Amperometric sensor system

• US 8,984,931 B2
• Filed: 10/16/2012
• Issued: 03/24/2015
• Est. Priority Date: 02/15/2011
• Status: Active Grant

• Current Assignee: Halogen Systems, Inc.
• Original Assignee: Michael A. Silveri
• Inventors: Silveri, Michael A.
• Primary Examiner(s): Macchiarolo, Peter
• Assistant Examiner(s): KOLB, NATHANIEL J
• Application Number:
  US13/653,386
• Publication Number:
  US 20130036799A1
• Time in Patent Office: 889 Days
• Field of Search: 422 8201- 8204, 73/614.1, 205/775
• US Class Current: 73/61.41
• CPC Class Codes: F04D 1/04 Helico-centrifugal pumps
• CPC Class Codes: G01N 27/06 of a liquid involving electrolysis G01N27/26
• CPC Class Codes: G01N 27/08 which is flowing continuously
• CPC Class Codes: G01N 27/4168 Oxidation-reduction potential, e.g. for chlorination of water water analysis G01N33/18
• CPC Class Codes: G01N 33/18 Water
• CPC Class Codes: G01N 33/1893 using flow cells
• CPC Class Codes: Y10T 29/49002 Electrical device making

Abstract

A sensor system that measures at least one parameter of water includes an electronics subsystem and includes a sensor housing electrically and mechanically coupled to the electronics subsystem. The sensor housing encloses a chamber that receives water via at least one inlet and that releases water via at least one outlet. At least one sensor has at least one electrode exposed to water in the chamber. A flow generator causes water to flow through the chamber. A plurality of objects within the chamber move in response to the water flow and abrasively clean the at least one electrode. Preferably, the sensor system includes a chlorine sensor having at least two electrodes. The electronics subsystem applies a first differential voltage between the two electrodes during a measurement interval and then applies a second differential voltage between the two electrodes during an interval following the measurement interval.

Claims

1. A method for quantifying two species in water, comprising:

applying a first differential measurement potential between at least first and second electrodes of at least one sensor probe;

measuring a first output signal responsive to the concentration of a parameter of water to be measured and responsive to the first differential measurement potential;

applying a second differential measurement potential between the at least first and second electrodes of the at least one sensor probe, the second differential measurement potential being different from the first differential measurement potential;

measuring a second output signal responsive to the concentration of the parameter of water to be measured and responsive to the second differential measurement potential;

determining a ratio of the first output signal to the second output signal; and

determining which of the two species is present based on the ratio of the first output signal to the second output signal; and

calculating and quantifying the species present.

2. The method as defined in claim 1, wherein:

both of the two species are present; and

each of the two species is quantified according to the ratio of the first output signal to the second output signal.

3. The method as defined in claim 1, wherein:

the first species comprises free chlorine and the second species comprises chloramine;

the ratio of the first output signal to the second output signal has a value in a first range when the species in the water comprises free chlorine and has a value in a second range when the species in the water comprises chloramine.