Luminescent borates, materials and articles incorporating such borates, and methods and apparatus for their production and use in article authentication

• US 8,993,101 B2
• Filed: 11/08/2012
• Issued: 03/31/2015
• Est. Priority Date: 11/15/2011
• Status: Active Grant

• Current Assignee: Honeywell International Inc.
• Original Assignee: Honeywell International Inc.
• Inventors: Kane, James, Rapoport, William Ross, Lau, Carsten
• Primary Examiner(s): HIGGINS, GERARD T
• Application Number:
  US13/672,136
• Publication Number:
  US 20130122266A1
• Time in Patent Office: 873 Days
• Field of Search: 428/195.1, 428/206, 252/301.4 R, 283/92
• US Class Current: 428/195.1
• CPC Class Codes: B42D 15/00 Printed matter of special format or style not otherwise provided for
• CPC Class Codes: B42D 2033/20 Coloured material; Pigments or inks
• CPC Class Codes: B42D 25/00 Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof printing processes to produce identification or security features B41M3/14
• CPC Class Codes: B42D 25/21 for multiple purposes
• CPC Class Codes: B42D 25/23 Identity cards
• CPC Class Codes: B42D 25/24 Passports
• CPC Class Codes: B42D 25/29 Securities; Bank notes
• CPC Class Codes: B42D 25/373 Metallic materials
• CPC Class Codes: C09D 11/50 Sympathetic, colour changing or similar inks
• CPC Class Codes: C09K 11/7712 Borates
• CPC Class Codes: C09K 11/7756 containing neodynium
• CPC Class Codes: C09K 11/778 Borates
• CPC Class Codes: G07D 7/1205 Testing spectral properties
• CPC Class Codes: Y10T 428/24802 Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
• CPC Class Codes: Y10T 428/24893 including particulate material
• CPC Class Codes: Y10T 428/2982 Particulate matter [e.g., sphere, flake, etc.]
• CPC Class Codes: Y10T 428/662 Wood timber product [e.g., piling, post, veneer, etc.]
• CPC Class Codes: Y10T 442/20 Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer

Abstract

Embodiments include luminescent materials and associated production methods. The material includes a crystal borate having a first substitutable element and a second substitutable element, one or more rare earth ions substituted for the first substitutable element, and chromium substituted for the second substitutable element. The one or more rare earth ions are selected from a group consisting of neodymium and ytterbium. The material also may include a medium within which particles of the borate are incorporated. The medium, with the luminescent material particles, may form a security feature of an article. Embodiments of methods for identifying whether such a luminescent material is incorporated with an article include exposing a portion of the article to excitation in a chromium absorption band, and determining whether a detected emission produced by the article as a result of the excitation indicates an ytterbium emission after termination of the exposing step.

Claims

1. A luminescent material comprising:

a luminescent borate formed from a borate having a crystal structure and including a first substitutable element and a second substitutable element;

wherein the luminescent borate comprises one or more rare earth ions substituted for the first substitutable element, wherein the one or more rare earth ions are selected from a group consisting of neodymium and ytterbium; and

wherein the luminescent borate further comprises chromium substituted for the second substitutable element.

2. The luminescent material of claim 1, wherein the borate has a formula MeX₃B₄O₁₂, wherein

Me is the first substitutable element, which is selected from a group consisting of yttrium, lanthanum, gadolinium, lutetium, and a mixture thereof,

X is the second substitutable element, which is selected from a group consisting of aluminum, scandium, and gallium,

B is boron, and

O is oxygen.

3. The luminescent material of claim 1, wherein the borate has the formula YAl₃B₄O₁₂, where Y is the first substitutable element yttrium, Al is the second substitutable element aluminum, B is boron, and O is oxygen.

4. The luminescent material of claim 1, wherein the borate has the formula LaAl₃B₄O₁₂, where La is the first substitutable element lanthanum, Al is the second substitutable element aluminum, B is boron, and O is oxygen.

5. The luminescent material of claim 1, wherein the borate has the formula GdAl₃B₄O₁₂, where Gd is the first substitutable element gadolinium, Al is the second substitutable element aluminum, B is boron, and O is oxygen.

