Methods and compositions for antimicrobial surfaces

• US 8,999,363 B2
• Filed: 11/15/2006
• Issued: 04/07/2015
• Est. Priority Date: 02/07/2005
• Status: Active Grant

• Current Assignee: Termpro LLC
• Original Assignee: Sishield Technologies, Inc.
• Inventors: Elfersy, Jacques
• Primary Examiner(s): Pak, John
• Assistant Examiner(s): Schlientz, Nathan W
• Application Number:
  US11/599,956
• Publication Number:
  US 20070065475A1
• Time in Patent Office: 3,065 Days
• Field of Search: 424/405, 424/616, 424/421, 514/63, 514/642, 514/643
• US Class Current: 424/421
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 25/08 containing solids as carriers or diluents
• CPC Class Codes: A01N 33/12 Quaternary ammonium compounds
• CPC Class Codes: A01N 55/00 Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing organo-phosphorus compounds A01N57/00

Abstract

The present invention comprises methods and compositions for treating solid surfaces having antimicrobial and biocidal properties. Such surfaces are capable of controlling or killing a broad spectrum of biological agents, including viruses, bacteria and other microbial agents in solids, liquids or gases that subsequently contact the treated surface.

Claims

1. An antimicrobial composition, comprising:

perlite coated with a composition comprising approximately 4% by weight an organosilane quaternary ammonium compound and approximately 2% by weight a quaternary ammonium compound,

wherein the quaternary ammonium compound is not an organosilane quaternary ammonium compound;

wherein the organosilane quaternary ammonium compound is 3-trimethoxysilyl propyltetradecyldimethyl ammonium chloride; and

wherein the quaternary ammonium compound is a mixture of alkyl (C12, C14 and C16) dimethyl benzyl ammonium chloride, octyl decyl dimethyl ammonium chloride, dioctyl dimethyl ammonium chloride and didecyl dimethyl ammonium chloride.

2. The antimicrobial composition of claim 1, wherein the composition further comprises at least one agent selected from the group consisting of an oxidizing agent, a chelating agent, and a stabilizing agent.

3. The antimicrobial composition of claim 2, wherein the oxidizing agent is hydrogen peroxide.

4. The antimicrobial composition of claim 2, wherein the chelating agent is ethylenediaminetetraacetic acid (EDTA) or a salt thereof

5. The antimicrobial composition of claim 2, wherein the stabilizing agent is propylene carbonate, glycol ether, a polyol, or sucrose.

6. A method of rendering perlite antimicrobial comprising:

contacting perlite with an aqueous composition, wherein the aqueous composition comprises approximately 4% by weight of an organosilane quaternary ammonium compound and approximately 2% by weight of a quaternary ammonium compound, and wherein the quaternary ammonium compound is not an organosilane quaternary ammonium compound; and

bonding at least a portion of the aqueous composition to at least a portion of the perlite to form an antimicrobial coating on the perlit,

wherein the organosilane quaternary ammonium compound is 3-trimethoxysilyl propyltetradecyldimethyl ammonium chloride; and

wherein the quaternary ammonium compound is a mixture of alkyl (C12, C14 and C16) dimethyl benzyl ammonium chloride, octyl decyl dimethyl ammonium chloride, dioctyl dimethyl ammonium chloride and didecyl dimethyl ammonium chloride.

7. The method of claim 6, wherein the aqueous composition further comprises at least one agent selected from the group consisting of an oxidizing agent, a chelating agent, or a stabilizing agent.

8. The method of claim 7, wherein the oxidizing agent is hydrogen peroxide.

9. The method of claim 7, wherein the chelating agent is ethylenediaminetetraacetic acid (EDTA) or a salt thereof.

10. The method of claim 7, wherein the stabilizing agent is propylene carbonate, glycol ether, a polyol, or sucrose.

11. A method of removing a portion of microbes present in a gas, liquid or solid, comprising:

contacting the gas, liquid or solid with a composition having antimicrobial activity, the composition having antimicrobial activity comprising perlite coated by an aqueous composition comprising approximately 4% by weight of an organosilane quaternary ammonium compound and approximately 2% by weight of a quaternary ammonium compound,

wherein the quaternary ammonium compound is not an organosilane quaternary ammonium compound;

wherein the organosilane quaternary ammonium compound is 3-trimethoxysilyl propyltetradecyldimethyl ammonium chloride; and

wherein the quaternary ammonium compound is a mixture of alkyl (C12, C14 and C16) dimethyl benzyl ammonium chloride, octyl decyl dimethyl ammonium chloride, dioctyl dimethyl ammonium chloride and didecyl dimethyl ammonium chloride.

12. The method of claim 11, wherein the aqueous composition further comprises at least one agent selected from the group consisting of an oxidizing agent, a chelating agent or a stabilizing agent.