Controlled release of actives for materials used in construction

• US 8,986,445 B2
• Filed: 06/04/2010
• Issued: 03/24/2015
• Est. Priority Date: 12/06/2007
• Status: Expired due to Fees

• Current Assignee: Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno
• Original Assignee: Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno
• Inventors: Eversdijk, Jacobus, Tempelaars, Karin, Fischer, Rudolf Hartmut
• Primary Examiner(s): MARCANTONI, PAUL D
• Application Number:
  US12/793,886
• Publication Number:
  US 20100313786A1
• Time in Patent Office: 1,754 Days
• Field of Search: 106/724, 106/694, 106/718, 106/725, 106/727, 106/773, 106/778, 106/803, 106/DIG.4
• US Class Current: 106/724
• CPC Class Codes: C01B 33/44 Products obtained from layered base-exchange silicates by ion-exchange with organic compounds such as ammonium, phosphonium or sulfonium compounds or by intercalation of organic compounds, e.g. organoclay material
• CPC Class Codes: C04B 14/208 delaminated mica or vermiculite platelets
• CPC Class Codes: C04B 2103/69 Fungicides
• CPC Class Codes: C04B 2111/20 Resistance against chemical, physical or biological attack
• CPC Class Codes: C04B 24/003 Phosphorus-containing compounds
• CPC Class Codes: C04B 24/04 Carboxylic acids; Salts, anhydrides or esters thereof
• CPC Class Codes: C04B 24/16 Sulfur-containing compounds
• CPC Class Codes: C04B 26/02 Macromolecular compounds
• CPC Class Codes: C04B 28/02 containing hydraulic cements other than calcium sulfates
• CPC Class Codes: C04B 28/14 containing calcium sulfate cements gypsum-paper plates E04C
• CPC Class Codes: C04B 40/0039 Premixtures of ingredients
• CPC Class Codes: Y10S 106/04 Bentonite

Abstract

The invention is directed to a construction material and to the use of modified layered inorganic material.

The construction material of the invention comprises a layered inorganic material, which layered inorganic material comprises an ionic organic modifier compound and a biocide. The construction material of the invention has increased resistance against microbial fouling.

Claims

1. A construction composition comprising a construction material and a biocide molecule release agent, wherein the biocide molecule release agent includes an inorganic material being either a negatively charged clay or a positively charged layered double hydroxide, wherein the inorganic material is modified with one or more ionic organic modifier compounds and wherein said inorganic material is intercalated with a biocide molecule being a fungicide, an algicide or a bactericide, wherein the construction material is cement, plaster, jointing compound, paint, glue, plastics, wallpaper, wood, textiles, straw, or thatch.

2. The construction composition according to claim 1, wherein the one or more ionic organic modifier compounds have a chemical or physical interaction with the biocide molecule.

3. The construction composition according to claim 1, wherein the inorganic material is modified with a mixture of at least two different ionic organic modifier compounds.

4. The construction composition according to claim 1, wherein the one or more ionic organic modifier compounds are ammonium compounds, phosphonium compounds, or sulphonium compounds, or mixtures thereof in combination with a negatively charged clay.

5. The construction composition according to claim 1, wherein the fungicide, algicide or bactericide is one or more of substituted benzenes, thiocarbamates, ethylene bis dithiocarbamates, thiophthalimides, organomercury compounds, pyrithiones or organotin compounds.

6. The construction composition according to claim 5, wherein the fungicide, algicide or bactericide is one or more of propiconazole, carbonic acid, butyl-3-iodo-2-propynylester, 1-[2-(2,4-dichlorophenyl)-2-(2-prop enyloxy)ethyl] 1H imidazole, bethoxazin, zinc pyrithione, sodium pyrithione, hydroxypyridone or bispyrithione.

7. The construction composition according to claim 1, comprising 1-60 000 ppm by weight of the biocide molecule, based on the total weight of the construction material.

8. The construction composition according to claim 1, wherein at least 25% of the exchange capacity of the inorganic material is occupied by the one or more ionic organic modifier compounds.

9. The construction composition according to claim 1, wherein the inorganic material comprises at least 1 wt. % of the biocide molecule, based on the total weight of the modified and loaded inorganic material.

15. The construction composition according to claim 1, wherein the negatively charged clay is smectite, montmorillonite, kaolinite, vermiculite, bentonite, saponite, or hectorite.

16. The construction composition according to claim 1, wherein the positively charged layered double hydroxide is hydrotalcite.

17. The construction composition according to claim 1, comprising 1-30 000 ppm by weight of the biocide molecule, based on the total weight of the construction material.

18. The construction composition according to claim 8, wherein at least 50% of the exchange capacity of the inorganic material is occupied by the one or more ionic organic modifier compounds.

19. The construction composition according to claim 8, wherein at least 100% of the exchange capacity of the inorganic material is occupied by the one or more ionic organic modifier compounds.

20. The construction composition according to claim 9, wherein the inorganic material comprises at least 1-60% wt of the biocide molecule, based on the total weight of the modified and loaded inorganic material.

21. The construction composition according to claim 9, wherein the inorganic material comprises at least 10-30 wt. % of the biocide molecule, based on the total weight of the modified and loaded inorganic material.

22. The construction composition according to claim 1, wherein the one or more ionic organic modifier compounds are conjugate bases of carboxylic acids, phosphonic acids, sulphonic acids or mixture thereof in combination with a positively charged layered double hydroxide.

10. A method for controlling the release profile of a specific biocide molecule in a construction material, comprising

providing an inorganic material being either a negatively charged clay or a positively charged layered double hydroxide;

adjusting the affinity of the inorganic material to the specific biocide molecule by modifying the inorganic material with one or more ionic organic modifier compounds;

intercalating the modified inorganic material with the biocide molecule being a fungicide, an algicide or a bactericide; and

including the modified and intercalated inorganic material in the construction material, wherein the construction material is cement, plaster, jointing compound, paint, glue, plastics, wallpaper, wood, textiles, straw, or thatch.

11. The method according to claim 10, wherein the one more ionic organic modifier compounds have a chemical or physical interaction with the biocide.

12. A method for reducing or preventing microbial fouling in a construction material comprising including into the construction material an inorganic material being either a negatively charged clay or a positively charged layered double hydroxide, wherein the inorganic material is modified with one or more ionic organic modifier compounds and wherein said inorganic material is intercalated with a biocide molecule being a bactericide, wherein the construction material is cement, plaster, jointing compound, paint, glue, plastics, wallpaper, wood, textiles, straw, or thatch.

13. A method for reducing or preventing fungi fouling in a construction material comprising including into the construction material an inorganic material being either a negatively charged clay or a positively charged layered double hydroxide, wherein the inorganic material is modified with one or more ionic organic modifier compounds and wherein said inorganic material is intercalated with a biocide molecule being a fungicide, wherein the construction material is cement, plaster, jointing compound, paint, glue, plastics, wallpaper, wood, textiles, straw, or thatch.

14. A method for reducing or preventing algae fouling in a construction material comprising including into the construction material an inorganic material being either a negatively charged clay or a positively charged layered double hydroxide, wherein the inorganic material is modified with one or more ionic organic modifier compounds and wherein said inorganic material is intercalated with a biocide molecule being an algicide, wherein the construction material is cement, plaster, jointing compound, paint, glue, plastics, wallpaper, wood, textiles, straw, or thatch.