6. The luminescent material of claim 1, wherein the one or more rare earth ions comprises neodymium substituted for the first substitutable element at a substitution percentage of about 5 to about 100 percent.

7. The luminescent material of claim 1, wherein the one or more rare earth ions comprises ytterbium substituted for the first substitutable element at a substitution percentage in a range of about 5 to about 100 percent.

8. The luminescent material of claim 1, wherein the one or more rare earth ions comprises:

neodymium substituted for the first substitutable element at a first substitution percentage in a range of about 5 to about 95 percent; and

ytterbium substituted for the first substitutable element at a second substitution percentage in a range of about 5 to about 95 percent.

9. The luminescent material of claim 1, wherein the chromium is substituted at a substitution percentage up to 100 percent.

10. The luminescent material of claim 1, wherein the borate has a crystal structure selected from a group consisting of a monoclinic Huntite-like structure, a rhombohedral Huntite-like structure, and a mixed Huntite-like structure.

11. The luminescent material of claim 1, wherein the luminescent borate is in a form of particles, and the material further comprises:

a medium within which the particles are incorporated, wherein the medium is selected from a group consisting of a glue, a liquid, a gel, a polymer, a slurry, a plastic, plastic base resin, a glass, a ceramic, a metal, a textile, wood, fiber, paper pulp, and paper.

12. The luminescent material of claim 1, wherein the luminescent borate is in a powder form, and the luminescent material comprises luminescent borate particles with a particle size of less than about 10 microns.

13. A method for producing a luminescent material for use in authentication, the method comprising the steps of:

preparing a luminescent borate from a borate having a crystal structure and including a first substitutable element and a second substitutable element, wherein preparing the luminescent borate comprises;

substituting one or more rare earth ions for the first substitutable element of the borate, and

substituting chromium for the second substitutable element of the borate, wherein the one or more rare earth ions are selected from a group consisting of neodymium and ytterbium; and

dispersing the luminescent borate in a medium to produce the luminescent material.

14. The method of claim 13, wherein the borate has a formula MeX₃B₄O₁₂, wherein

Me is the first substitutable element, which is selected from a group consisting of yttrium, lanthanum, gadolinium, lutetium, and a mixture thereof,

X is the second substitutable element, which is selected from a group consisting of aluminum, scandium, and gallium,

B is boron, and

O is oxygen.

15. The method of claim 13, further comprising the step of:

processing the luminescent borate to produce particles with a particle size of less than 10 microns, wherein the particles of the luminescent borate are dispersed in the medium.

16. The method of claim 13, wherein the medium is selected from a group consisting of a glue, a liquid, a gel, a polymer, a slurry, a plastic, plastic base resin, a glass, a ceramic, a metal, a textile, wood, fiber, paper pulp, and paper.

17. An article comprising:

a security feature that includes;

a medium, and

particles of a luminescent borate dispersed in the medium, the luminescent borate formed from a borate having a crystal structure and including a first substitutable element and a second substitutable element, wherein the luminescent borate comprises one or more rare earth ions substituted for the first substitutable element, wherein the luminescent borate further comprises chromium substituted for the second substitutable element, and wherein the one or more rare earth ions are selected from a group consisting of neodymium and ytterbium.

18. The article of claim 17, wherein the borate has a formula MeX₃B₄O₁₂, wherein

Me is the first substitutable element, which is selected from a group consisting of yttrium, lanthanum, gadolinium, lutetium, and a mixture thereof,

X is the second substitutable element, which selected from a group consisting of aluminum, scandium, and gallium,

B is boron, and

O is oxygen.

19. The article of claim 17, further comprising:

a substrate, wherein the medium is an ink that is printed on a surface of the substrate.

20. The article of claim 17, wherein the article is an article selected from a group consisting of an identification card, a driver'"'"'s license, a passport, identity papers, a banknote, a check, a document, a paper, a stock certificate, a packaging component, a credit card, a bank card, a label, a seal, a postage stamp, a token, a liquid, a human, an animal, and a biological sample.