×

10¹² Ω

·

cm.

2. The electrophotographic photosensitive member according to claim 1, wherein the metal oxide particle coated with tin oxide doped with niobium or tantalum is titanium oxide particle coated with tin oxide doped with niobium.

3. The electrophotographic photosensitive member according to claim 1, wherein the metal oxide particle coated with tin oxide doped with niobium or tantalum is titanium oxide particle coated with tin oxide doped with tantalum.

4. The electrophotographic photosensitive member according to claim 1, wherein the metal oxide particle coated with tin oxide doped with niobium or tantalum is tin oxide particle coated with tin oxide doped with niobium.

5. The electrophotographic photosensitive member according to claim 1, wherein the metal oxide particle coated with tin oxide doped with niobium or tantalum is tin oxide particle coated with tin oxide doped with tantalum.

6. The electrophotographic photosensitive member according to claim 1, wherein the metal oxide particle coated with tin oxide doped with niobium or tantalum is zinc oxide particle coated with tin oxide doped with niobium.

7. The electrophotographic photosensitive member according to claim 1, wherein the metal oxide particle coated with tin oxide doped with niobium or tantalum is zinc oxide particle coated with tin oxide doped with tantalum.

8. The electrophotographic photosensitive member according to claim 1, wherein the Ia and the Ib satisfy relations (iii) and (iv):

Ia≦

5,000 

 

(iii)

20≦

Ib 

 

(iv).

9. A process cartridge that integrally supports:

an electrophotographic photosensitive member according to claim 1, and

at least one unit selected from the group consisting of a charging unit, a developing unit, a transferring unit, and a cleaning unit, the cartridge being detachably mountable on a main body of an electrophotographic apparatus.

10. An electrophotographic apparatus comprising:

an electrophotographic photosensitive member according to claim 1,

a charging unit,

an exposing unit,

a developing unit, and

a transferring unit.

11. A method for producing an electrophotographic photosensitive member comprising:

forming a conductive layer having a volume resistivity of not less than 1.0×

10⁸ Ω

·

cm and not more than 5.0×

10¹² Ω

·

cm on a cylindrical support, and

forming a photosensitive layer on the conductive layer,

wherein,

the formation of the conductive layer is preparing a coating solution for a conductive layer using a solvent, a binder material, and metal oxide particle coated with tin oxide doped with niobium or tantalum, and forming the conductive layer using the coating solution for a conductive layer,

the metal oxide particle coated with tin oxide doped with niobium or tantalum used for preparation of the coating solution for a conductive layer has a powder resistivity of not less than 1.0×

10³ Ω

·

cm and not more than 1.0×

10⁵ Ω

·

cm, and

the mass ratio (P/B) of the metal oxide particle coated with tin oxide doped with niobium or tantalum (P) to the binder material (B) in the coating solution for a conductive layer is not less than 1.5/1.0 and not more than 3.5/1.0.

12. The method for producing an electrophotographic photosensitive member according to claim 11, wherein the powder resistivity of the metal oxide particle coated with tin oxide doped with niobium or tantalum used for preparation of the coating solution for a conductive layer is not less than 3.0×

10³ Ω

·

cm and not more than 5.0×

10⁴ Ω

·

cm.

13. The method for producing an electrophotographic photosensitive member according to claim 11, wherein the metal oxide particle coated with tin oxide doped with niobium or tantalum is titanium oxide particle coated with tin oxide doped with niobium.

14. The method for producing an electrophotographic photosensitive member according to claim 11, wherein the metal oxide particle coated with tin oxide doped with niobium or tantalum is titanium oxide particle coated with tin oxide doped with tantalum.

15. The method for producing an electrophotographic photosensitive member according to claim 11, wherein the metal oxide particle coated with tin oxide doped with niobium or tantalum is tin oxide particle coated with tin oxide doped with niobium.

16. The method for producing an electrophotographic photosensitive member according to claim 11, wherein the metal oxide particle coated with tin oxide doped with niobium or tantalum is tin oxide particle coated with tin oxide doped with tantalum.

17. The method for producing an electrophotographic photosensitive member according to claim 11, wherein the metal oxide particle coated with tin oxide doped with niobium or tantalum is zinc oxide particle coated with tin oxide doped with niobium.

18. The method for producing an electrophotographic photosensitive member according to claim 11, wherein the metal oxide particle coated with tin oxide doped with niobium or tantalum is zinc oxide particle coated with tin oxide doped with tantalum.